Characterization of polyglycerol polyricinoleate formulations using NMR spectroscopy, mass spectrometry and dynamic light scattering

JAOCS, Journal of the American Oil Chemists' Society

Volumn 90, Issue 1, 2013, Pages 39-51

  Orfanakis, Andreas ^a   Hatzakis, Emmanuel ^a   Kanaki, Katerina ^a   Pergantis, Spiros A ^a   Rizos, Apostolos ^a   Dais, Photis ^a  

^a UNIVERSITY OF CRETE   (Greece)

Author keywords

Dynamic light scattering; ESI MS; NMR; PGPR; Tandem MS

Indexed keywords

CHAIN ASSOCIATION; ESI-MS; ESTOLIDES; NMR TECHNIQUES; PGPR; POLYGLYCEROLS; POLYRICINOLEATE; RICINOLEIC ACID; STRUCTURE AND MORPHOLOGY; TANDEM MASS SPECTROMETRY; TANDEM MS;

AGGREGATES; ELECTROSPRAY IONIZATION; EMULSIFICATION; ESTERS; GLYCEROL; LINOLEIC ACID; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERS;

DYNAMIC LIGHT SCATTERING;

THEOBROMA CACAO;

EID: 84872313735     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-012-2137-4     Document Type: Article

References (21)

1. Wilson R, van Shie BJ, Howes D (1998) Overview of the preparation, use and biological studies on polyglycerol polyricinoleate (PGPR). Food Chem Technol 36:711-718 (Pubitemid 28408690)
2. Wilson R, Smith M (1998) Human studies on polyglycerol polyricinoleate (PGPR). Food Chem Technol 36:743-745 (Pubitemid 28408693)
3. Bódalo A, Bastida J, Máximo MF, Montiel MC, Gómez M, Murcia MD (2008) Production of ricinoleic acid estolide with free and immobilized lipase from Candida rugosa. Biochem Eng J 39:450-456 (Pubitemid 351474465)
4. Sahasrabudhe MR (1967) Chromatographic analysis of polyglycerols and their fatty acid esters. J Am Oil Chem Soc 44:376-378
5. Garti N, Aserin A (1981) Analyses of polyglycerol esters of fatty acids using high performance liquid chromatography. J Liq Chromatogr 4:1173-1194 (Pubitemid 12539163)
6. Garti N, Aserin A (1982) Polyglycerol esters composition: theoretical random distribution versus HPLC analysis. J Am Oil Chem Soc 59:317-319
7. De Meulenaer B, Vanhoutte B, Heyghebaert A (2000) Combined liquid and gas chromatographic characterization of polyglycerol fatty acid esters. J Chromatogr 896:239-251
8. Chester TL, Innis DP (1986) Effect of free hydroxy groups in the separation of polyglycerol esters by capillary supercritical fluid chromatography. J High Resolut Chromatogr Chromatogr Commun 9:178-181 (Pubitemid 16523675)
9. AOAC (1998) Official methods of analysis, Official methods 965.32.41.1.12, 969.17.33.6. 08, 16th edn, vol II and III
10. Lyerla JR, Levy GC (1974) Carbon-13 nuclear spin relaxation. In: Levy GC (ed) Topics in carbon-13 NMR spectroscopy. Wiley, New York, pp 100-101
11. Freeman R, Hill HDW, Kaptein R (1972) Proton-decoupled NMR. Spectra of carbon-13 with the nuclear overhauser effect suppressed. J Magn Reson 7:327-329
12. Berger S, Braun S (2004) 200 and more experiments: a practical course. Wiley VCH, Weinheim
13. Morris KF, Johnson CS Jr (1992) Diffusion-ordered two-dimensional nuclear magnetic resonance spectroscopy. J Am Chem Soc 114:3139-3141
14. Lin JT, Arcinas A, Harden LR, Fagerquist CK (2006) Identification of (12-ricinoleoyl ricinoleoyl) diricinoleoylglycerol, an acylglycerol containing four acyl chains, in castor (Ricinus communis L.) oil by LC-ESI-MS. J Agric Food Chem 54:3498-3504 (Pubitemid 43844173)
15. Lin J-T, Arcinas A (2008) Regiospecific Identification of 2-(12-ricinoleoyl ricinoleoyl)-1,3-diricinoleoyl-sn-glycerol in castor (Ricinus communis L.) oil by ESI-MS. J Agric Food Chem 56:3616-3622 (Pubitemid 351860161)
16. Hayes DG, Kleiman R, Weisleder D, Adlof RO, Cuperus FP, Derksen JTP (1995) The triglyceride composition, structure, and presence of estolides in the oils of Lesquerella and related species. Ind Crops Prod 4:295-301
17. Batrakov SG, Tolkachev ON (1997) The structures of triacylglycerols from sclerotia of the rye ergot Claviceps purpurea (Fries) Tul. Chem Phys Lipids 86:1-12 (Pubitemid 27192376)
18. AOCS (2012) The lipid library. Lipid chemistry, biology, technology & Analysis. http://lipidlibrary.aocs.org/index.html
19. 1H NMR spectroscopy in combination with multivariate statistical analysis. A proposal for the detection of seed oil adulteration in virgin olive oils. J Agric Food Chem 51:5715-5722
20. Vlahov G (1999) Application of NMR to the study of olive oils. Progr Nucl Magn Reson Spectrosc 35:341-357 (Pubitemid 129593319)
21. Jakes J (1988) Testing of the constrained regularization method of inverting Laplace transform on simulated very wide quasielastic light scattering autocorrelation functions. J Phys B 38:1305-1307