Synthesis of the First Lanthanoid(II) Pyrazolate Complex by Redox Transmetallation from Thallium and Mercury Reagents

European Journal of Inorganic Chemistry

Volumn , Issue 5, 1998, Pages 543-545

  Deacon, Glen B ^a   Delbridge, Ewan E ^a   Skelton, Brian W ^b   White, Allan H ^b  

^a MONASH UNIVERSITY   (Australia)

^b UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

Author keywords

Diphenylmercury; Lanthanoid(II) complexes; Redox transmetallation; Thallium; X ray crystal structure; Ytterbium; 2 Pyrazolate complexes

Indexed keywords

CRYSTAL STRUCTURE; MERCURY COMPOUNDS; THALLIUM COMPOUNDS; YTTERBIUM COMPOUNDS;

DIPHENYLMERCURY; LANTHANOID(II) COMPLEX; LANTHANOIDS; PYRAZOLATE; REDOX TRANSMETALLATION; TETRA-HYDROFURAN; TETRAHYDROFURANS; TRANSMETALLATION; X RAY CRYSTAL STRUCTURES; Η2-PYRAZOLATE COMPLEX;

SYNTHESIS (CHEMICAL);

EID: 2742598208     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(199805)1998:5<543::AID-EJIC543>3.0.CO;2-D     Document Type: Article

References (41)

1. H Schumann, J. A. Meese-Marktscheffel, L. Esser, Chem. Rev. 1995, 95, 865-986.
2. F. T. Edelmann, in Comprehensive Organometallic Chemistry, 2nd ed. (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon, Oxford, 1995, chapter 2.
3. M. N. Bochkarev, L. N. Zakharov, G. S. Kalinina, Organoderivatives of Rare Earth Elements Kluwer Academic Press, Dordrecht, 1995.
4. L. N. Bochkarev, T. A. Stepantseva, L. N. Zakharov, G. K. Fukin, A. I. Yanovsky, Y. T. Struchkov, Organometallics. 1995, 14, 2127-2129.
5. G. B. Deacon, G. D. Fallon, C. M. Forsyth, H. Schumann, R. Weimann, Chem. Her. 1997, 130, 409-415.
6. B. Cetinkaya, P. B. Hitchcock, M. F. Lappert, R. G. Smith, J. Chem. Soc., Chem. Comm 1992, 932-934.
7. [7a] G. B. Deacon, A. J. Koplick, T. D. Tuong, Aust. J. Chem. 1984, 37, 517-525.
8. [7b] G. B Deacon, C. M. Forsyth, R. H. Newnham, T. D. Tuong, Aust. J. Chem. 1987, 40, 895-906.
9. [8a] G. B. Deacon, G. N. Pain, T. D. Tuong, Inorg. Synth. 1990, 28, 291-297.
10. [8b] G. B. Deacon, A. J. Koplick, G. N. Pain, T. D. Tuong, in Herrmann-Brauer, Synthetic Methods of Organometallic and Inorganic Chemistry, 3rd edn (Eds.: W. A. Herrmann) Vol. 6, 52-55, 86-87.
11. [9a] G. B. Deacon, A. Dietrich, C. M. Forsyth, H. Schumann, Angew. Chem. 1989, 101, 1374-1375; Angew. Chem. Int. Ed. Engl. 1989, 28, 1370-1371.
12. [9a] G. B. Deacon, A. Dietrich, C. M. Forsyth, H. Schumann, Angew. Chem. 1989, 101, 1374-1375; Angew. Chem. Int. Ed. Engl. 1989, 28, 1370-1371.
13. [9b] G. B. Deacon, C. M. Forsyth, W. C. Patalinghug, A. H. White, A. Dietrich, H. Schumann, Aust. J. Chem. 1992, 45, 671-683.
14. [9c] G. B. Deacon, C. M. Forsyth, B. M. Gatehouse, A. Philosof, B. W. Skelton, A. H. White, P. A. White, Aust. J. Chem. 1997, 50, 959-970
15. [10a] G. Y. Lin, T W. Wong, J. Organomet. Chem. 1995, 495, 203-208.
16. [10b] G. Y. Lin, T. W. Wong, J. Organomet. Chem. 1996, 523, 93-98.
17. [11a] G. B. Deacon, P. B. Hitchcock, S. A. Holmes, M. F. Lappert, P. MacKinnon, R. H. Newnham, J. Chem. Soc. Chem. Comm. 1989, 935-937.
18. [11b] G. B. Deacon, T Feng, S. Nickel, M. I Ogden, A. H. White, Aust. J. Chem. 1992, 45, 671-683.
19. [11c] G. B. Deacon, T. Feng, P. MacKinnon, R. H. Newnham, S. Nickel, B. W. Skelton, A. H. White, Aust. J. Chem. 1993, 46, 387-399.
20. [12a] H. Schumann, Pil Ryul Lee, J. Loebel, Angew. Chem. 1989, 101, 1073-1074; Angew. Chem. Int. Ed Engl. 1989, 28, 1033-1035.
21. [12a] H. Schumann, Pil Ryul Lee, J. Loebel, Angew. Chem. 1989, 101, 1073-1074; Angew. Chem. Int. Ed Engl. 1989, 28, 1033-1035.
22. [12b] H. Schumann, J. Loebel, J. Pickardt, Changtao Qian, Zuowei Xie, Organometallics 1991, 10, 215-219.
23. [12c] G. B. Deacon, B. M. Gatehouse, S. Nickel, S. N. Platts, Aust J. Chem. 1991, 44, 613-621.
24. [12d] J. E. Cosgriff, G. B. Deacon, B. M. Gatehouse, H. Hemling, H. Schumann, Angew. Chem. 1993, 105, 906-907; Angew. Chem. Int. Ed. Engl. 1993, 32, 874-875.
25. [12d] J. E. Cosgriff, G. B. Deacon, B. M. Gatehouse, H. Hemling, H. Schumann, Angew. Chem. 1993, 105, 906-907; Angew. Chem. Int. Ed. Engl. 1993, 32, 874-875.
26. [12e] J. E. Cosgriff, G. B. Deacon, B. M. Gatehouse, Aust J. Chem 1993, 46, 1881-1896.
27. [12f] J. E. Cosgriff, G. B. Deacon, B. M. Gatehouse, H. Hemling, H. Schumann, Aust J. Chem. 1994, 47, 1223-1235.
28. [12g] J. E. Cosgriff, G. B. Deacon, B. M. Gatehouse, Pil Ryul Lee, H. Schumann, Z Anorg. allg. Chem. 1996, 622, 1399-1403.
29. [12h] J. E. Cosgriff, G. B. Deacon, G. D. Fallon, B. M. Gatehouse, H. Schumann, R. Weimann, Chem. Ber. 1996, 129, 953-958.
30. G. Bielang, Doctoral Dissertation, Hamburg, 1979.
31. W. T. Carnall, in The Absorption and Fluorescence Spectra of Rare Earth Ions in Solution in Handbook on the Physics and Chemistry of Rare Earths. (Eds.: K. A. Gschneidner and L. Eyring) vol. 3, chapter 24, North-Holland, Amsterdam, 1979.
32. [14a] G. S. Ofelt, J. Chem. Phys. 1963, 38, 2171-2180.
33. [14b] A. N. Kamenskaya, N. B. Mikheev, N. A. Konovalova, Russ. J. Inorg. Chem. 1977, 22, 1152-1155.
34. [15a] S. Trofimenko, Prog. Inorg. Chem. 1986, 34, 115-120.
35. [15b] S. Trofimenko. Chem. Rev 1972, 72, 497-509.
36. [15c] J. E. Cosgriff, G. B. Deacon, Angew Chem. 1998, 110, 298-299; Angew. Chem. Int. Ed. Engl. 1998, 37, 286-287.
37. [15c] J. E. Cosgriff, G. B. Deacon, Angew Chem. 1998, 110, 298-299; Angew. Chem. Int. Ed. Engl. 1998, 37, 286-287.
38. [16a] I. A. Guzei, A. G. Baboul, G. P. A Yap, A. L. Rheingold, H. B. Schlegel, C. H. Winter, J. Am. Chem. Soc. 1997, 119, 3387-3388.
39. [16b] I. A. Guzei, G. P. A. Yap, C. H. Winter, Inorg. Chem. 1997, 36, 1738-1739.
40. [16c] D. Röttger, G. Erker, M. Grehl, R.Frölich, Organometallics, 1994, 13, 3897-3902.
41. R. D Shannon, Acta Crystallogr., Sect. A 1976, 32, 751-767.