Homo-Diels-Alder reaction of a very inactive diene, bicyclo[2,2,1]hepta-2, 5-diene, with the most active dienophile, 4-phenyl-1,2,4-triazolin-3,5-dione. Solvent, temperature, and high pressure influence on the reaction rate

Journal of Physical Organic Chemistry

Volumn 26, Issue 1, 2013, Pages 47-53

  Kiselev, Vladimir D ^a   Shakirova, Ilzida I ^a   Kornilov, Dmitry A ^a   Kashaeva, Helen A ^a   Potapova, Lubov N ^a   Konovalov, Alexander I ^a  

^a KAZAN FEDERAL UNIVERSITY   (Russian Federation)

Author keywords

4 phenyl 1,2,4 triazolin 3,5 dione; activation volume; bicyclo 2,2,1 hepta 2,5 diene; heat of reaction; homo Diels Alder reaction; rate constants; reaction volume

Indexed keywords

4-PHENYL-1,2,4- TRIAZOLIN-3,5-DIONE; ACTIVATION VOLUME; BICYCLO[2,2,1]HEPTA-2,5-DIENE; HEAT OF REACTION; HOMO-DIELS-ALDER REACTION; REACTION VOLUME;

BUTADIENE; CYCLOADDITION; HIGH PRESSURE EFFECTS; MALEIC ANHYDRIDE; RATE CONSTANTS; SOLVENTS; THERMOCHEMISTRY; TOLUENE;

OLEFINS;

EID: 84872135288     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.3054     Document Type: Article

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