Thermal curing and degradation mechanism of polyhedral oligomeric octa(propargylaminophenyl)silsesquioxane

Polymer Degradation and Stability

Volumn 98, Issue 1, 2013, Pages 281-287

  Fan, Haibo ^a   Li, Xiangmei ^a   Liu, Yanlin ^a   Yang, Rongjie ^a  

^a BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

Author keywords

Curing; Degradation; Mechanism; Octa(propargylaminophenyl)silsesquioxane

Indexed keywords

CONTROLLED TEMPERATURE; DECOMPOSITION PRODUCTS; DEGRADATION MECHANISM; DEGRADATION PRODUCTS; INERT ATMOSPHERES; PHENYL GROUP; SECONDARY AMINES; SILSESQUIOXANES; SIX-MEMBERED RINGS; THERMAL CURING; THERMAL OXIDATIVE DEGRADATION; XRD;

ACETYLENE; DEGRADATION; MECHANISMS; OLEFINS; OLIGOMERS; ORGANIC COMPOUNDS;

CURING;

EID: 84871906103     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2012.09.015     Document Type: Article

References (27)

1. P.D. Lickiss, and F. Rataboul Advances in organometallic chemistry Adv Organomet Chem 57 2008 1
2. Q. Li, Y. Zhou, X.D. Huang, S.F. Deng, F.R. Huang, and L. Du Synthesis and characterization of a novel arylacetylene oligomer containing POSS units in main chains Eur Polym J 44 2008 2538
3. D.B. Cordes, P.D. Liickiss, and F. Rataboul Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes Chem Rev 110 2010 2081
4. M. Ak, B. Gacal, B. Kiskan, Y. Yagci, and L. Toppare Enhancing electrochromic properties of polypyrrole by silsesquioxane nanocages Polymer 49 2008 2202
5. V. Ervithayasuporn, X. Wang, B. Gacal, and B.N. Gacal Formation of trimethylsilylated open-cage oligomeric azidophenylsilsesquioxanes J Organomet Chem 696 2011 2193
6. J. Zhang, R.W. Xu, and D.S. Yu A novel poly-benzoxazinyl functionalized polyhedral oligomeric silsesquioxane and its nanocomposite with polybenzoxazine Eur Polym J 43 2007 743
7. J. Chol, R. Tamaki, S.G. Kim, and R.M. Laine Organic/inorganic imide nanocomposites from aminophenylsilsesquioxanes Chem Mater 15 2003 3365
8. W.A. Zhang, and A.H.E. Muller A "click chemistry" approach to linear and star-shaped telechelic POSS-containing hybrid polymers Macromolecules 43 2010 3148
9. A. Fina, D. Tabuani, F. Camiato, A. Frache, E. Boccaleri, and G. Camino Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation Thermochim Acta 440 2006 36
10. S. Lu, and I. Hamerton Recent developments in the chemistry of halogen-free flame retardant polymers Prog Polym Sci 27 2002 1661
11. Y.Y. Jiang, X.M. Li, and R.J. Yang Polycarbonate composites flame-retarded by polyphenylsilsesquioxane of ladder structure J Appl Polym Sci 124 2012 4381
12. Y.Y. Jiang, X. Zhang, J.Y. He, X.M. Li, and R.J. Yang Effect of polyphenylsilsesquioxane on the ablative and flame-retardation properties of ethylene propylene diene monomer (EPDM) composite Polym Degrad Stab 96 2011 949
13. W.C. Zhang, X.M. Li, and R.J. Yang Novel flame retardancy effects of DOPO-POSS on epoxy resins Polym Degrad Stab 96 2011 2167
14. W.C. Zhang, X.M. Li, and R.J. Yang Pyrolysis and fire behaviour of epoxy resin composites based on a phosphorus-containing polyhedral oligomeric silsesquioxane (DOPO-POSS) Polym Degrad Stab 96 2011 1821
15. C. Bolln, A. Tsuchida, H. Frey, and R.M. Ulhaupt Thermal properties of the homologous series of 8-fold alkyl-substituted octasilsesquioxanes Chem Mater 9 1997 1475
16. R.A. Mantz, P.F. Jones, K.P. Chaffee, J.D. Lichtenhan, and J.W. Gilman Thermolysis of polyhedral oligomeric silsesquioxane (POSS) macromers and POSS-siloxane copolymers Chem Mater 8 1996 1250
17. J. Zeng, C. Bennett, W.L. Jarrett, S. Iyer, S. Kumar, and L.J. Mathias Structural changes in trisilanol POSS during nanocomposite melt processing Compos Interfac 11 2005 673
18. A. Fina, D. Tabuani, A. Frache, E. Boccaleri, and G. Camino Fire retardancy of polymers: new applications of mineral fillers 2005 Royal Society of Chemistry Cambridge, UK p. 202-20
19. H.B. Fan, J.Y. He, and R.J. Yang Synthesis, characterization, and thermal curing of a novel polyhedral oligomeric octa(propargylaminophenyl) silsesquioxane J Appl Polym Sci 2012 10.1002/APP.37734
20. H.B. Fan, D.H. Li, and R.J. Yang Synthesis improvement and characterization of polyhedral oligomeric octa(aminophenyl)silsesquioxane Acta Chim Sinica 70 4 2012 429
21. Fan HB, Yang RJ, Li XM. Purity analysis of polyhedral oligomeric octa(nitrophenyl)silsesquioxane. Acta Chim Sinica http://dx.doi.org/10.6023/ a12030047.
22. H.B. Fan, and R.J. Yang Synthesis and characterization of polyhedral oligomeric azido-cctaphenylsilsesquioxane J Appl Polym Sci 124 2012 4389
23. C. Simionescu, V. Percec, and S. Dumitrescu Polymerization of acetylenic derivatives J Polym Sci Polym Chem Ed 15 1977 2497
24. M.D. Sefcik, E.O. Stejskal, and R.A. Mckay Schaefer. Investigation of the structure of acetylene-terminated polyimide resins using magic-angle carbon-13 nuclear magnetic resonance Macromolecules 12 3 1979 423
25. X.W. Ding, H.M. Qi, Y.Q. Zhuang, and J. Wang Curing kinetics and structure characterization of arylacetylene polymer J East China Univ Sci Technol 27 2 2001 161
26. N. Shanmugam, A. Muthukaruppan, and H. Ian Octasilsesquioxane-reinforced DGEBA and TGDDM epoxy nanocomposites: characterization of thermal, dielectric and morphological properties Acta Mater 58 2010 3345
27. L. Song, Q.L. He, Y. Hu, H. Chen, and L. Liu Study on thermal degradation and combustion behaviors of PC/POSS hybrids Polym Degrad Stab 93 2008 627