Adsorption geometry of CO versus coverage on TiO2(110) from s- and p-polarized infrared spectroscopy

Journal of Physical Chemistry Letters

Volumn 3, Issue 23, 2012, Pages 3425-3430

  Petrik, Nikolay G ^a   Kimmel, Greg A ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION GEOMETRIES; BONDING GEOMETRY; CO COVERAGE; CO MOLECULE; DIELECTRIC SUBSTRATES; INFRARED REFLECTION ABSORPTION SPECTROSCOPY; LIGHT INCIDENT; P-POLARIZED; REFLECTION-ABSORPTION; RUTILE TIO; TIO;

GEOMETRY; INFRARED SPECTROSCOPY; OXIDE MINERALS; REACTION KINETICS; TEMPERATURE PROGRAMMED DESORPTION; TITANIUM DIOXIDE;

ADSORPTION;

EID: 84870801590     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz301413v     Document Type: Article

References (29)

1. 2 Photocatalysis Surf. Sci. Rep. 2011, 66, 185-297
2. 2 Photocatalysis and Related Surface Phenomena Surf. Sci. Rep. 2008, 63, 515-582
3. 2(110) Chem. Phys. Lett. 1997, 269, 485-488
4. 2(110) J. Phys. Chem. B 1999, 103, 203-208
5. 2(110) Surfaces J. Phys. Chem. C 2010, 114, 19419-19424
6. 2(110) J. Phys. Chem. C 2009, 113, 17471-17478
7. 2(110) J. Am. Chem. Soc. 2009, 131, 980-984
8. 2(101): A Photoemission and NEXAFS Spectroscopy Study Langmuir 2010, 26, 14548-14555
9. 2(110) J. Am. Chem. Soc. 2009, 131, 17926-17932
10. 2(110) Surf. Sci. 2001, 471, 163-169
11. Rohmann, C.; Wang, Y. M.; Muhler, M.; Metson, J.; Idriss, H.; Woüll, C. Direct Monitoring of Photo-induced Reactions on Well-defined Metal Oxide Surfaces Using Vibrational Spectroscopy Chem. Phys. Lett. 2008, 460, 10-12
12. 2(110): A Combined Experimental and Theoretical Study J. Chem. Phys. 2009, 130, 144703
13. 2(110): Anisotropy and the Hydrogen-Bonding Network J. Phys. Chem. Lett. 2012, 3, 778-784
14. Wang, Y. M.; Woüll, C. Chemical Reactions on Metal Oxide Surfaces Investigated by Vibrational Spectroscopy Surf. Sci. 2009, 603, 1589-1599
15. 2(110): A Key Parameter for Theoretical Understanding Phys. Rev. Lett. 2005, 95, 226104
16. Xu, M.; Noei, H.; Fink, K.; Muhler, M.; Wang, Y.; Woüll, C. The Surface Science Approach for Understanding Reactions on Oxide Powders: The Importance of IR Spectroscopy Angew. Chem., Int. Ed. 2012, 51, 4731-4734
17. Over, H. Crystallographic Study of Interaction Between Adspecies on Metal Surfaces Prog. Surf. Sci. 1998, 58, 249-376
18. 2(110): The Role of Surface Oxygen Vacancies J. Chem. Phys. 2004, 120, 4512-4516
19. 2(110) Surf. Sci. 2003, 524, 49-62
20. 2O: Structures, Energies, Thermodynamics, and Dynamics from PBE+U Phys. Rev. B 2011, 84, 035413
21. 2(110) Surface: A Theoretical Study J. Phys. Chem. B 1998, 102, 4556-4565
22. 2(110): A First Principles Study J. Chem. Phys. 2006, 125, 144706
23. 2(110) Chem. Phys. Lett. 2011, 513, 212-217
24. 2(110)-1 × 1 Surface? J. Am. Chem. Soc. 2009, 131, 7958-7959
25. 2(110) J. Phys. Chem. B 2006, 110, 6229-6235
26. 2 J. Chem. Phys. 1990, 92, 7498
27. Redhead, P. A. Thermal Desorption of Gases Vacuum 1962, 12, 203
28. Richter, L. J.; Buntin, S. A.; Chu, P. M.; Cavanagh, R. R. Adsorption and Photodecomposition of MO(CO)(6) on SI(111) 7 × 7-An Infrared Reflection-Absorption Spectroscopy Study J. Chem. Phys. 1994, 100, 3187-3200
29. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229