Application of a stereoselective rhodium(II)-catalyzed oxonium ylide formation-[2,3]-sigmatropic rearrangement of an α-diazo-β-keto ester to the synthesis of 2-epi-cinatrin C1 dimethyl ester

Synlett

Volumn 24, Issue 1, 2013, Pages 65-68

  Yakura, Takayuki ^a   Ozono, Ayaka ^a   Matsui, Katsuaki ^a   Yamashita, Masayuki ^b   Fujiwara, Tomoya ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

^b KYOTO PHARMACEUTICAL UNIVERSITY   (Japan)

Author keywords

2,3 sigmatropic rearrangement; cinatrin; diazoketo ester; oxonium ylide; rhodium(II) catalyst

Indexed keywords

2 EPI CINATRIN C1 DIMETHYL ESTER; ALPHA DIAZO BETA KETO ESTER; CATION; ESTER DERIVATIVE; GLUCOSE; NATURAL PRODUCT; OXONIUM YLIDE; RHODIUM; UNCLASSIFIED DRUG;

[2,3] SIGMATROPIC REARRANGEMENT; ARTICLE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; DRUG SYNTHESIS; PHYSICAL CHEMISTRY; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 84871722359     PISSN: 09365214     EISSN: 14372096     Source Type: Journal    
DOI: 10.1055/s-0032-1317694     Document Type: Article

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