Removal of Cs from simulated high-level waste solutions by extraction using chlorinated cobaltdicarbollide in a mixture of nitrobenzene and xylene

Journal of Radioanalytical and Nuclear Chemistry

Volumn 291, Issue 3, 2012, Pages 611-616

  Murali, M S ^a   Raut, D R ^a   Prabhu, D R ^a   Mohapatra, P K ^a   Tomar, B S ^a   Manchanda, V K ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

CCD; Characterization; Cs; Dielectric constant; Gamma dose; HLW

Indexed keywords

EID: 84871457915     PISSN: 02365731     EISSN: 15882780     Source Type: Journal    
DOI: 10.1007/s10967-011-1460-9     Document Type: Article

References (41)

1. Handley TH, Burros CL (1959) Determination of radioactive cesium. Anal Chem 31: 332-334
2. Popov L, Kuleff I, Djingova R (2006) Determination of radiocesium in environmental water samples using copper ferro(II)cyanide, sodium tetraphenylborate. J Radioanal Nucl Chem 269: 203-207
3. Rais J, Selucky P, Kyrs M (1976) Extraction of alkali metals into nitrobenzene in the presence of univalent polyhedral borate anions. J Inorg Nucl Chem 38: 1376-1378
4. 137Cs into nitrobenzene by cobalt dicarbolide. Radiochem Radioanal Lett 34: 23-28
5. Selucky P, Vanura P, Rais J, Kyrs M (1979) A rapid method for the separation of 90Sr for its determination in a mixture with longlived fission products. Radiochem Radioanal Lett 38: 297-302
6. 137Cs by cobalt dicarbolide. J Radioanal Chem 51: 245-252
7. 137Cs isolation from biological material. Radiochem Radioanal Lett 39: 75-86
8. 2+ from a mixture of cation forming stable non-extractable complexes with ethylenediamine N, N, N′, N′-tetra acetic acid in the water-nitrobenzene system. J Radioanal Nucl Chem 92: 71-77
9. Makrlik E, Vanura P (1985) Applications of the dicarbollylcobaltate( III) anion in the water/nitrobenzene extraction system. Talanta 32: 423-429
10. 3 solutions: a technology review and assessment. Sep Sci Technol 22: 191-214
11. Law JD, Herbst RS, Peterman DR, Tillotson RD, Todd TA (2004) Development of a cobalt dicarbollide/polyethylene glycol solvent extraction process for separation of cesium, strontium to support advanced aqueous reprocessing. Nucl Technol 147: 284-290
12. Kumar A, Mohapatra PK, Manchanda VK (1998) Extraction of cesium-137 from nitric acid medium in the presence of macrocyclic polyethers. J Radioanal Nucl Chem 229: 169-172
13. Ungaro R, Casnati A, Ugozzoli F, Pochini A, Dozol J-F, Hill C, Rouquette H (1994) 1.3-Dialkoxycalix[4]arenecrown-6 in 1, 3- alternate conformation: cesium-selective ligands that exploit cation-arene interactions. Angew Chem Int Ed Engl 33: 1506
14. Raut DR, Mohapatra PK, Ansari SA, Manchanda VK (2009) Use of Calix[4]-bis-2, 3-naphthocrown-6 for separation of cesium from pressurized heavy water reactor simulated high level waste solutions (PHWR-SHLW). Sep Sci Technol 44: 3664-3678
15. Miller RL, Pinkerton AB, Hurlburt PK, Abney KD (1995) Extraction of Cs, Sr into hydrocarbon solvent using-tetra-cobalt dicarbolide. Solvent Extr Ion Exch 13: 813-827
16. Samanta SK, Ramaswamy M (1992) Studies on cesium uptake by phenolic resins. Sep Sci Technol 27: 255-267
17. Zhang A, Kuraoka E, Kumagai M (2007) Development of the chromatographic partitioning of cesium, strontium utilizing two macroporous silica-based calix[4]arene-crown, amide impregnated polymeric composites: PREC partitioning process. J Chromatogr A 1157: 85-95
18. Zhang A, Wei Y, Hoshi H, Koma Y, Kamiya M (2007) Partitioning of cesium from a simulated high level liquid waste by extraction chromatography utilizing a macroporous silica-based supramolecular calix[4]arene-crown impregnated polymeric composite. Solvent Extr Ion Exch 25: 389-405
19. Raut DR, Mohapatra PK, Ansari SA, Manchanda VK (2008) Evaluation of a calix[4]-bis-crown-6 ionophore for selective Cs- 137 transport across liquid membrane from acidic feeds. J Membr Sci 310: 229-236
20. Kandwal P, Mohapatra PK, Ansari SA, Manchanda VK (2010) Selective cesium transport using hollow fiber supported liquid membrane containing calix[4]arene-bis-napthocrown-6 as the carrier extractant. Radiochim Acta 98: 493-498
21. Asfari Z, Bressot C, Vicens J, Hill C, Dozol J-F, Rouquette H, Eymard S, Lamare V, Tournois B (1995) Doubly crowned calix[4]arenas in the 1, 3-alternate conformation as cesium selective carriers in supported liquid membranes. Anal Chem 67: 3133-3139
22. Smit J van R (1961) The AMP process for cesium separation. I. Adsorption of cesium on ammonium 12-molybdophosphate, Report AERE-R-3884, AERE, Harwell
23. 137Cs from acidic nuclear waste solutions. Adv Environ Res 6: 107-121 and the references therein
24. Mimura H, Wu Y, Yufei W, Nilbori Y, Yamagishi I, Ozawa M, Ohnishi T, Koyama S (2011) Selective separation and recovery of cesium by ammonium tungstophosphate-alginate micro capsules. Nucl Eng Des (in press), and references therein
25. Makrlik E, Vanura P, Selucky P (2011) Individual extraction constants of some univalent cations in the two-phase watermethyltrifluoro sulfone system. J Radioanal Nucl Chem 288: 177-180
26. Romanovsky VN (2002) Radium institute research on actinide separation from high-level waste. J Nucl Sci Technol Suppl 3: 8-13
27. Herbst RS, Law JD, Todd TA (2002) Universal solvent extraction (UNEX) flowsheet testing for the removal of cesium, strontium, actinide elements from radioactive, acidic dissolved waste. Solvent Extr Ion Exch 20: 429-445
28. Herbst RS, Peterman DR, Tillotson RD, Delmau LH (2008) Fundamental chemistry of cesium extraction from acidic media by HCCD in FS-13. Solvent Extr Ion Exch 26: 163-174 and the references therein
29. Mason CFV, Reilly SD, Smith PH (1990) Cobalt (III) Dicarbollide, a potential Cs-137 and Sr-90 waste extraction agent. Report LA-11695, Los Alamos, N.Mex.: Los Alamos National Laboratory, USA.
30. Makrlik E, Vanura P, Selucky P (2011) Solvent extraction of cesium into nitrobenzene by using sodium, potassium, rubidium dicarbollylcobaltates in the presence of polypropyleneglycol PPG425. J Radioanal Chem 288: 429-433
31. Makrlik E, Vanura P, Selucky P (2011) Solvent extraction of Cs into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and polypropyleneglycol PPG-425. J Radloanal Nucl Chem 287: 981-985
32. Makrlik E, Vanura P, Selucky P (2009) Solvent extraction of Cs into nitrobenzene by using ammonium and thallium dicarbollylcobaltates in the presence of 2, 3 naphtho-15-Crown-5. J Radloanal Nucl Chem 281: 547-551
33. Manosso HC (2009) Deoforbicini, treatment of wastes containing cesium ion by electrochemical ion-exchange (EIX). J Radioanal Nucl Chem 279: 417-422
34. Chaltikyan V, Papoyan A, Oshita H, Shiotani H, Ono K et al (2009) Perspectives of laser-chemical isotope separation of a long-lived fission product Cs-135. J Radioanal Chem 280: 343-352
35. 60Co from aqueous solution by titanosilicate: a radio tracer study. J Radioanal Nucl Chem 285: 483-489
36. Khanchi AR, Yavari R, Pourazarsa SK (2007) Preparation, evaluation of composite ion-exchanger for the removal of cesium, strontium radioisotopes. J Radioanal Nucl Chem 273: 141-145
37. Grunder M, Dozol AF, Asfari Z, Vicens J (1999) Simultaneous removal of technetium, cesium by functionalized calixarenes from acidic liquid waste. J Radioanal Nucl Chem 241: 59-61
38. 2 solution. J Radioanal Nucl Chem 284: 387-395
39. Makrlik E, Vanura P, Selucky P (2010) Extraction of Cs into phenyltrifluoromethyl sulfone by using hydrogen dicarbollylcobaltate in the presence of polyethyleneglycol PEG 400. J Radioanal Nucl Chem 286: 295-298
40. Banerjee D, Rao MA, Gabriel J, Samanta SK (2008) Recovery of purified radiocesium from acidic solution using ammonium molybdophosphate, resorcinol formaldehyde plycondensate resin. Desalination 232: 172-180
41. Abdul AS, Gibson TL, Rai DN (1990) Laboratory studies of the flow of some organic solvents, their aqueous solutions through bentonite, kaolin clays. Ground Water 28: 524-533