Effects of three-dimensional cathode microstructure on the performance of lithium-ion battery cathodes

Electrochimica Acta

Volumn 88, Issue , 2013, Pages 580-588

  Wiedemann, Andreas H ^a   Goldin, Graham M ^b   Barnett, Scott A ^c   Zhu, Huayang ^a   Kee, Robert J ^a  

^a Department of Metallurgical and Materials Engineering   (United States)

^b ANSYS INC   (United States)

^c Northwestern University   (United States)

Author keywords

Cathode microstructure; Li ion battery; Three dimensional model

Indexed keywords

CATHODE MICROSTRUCTURE; COMPUTATIONAL MODEL; COMPUTATIONAL SIMULATION; DISCHARGE CHARACTERISTICS; DISCHARGE RATES; DISCRETIZATIONS; ELECTRODE MATERIAL; ELECTRODE STRUCTURE; ELECTROSTATIC POTENTIALS; FINITE-VOLUME; LI-ION BATTERIES; LITHIUM-ION BATTERY CATHODES; MICROSTRUCTURAL GEOMETRY; SOLID-PHASE; SPATIAL VARIATIONS; SPHERICAL ELECTRODES; THREE-DIMENSIONAL MICROSTRUCTURES; THREE-DIMENSIONAL MODEL;

CATHODES; ELECTRIC DISCHARGES; ELECTROCHEMICAL CELLS; EXPERIMENTS; LITHIUM COMPOUNDS; MICROSTRUCTURE; THREE DIMENSIONAL COMPUTER GRAPHICS;

THREE DIMENSIONAL;

EID: 84870658563     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2012.10.104     Document Type: Article

References (26)

1. M. Doyle, and J. Newman The use of mathematical modeling in the design of lithium/polymer battery systems Electrochimica Acta 40 1993 2191
2. M. Doyle, T.F. Fuller, and J. Newman Modeling of galvanostatic charge and discharge of the lithium/polymer/insertion cell Journal of the Electrochemical Society 140 1993 1526
3. J. Newman, and K.E. Thomas-Alyea Electrochemical Systems 2004 John Wiley and Sons
4. A.M. Colclasure, and R.J. Kee Thermodynamically consistent modeling of elementary electrochemistry in lithium-ion batteries Electrochimica Acta 55 2010 8960
5. C.W. Wang, and A.M. Sastry Mesoscale modeling of a Li-ion polymer cell Journal of the Electrochemical Society 154 2007 A1035
6. R.E. Garcia, and Y.M. Chiang Spatially resolved modeling of microstructurally complex battery architectures Journal of the Electrochemical Society 154 2007 A856
7. G.M. Goldin, A.M. Colclasure, A.H. Wiedemann, and R.J. Kee Three-dimensional particle-resolved models of Li-ion batteries to assist the evaluation of empirical parameters in one-dimensional models Electrochimica Acta 64 2012 118
8. 2 positive electrode Journal of Power Sources 196 2011 3443
9. J. Joos, T. Carraro, A. Weber, and E. Ivers-Tiffé Reconstruction of porous electrodes by FIB/SEM for detailed microstructure modeling Journal of Power Sources 196 2011 7302
10. M. Ender, J. Joos, T. Carraro, and E. Ivers-Tiffé Three-dimensional reconstruction of a composite cathode for lithium-ion cells Electrochemistry Communications 13 2011 166
11. 2 Li-ion battery cathode Electrochemical and Solid-State Letters 15 2012 A33
12. P.R. Shearing, L.E. Howard, P.S. Jørgensen, N.P. Brandon, and S.J. Harris Characterization of the 3-dimensional microstructure of a graphite negative electrode from a Li-ion battery Electrochemistry Communications 12 2010 374
13. 2-based rocking-chair rechargeable batteries Journal of the Electrochemical Society 156 2009 A896
14. 4 electrode via particle-scale modeling Journal of the Electrochemical Society 158 2011 A487
15. 4 spinel particles Journal of the Electrochemical Society 158 2011 A371
16. G.B. Less, J.H. Seo, S. Han, A.M. Sastry, J. Zausch, A. Latz, S. Schmidt, C. Wiesner, D. Kehrwald, and S. Fell Micro-scale modeling of Li-ion batteries: parameterization and validation Journal of the Electrochemical Society 159 2012 A697
17. B. Vijayaraghavan, D.R. Ely, Y.-M. Chiang, R. Garcia-Garcia, and R.E. Garcia An analytical method to determine tortuosity in rechargeable battery electrodes Journal of the Electrochemical Society 159 2012 A548
18. J.R. Wilson, W. Kobsiriphat, R. Mendoza, H.Y. Chen, J.M. Hiller, D.J. Miller, K. Thornton, P.W. Voorhees, S.B. Adler, and S.A. Barnett Three-dimensional reconstruction of a solid-oxide fuel-cell anode Nature Materials 5 2006 541
19. J.S. Cronin, K. Muangnapoh, Z. Patterson, K.J. Yakal-Kremski, V.P. Dravid, and S.A. Barnett Effect of firing temperature on LSM-YSZ composite cathodes: a combined three-dimensional microstructure and impedance spectroscopy study Journal of the Electrochemical Society 159 2012 B385
20. N.S.K. Gunda, H.W. Choi, A. Berson, B. Kenney, K. Karan, J.G. Pharoah, and S.K. Mitra Focused ion beam-scanning electron microscopy on solid-oxide fuel-cell electrode: Image analysis and computing effective transport properties Journal of Power Sources 196 2011 3592
21. K. Matsuzaki, N. Shikazono, and N. Kasagi Three-dimensional numerical analysis of mixed ionic and electronic conducting cathode reconstructed by focused ion beam scanning electron microscope Journal of Power Sources 196 2011 3073
22. J.R. Izzo Jr., A.S. Joshi, K.N. Grew, W.K.S. Chiu, A. Tkachuk, S.H. Wang, and W. Yun Nondestructive reconstruction and analysis of SOFC anodes using X-ray computed tomography at sub-50 nm resolution Journal of the Electrochemical Society 155 2008 B504
23. Fluent software package, Version 14.0, Ansys Inc., see also http://www.ansys.com.
24. D.K. Karthikeyan, G. Sikha, and R.E. White Thermodynamic model development for lithium intercalation electrodes Journal of Power Sources 185 2008 1398
25. K. Smith, and C. Wang Solid-state diffusion limitations on pulse operation of a lithium ion cell for hybrid electric vehicles Journal of Power Sources 161 2006 628
26. 2 Solid State Ionics 178 2007 1390