Why can the activation volume of the cycloadduct decomposition in isopolar retro-diels-alder reactions be negative?

International Journal of Chemical Kinetics

Volumn 42, Issue 2, 2010, Pages 117-125

  Kiselev, Vladimir D ^a  

^a KAZAN FEDERAL UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

9-CHLOROANTHRACENE; ACTIVATION VOLUME; BRANCHED STRUCTURES; CYCLOADDUCTS; DIELS-ALDER CYCLOADDITIONS; DIELS-ALDER REACTION; ENTHALPY OF SOLUTION; ENTROPY OF ACTIVATION; NEGATIVE VALUES; RETRO-DIELS-ALDER REACTIONS; SOLVENT MOLECULES; TETRACYANOETHYLENE; TRANSITION STATE;

CYCLOADDITION; ENTHALPY; PRESSURE EFFECTS;

RATE CONSTANTS;

EID: 76349091378     PISSN: 05388066     EISSN: 10974601     Source Type: Journal    
DOI: 10.1002/kin.20462     Document Type: Article

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