Photomediated oxidation of atomically precise Au25(SC 2H4Ph)18- nanoclusters

Journal of Physical Chemistry Letters

Volumn 4, Issue 1, 2013, Pages 195-202

  Kauffman, Douglas R ^a,b   Alfonso, Dominic ^a   Matranga, Christopher ^a   Li, Gao ^c   Jin, Rongchao ^c  

^a NATIONAL ENERGY TECHNOLOGY LABORATORY   (United States)

^b URS   (United States)

^c CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBATE SYSTEMS; ANIONIC CHARGE; CATALYTIC REACTIONS; ELECTRON DONOR ACCEPTORS; ELECTRON-ACCEPTING; MOLECULAR SPECIES; NON-AQUEOUS; OPTICAL SPECTROSCOPY; PHOTOCHEMICAL PATHWAYS; PHOTOPHYSICAL PROCESS; RELATIVE ENERGIES; SOLVENT SYSTEM; SPONTANEOUS PROCESS;

ADSORPTION; CATALYSIS; CHARGE TRANSFER; DENSITY FUNCTIONAL THEORY;

NANOCLUSTERS;

EID: 84872188201     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz302056q     Document Type: Article

References (47)

1. 25 Cluster and Optical Properties J. Am. Chem. Soc. 2008, 130, 5883-5885
2. 18] J. Am. Chem. Soc. 2008, 130, 3754-3755
3. Qian, H.; Zhu, M.; Wu, Z.; Jin, R. Quantum Sized Gold Nanoclusters with Atomic Precision Acc. Chem. Res. 2012, 45, 1470-1479
4. 18 Acc. Chem. Res. 2010, 43, 1289-1296
5. Maity, P.; Xie, S.; Yamauchi, M.; Tsukuda, T. Stabilized Gold Clusters: from Isolation Toward Controlled Synthesis Nanoscale 2012, 4, 4027-4037
6. n Nanoclusters as Catalysts for Selective Oxidation and Hydrogenation Processes Adv. Mater. 2010, 22, 1915-1920
7. 18 Nanoclusters and Identification of Perimeter Sites as Active Centers ACS Nano 2012, 6, 6014-6022
8. 18 Nanoparticles as Catalysts for the Selective Hydrogenation of α,β-Unsaturated Ketones and Aldehydes Angew. Chem., Int. Ed. 2010, 49, 1295-1298
9. 25 Nanoparticle Catalyst for Hydrogenation of Cyclic Ketone J. Catal. 2010, 271, 155-160
10. 2: A Unique Interaction and Enhanced Electrocatalytic Activity J. Am. Chem. Soc. 2012, 134, 10237-10243
11. Chen, W.; Chen, S. Oxygen Electroreduction Catalyzed by Gold Nanoclusters: Strong Core Size Effects Angew. Chem., Int. Ed. 2009, 48, 4386-4389
12. - Cluster to Charge Neutral Cluster via Air Oxidation J. Phys. Chem. C 2008, 112, 14221-14224
13. Lopez-Acevedo, O.; Kacprzak, K. A.; Akola, J.; Häkkinen, H. Quantum Size Effects in Ambient CO Oxidation Catalysed by Ligand-Protected Gold Clusters Nat. Chem. 2010, 2, 329-334
14. 35) for CO Oxidation ACS Nano 2011, 5, 7818-7829
15. Staykov, A.; Nishimi, T.; Yoshizawa, K.; Ishihara, T. Oxygen Activation on Nanometer-Size Gold Nanoparticles J. Phys. Chem. C 2012, 116, 15992-16000
16. Liu, Y.; Tsunoyama, H.; Akita, T.; Xie, S.; Tsukuda, T. Aerobic Oxidation of Cyclohexane Catalyzed by Size-Controlled Au Clusters on Hydroxyapatite: Size Effect in the sub-2 nm Regime ACS Catal. 2011, 1, 2-6
17. 25 Clusters on Hydroxyapatite Chem. Commun. 2010, 46, 550-552
18. 25 J. Am. Chem. Soc. 2008, 130, 3756-3757
19. 18 J. Am. Chem. Soc. 2007, 129, 11322-11323
20. 18 Nanoclusters Probed by NMR and Optical Spectroscopy ACS Nano 2009, 3, 2036-2042
21. 18 Leading to Functionalized Gold Clusters: Spectroscopy, Kinetics, and Luminescence J. Phys. Chem. C 2008, 112, 12168-12176
22. Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesides, G. M. Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology Chem. Rev. 2005, 105, 1103-1170
23. Zhu, Y.; Qian, H.; Jin, R. Catalysis Opportunities of Atomically Precise Gold Nanoclusters J. Mater. Chem. 2011, 21, 6793-6799
24. 3) J. Phys. Chem. Lett. 2010, 1, 2594-2599
25. 38 clusters J. Phys. Chem. Lett. 2011, 2, 2752-2758
26. q Nanoclusters: Effects of Charge State J. Phys. Chem. C 2010, 114, 19935-19940
27. 38 Nanoparticles J. Am. Chem. Soc. 2004, 126, 6193-6199
28. 140 Quantum dots J. Phys. Chem. B 2006, 110, 20282-20289
29. 1- Nanoparticles with Metal Ions J. Phys. Chem. C 2010, 114, 15890-15896
30. Wu, Z.; Jin, R. On the Ligand's Role in the Fluorescence of Gold Nanoclusters Nano Lett. 2010, 10, 2568-2573
31. + Clusters J. Am. Chem. Soc. 2012, 134, 15205-15208
32. 25 Clusters J. Phys. Chem. C 2010, 114, 22417-22423
33. 25 Nanoclusters J. Phys. Chem. C 2012, 116, 19032-19038
34. 25 Cluster by Ag Doping Chem. Commun. 2010, 46, 4713-4715
35. + and Oxoammonium Cations J. Phys. Chem. Lett. 2011, 2, 2104-2109
36. z Clusters Anal. Chem. 2011, 83, 6355-6362
37. Franceschetti, A.; Zunger, A. Pseudopotential Calculations of Electron and Hole Addition Spectra of InAS, InP, and Si Quantum Dots Phys. Rev. B 2000, 62, 2614-2623
38. Connelly, N. G.; Geiger, W. E. Chemical Redox Agents for Organometallic Chemistry Chem. Rev. 1996, 96, 877-910
39. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2 nd ed.; John Wiley & Sons: New York, 2001.
40. Laoire, C. O.; Mukerjee, S.; Abraham, K. M.; Plichta, E. J.; Hendrickson, M. A. Influence of Nonaqueous Solvents on the Electrochemistry of Oxygen in the Rechargeable Lithium-Air Battery J. Phys. Chem. C 2010, 114, 9178-9186
41. Marković, N. M.; Schmidt, T. J.; Stamenković, V.; Ross, P. N. Oxygen Reduction Reaction on Pt and Pt Bimetallic Surfaces: A Selective Review Fuel Cells 2001, 1, 105-116
42. 2 Electrodes Adv. Mater. 2010, 22, 3185-3188
43. Negishi, Y.; Nobusada, K.; Tsukuda, T. Glutathione-Protected Gold Clusters Revisited: Bridging the Gap between Gold(I)-Thiolate Complexes and Thiolate-Protected Gold Nanocrystals J. Am. Chem. Soc. 2005, 127, 5261-5270
44. Wilkinson, F. Quenching of Electronically Excited States by Molecular Oxygen Pure Appl. Chem. 1997, 69, 851-856
45. DeRosa, M. C.; Crutchley, R. J. Photosensitized Singlet Oxygen and its Applications Coord. Chem. Rev. 2002, 233-234, 351-371
46. Ijeri, V. S.; Daasbjerg, K.; Ogilby, P. R.; Poulsen, L. Spacial and Temporal Electrochemical Control of Singlet Oxygen Production and Decay in Photosensitized Experiments Langmuir 2008, 24, 1070-1079
47. Smith, W. H.; Bard, A. J. Electrochemical Reactions of Organic Compounds in Liquid Ammonia. III. Reductive Alkylation of Quinoline J. Am. Chem. Soc. 1975, 97, 6491-6495