Synthesis, structures and reactivity of lanthanoid(II) formamidinates of varying steric bulk

Chemistry - A European Journal

Volumn 19, Issue 4, 2013, Pages 1410-1420

  Cole, Marcus L ^a,b   Deacon, Glen B ^a   Forsyth, Craig M ^a   Junk, Peter C ^a,c   Konstas, Kristina ^a,d   Wang, Jun ^a   Bittig, Henry ^a   Werner, Daniel ^a  

^a MONASH UNIVERSITY   (Australia)

^b UNIVERSITY OF NEW SOUTH WALES   (Australia)

^c JAMES COOK UNIVERSITY   (Australia)

^d CSIRO   (Australia)

Author keywords

C F Cl Br activation; formamidinate; heteroleptic lanthanide compounds; lanthanides; X ray diffraction

Indexed keywords

1 ,2-DICHLOROETHANES; FORMAMIDINATE; FORMAMIDINES; PERFLUORODECALIN; SIX-COORDINATE MONOMERS; STERIC BULK; THF LIGANDS; TRANSMETALLATION; UNIDENTATE; X RAY CRYSTAL STRUCTURES;

CHEMICAL ACTIVATION; CHLORINE COMPOUNDS; DIMERS; EUROPIUM; LIGANDS; MERCURY (METAL); NEODYMIUM; RARE EARTH ELEMENTS; REDOX REACTIONS; TERBIUM; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION; YTTERBIUM;

LANTHANUM;

COORDINATION COMPOUND; LANTHANIDE; YTTERBIUM;

ARTICLE; CHEMISTRY; CONFORMATION; ISOMERISM; OXIDATION REDUCTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

COORDINATION COMPLEXES; CRYSTALLOGRAPHY, X-RAY; ISOMERISM; LANTHANOID SERIES ELEMENTS; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; YTTERBIUM;

EID: 84872469410     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201202861     Document Type: Article

References (56)

1. R. Kempe, Angew. Chem. 2000, 112, 478-504
2. Angew. Chem. Int. Ed. 2000, 39, 468-493
3. P. W. Roesky, Chem. Soc. Rev. 2000, 29, 335-345
4. W. E. Piers, D. J. H. Emslie, Coord. Chem. Rev. 2002, 233, 131-155
5. F. T. Edelmann, D. M. M. Freckmann, H. Schumann, Chem. Rev. 2002, 102, 1851-1896
6. S. Cotton, in Comprehensive Coordination Chemistry II Vol 3 (eds.: J. A. McCleverty, T. J. Meyer, G. F. R. Parkin), Elsevier, Oxford, 2004, Chapter 3.2, pp. 93-188
7. R. Anwander, Top. Curr. Chem. 1996, 179, 33-112
8. F. T. Edelmann, Coord. Chem. Rev. 1994, 137, 403-481
9. F. T. Edelmann, Top. Curr. Chem. 1996, 179, 113-148
10. F. T. Edelmann, Adv. Organomet. Chem. 2008, 57, 183-352
11. F. T. Edelmann, in Comprehensive Organometallic Chemistry III Vol. 4 (eds.: R. H. Crabtree, D. M. P. Mingos) Elsevier, Oxford, UK 2006, 1-190
12. F. T. Edelmann, Chem. Soc. Rev. 2009, 38, 2253-2268.
13. M. L. Cole, G. B. Deacon, C. M. Forsyth, P. C. Junk, K. Konstas, J. Wang, Chem. Eur. J. 2007, 13, 8092-8110.
14. P. C. Junk, M. L. Cole, Chem. Commun. 2007, 1579-1590.
15. G. B. Deacon, C. M. Forsyth, S. Nickel, J. Organomet. Chem. 2002, 647, 50-60
16. G. B. Deacon, C. M. Forsyth, in Inorganic Chemistry Highlights (eds. G. Meyer, D. Naumann, L. Wesemann) Wiley-VCH, Weinheim, 2002, Chapter 7, pp. 139-153
17. K. Müller-Buschbaum, Z. Anorg. Allg. Chem. 2005, 631, 811-828
18. G. Meyer, Z. Anorg. Allg. Chem. 2008, 634, 201-222.
19. M. L. Cole, G. B. Deacon, P. C. Junk, K. Konstas, Chem. Commun. 2005, 1581-1583.
20. M. L. Cole, P. C. Junk, Chem. Commun. 2005, 2695-2697.
21. M. L. Cole, G. B. Deacon, C. M. Forsyth, P. C. Junk, D. C. Polo, J. Wang, Dalton Trans. 2010, 39, 6732-6738.
22. M. Wedler, M. Noltemeyer, U. Pieper, H.-G. Schmidt, D. Stalke, F. T. Edelmann, Angew. Chem. 1990, 102, 941-943
23. Angew. Chem. Int. Ed. Engl. 1990, 29, 894-896.
24. S. Yao, H.-S. Chan, C.-K. Lam, H. K. Lee, Inorg. Chem. 2009, 48, 9936-9946
25. D. Heitmann, C. Jones, P. C. Junk, K. Lippert, A. Stasch, Dalton Trans. 2007, 187-189.
26. W. T. Carnall, in Handbook on the Physics and Chemistry of Rare Earths Vol. 3 (eds: K. A. Gschneider, L. Eyring) North Holland Publishing Company, Amsterdam, 1979, pp. 171-208.
27. G. B. Deacon, E. E. Delbridge, B. W. Skelton, A. H. White, Eur. J. Inorg. Chem. 1999, 751-761
28. G. B. Deacon, E. E. Delbridge, B. W. Skelton, A. H. White, Eur. J. Inorg. Chem. 1998, 543-545.
29. G. B. Deacon, D. L. Wilkinson, Inorg. Chim. Acta 1988, 142, 155-159.
30. M. L. Cole, G. B. Deacon, C. M. Forsyth, K. Konstas, P. C. Junk, Dalton Trans. 2006, 3360-3367.
31. G. B. Deacon, J. E. Cosgriff, E. T. Lawrenz, C. M. Forsyth, D. L. Wilkinson, in Herrmann-Brauer, Synthetic Methods of Organometallic and Inorganic Chemistry Vol. 6 (ed.: W. A. Herrmann), Thieme, Stuttgart, 1997, p. 48.
32. M. L. Cole, A. J. Davies, C. Jones, P. C. Junk, New J. Chem. 2005, 29, 1404-1408.
33. A. G. Avent, M. A. Edelmann, M. F. Lappert, G. A. Lawless, J. Am. Chem. Soc. 1989, 111, 3423-3425.
34. J. M. Keates, G. A. Lawless, Organometallics 1997, 16, 2842-2846.
35. J. R. van den Hende, P. B. Hitchcock, S. A. Holmes, M. F. Lappert, J. Chem. Soc. Dalton Trans. 1995, 1435-1440
36. J. R. van den Hende, P. B. Hitchcock, M. F. Lappert, J. Chem. Soc. Dalton Trans. 1995, 2251.
37. G. B. Deacon, G. D. Fallon, C. M. Forsyth, H. Schumann, R. Weiman, Chem. Ber./Rec. 1997, 130, 409-415.
38. A. M. Dietel, C. Döring, G. Glatz, M. V. Butovskii, O. Tok, F. M. Schappacher, R. Pöttgen, R. Kempe, Eur. J. Inorg. Chem. 2009, 1051-1059.
39. G. B. Deacon, S. C. Harris, G. Meyer, D. Stellfeldt, D. L. Wilkinson, G. Zelesny, J. Organomet. Chem. 1998, 552, 165-170.
40. G. B. Deacon, G. Meyer, D. Stellfeldt, Eur. J. Inorg. Chem. 2000, 1061-1071.
41. P. L. Watson, T. H. Tulip, I. Williams, Organometallics 1990, 9, 1999-2009.
42. R. D. Shannon, Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1976, 32, 751-767.
43. K. Nakamoto, Infrared and Raman Spectra of Inorganic Compounds, Part A Theory and Applications in Inorganic Chemistry, Wiley, Hoboken, 2009, pp. 240-242.
44. R. H. Hauge, J. W. Hastie, J. L. Margrave, J. Less-Common Met. 1971, 23, 359-365.
45. G. B. Deacon, T. Feng, P. C. Junk, B. W. Skelton, A. N. Sobolev, A. H. White, Aust. J. Chem. 1998, 51, 75-89.
46. D. Stellfeldt, G. Meyer, G. B. Deacon, Z. Anorg. Allg. Chem. 2001, 627, 1659-1662.
47. M. Choca, J. R. Ferraro, K. Nakamoto, J. Inorg. Nucl. Chem. 1975, 37, 1425-1428.
48. G. B. Deacon, S. Harris, G. Meyer, D. Stellfeldt, D. Wilkinson, G. Zelesny, J. Organomet. Chem. 1996, 525, 247-254.
49. From a survey of the Cambridge Structural Database (CSD), Version ConQuest 1.14, December 2011.
50. G. B. Deacon, C. M. Forsyth, P. C. Junk, B. W. Skelton, A H. White, Chem. Eur. J. 1999, 5, 1452-1459.
51. J. Wang, Y. Yao, J. Cheng, X. Pang, Y. Zhang, Q. Shen, J. Mol. Struct. 2005, 743, 229-235.
52. R. M. Roberts, J. Am. Chem. Soc. 1949, 71, 3848-3849.
53. G. B. Deacon, D. Tunaley, J. Organomet. Chem. 1978, 156, 403-426.
54. Z. Otwinowski, W. Minor, Methods Enzymol. 1997, 276, 307-326.
55. G. M. Sheldrick, SHELXL-97, University of Göttingen, Göttingen, 1997.
56. L. J. Barbour, J. Supramol. Chem. 2001, 1, 189-191.