Influence of H2O on the low-temperature NH3-SCR of NO over V2O5/AC catalyst: An experimental and modeling study

Chemical Engineering Journal

Volumn 215-216, Issue , 2013, Pages 651-657

  Lei, Zhigang ^a   Han, Bin ^a   Yang, Kun ^a   Chen, Biaohua ^a  

^a BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

Mathematical model; Reaction kinetics; Reaction mechanism; Selective Catalytic Reduction (SCR); V2O5 AC catalyst

Indexed keywords

ELEY-RIDEAL MECHANISM; EMPIRICAL MODEL; INTRINSIC KINETICS; KINETIC MEASUREMENT; LANGMUIR-HINSHELWOOD; LOW TEMPERATURES; MARS-VAN KREVELEN; MODELING STUDIES; MONOLITHIC REACTOR; PREEXPONENTIAL FACTOR; REACTION MECHANISM; REACTOR DESIGNS; SCALE-UP; SCR OF NO; VANADIUM PENTOXIDE;

ACTIVATED CARBON; ACTIVATION ENERGY; CATALYSTS; KINETICS; MATHEMATICAL MODELS; NITRIC OXIDE; REACTION KINETICS; REACTION RATES; VANADIUM COMPOUNDS;

SELECTIVE CATALYTIC REDUCTION;

EID: 84870685665     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2012.11.011     Document Type: Article

References (40)

1. Lu P., Li C.T., Zeng G.M., Peng D.L., Cui H.F., Li S.H., Zhai Y.B. Low temperature selective catalytic reduction of NO by activated carbon fiber loading lanthanum oxide and ceria. Appl. Catal., B: Environ. 2010, 96(1-2):157-161.
2. 3 over mordenite-type zeolite catalysts. Catal. Today 1997, 38(2):181-186.
3. 3. Chem. Eng. J. 2009, 149(1-3):173-182.
4. x with ammonia. Environ. Sci. Technol. 2010, 44(5):1799-1805.
5. 3. Ind. Eng. Chem. Res. 1996, 35(8):2516-2521.
6. x: mechanistic perspectives on the role of base metal and noble metal ion substitution. Ind. Eng. Chem. Res. 2008, 47(23):9240-9247.
7. Koebel M., Elsener M. Selective catalytic reduction of NO over commercial DeNOx-catalysts: experimental determination of kinetic and thermodynamic parameters. Chem. Eng. Sci. 1998, 53(4):657-669.
8. Bosch H., Janssen F. Formation and control of nitrogen oxides. Catal. Today 1988, 2(4):369-379.
9. 2 traces in the gas feed. Appl. Catal., B: Environ. 2006, 66(3-4):281-287.
10. 3 at low temperatures. J. Catal. 1999, 187(1):245-248.
11. 5 catalyst surface. Catal. Today 2006, 118(3-4):268-278.
12. 5 catalyst. Appl. Catal., B: Environ. 2002, 36(4):325-332.
13. 2-supported vanadia-tungsta commercial catalyst. Catal. Today 2000, 60(1-2):73-82.
14. Lin C.H., Bai H. Surface acidity over vanadia/titania catalyst in the selective catalytic reduction for NO removal-in situ DRIFTS study. Appl. Catal., B: Environ. 2003, 42(3):279-287.
15. 3 over vanadium oxide supported on carbon-ceramic cellular monoliths. Ind. Eng. Chem. Res. 2004, 43(10):2349-2355.
16. 3 over carbon modified by acid oxidation and by metal impression and its kinetic studies. Appl. Catal., B: Environ. 2001, 35(1):21-30.
17. 5/AC catalyst. Ind. Eng. Chem. Res. 2011, 50(9):5360-5368.
18. 3 at lower temperatures. Appl. Catal., B: Environ. 2002, 39(4):361-368.
19. 2 pillared clay catalysts. Appl. Catal., B: Environ. 2000, 24(1):13-21.
20. 3 catalyst. Catal. Today 2009, 147S:S285-S289.
21. 3 at low temperature. Appl. Catal., B: Environ. 1999, 23(4):229-233.
22. 3 over activated carbon-supported vanadium oxide catalyst. J. Catal. 2001, 197(1):6-16.
23. 3-SCR of NO at low temperature over carbon-coated monoliths. J. Catal. 2005, 233(1):166-175.
24. X by ammonia over oxide catalysts: a review. Appl. Catal., B: Environ. 1998, 18(1-2):1-36.
25. 2 under the dilute gas condition. J. Catal. 1980, 62(1):140-148.
26. 3 over supported vanadia catalysts. J. Catal. 1996, 161(1):211-221.
27. 2. Appl. Catal., B: Environ. 2004, 53(1):29-36.
28. 3. Ind. Eng. Chem. Res. 2000, 39(6):1781-1787.
29. Lintz H.G., Turek T. Intrinsic kinetics of nitric oxide reduction by ammonia on vanadia-titania catalyst. Appl. Catal., A: Gen. 1992, 85(1):13-25.
30. Tronconi E. Interaction between chemical kinetics and transport phenomena in monolithic catalysts. Catal. Today 1997, 34(3-4):421-427.
31. 2. J. Catal. 1996, 161(1):247-253.
32. Press W.H., Flannery B.P., Teukolsky S.A., Vetterling W.T. Numerical Recipes in FORTRAN: The Art of Scientific Computing 1992, Cambridge University Press, Cambridge, England. second ed.
33. 3 species: SCR mechanism. J. Catal. 2004, 226(1):138-155.
34. 3 over vanadia/titania-based catalysts. Ind. Eng. Chem. Res. 1998, 37(12):4577-4590.
35. Liu L.S., Liu Z.Y., Huang Z.G., Liu Z.H., Liu P.G. Preparation of activated carbon honeycomb monolith directly from coal. Carbon 2006, 44(8):1581-1616.
36. x: a mathematical model for design of catalyst and reactor. Chem. Eng. Sci. 1996, 47(9-11):2401-2406.
37. Bhattacharya M., Harold M.P., Balakotaiah V. Shape normalization for catalytic monolith. Chem. Eng. Sci. 2004, 59(18):3737-3766.
38. Bhattacharya M., Harold M.P., Balakotaiah V. Mass transfer coefficients in washcoated monoliths. AIChE J. 2004, 50(11):2939-2955.
39. Chilton N., Jack N.L., Wayne E.M., Ramu M.R. Physical and chemical properties of selected agricultural byproduct-based activated carbons and their ability to adsorb geosmin. Bioresour. Technol. 2002, 84(2):177-185.
40. Wang L.W., Tamainot-Telto Z., Thorpe R., Critoph R.E., Metcalf S.J., Wang R.Z. Study of thermal conductivity, permeability, and adsorption performance of consolidated composite activated carbon adsorbent for refrigeration. Renew. Energy 2011, 36(8):2062-2066.