Transition-metal-free aerobic oxidative cleavage of C-C bonds in α-hydroxy ketones and mechanistic insight to the reaction pathway

Angewandte Chemie - International Edition

Volumn 51, Issue 50, 2012, Pages 12570-12574

  Liu, Hui ^a   Dong, Chao ^a   Zhang, Zeguang ^a   Wu, Peiyu ^a   Jiang, Xuefeng ^a  

^a EAST CHINA NORMAL UNIVERSITY   (China)

Author keywords

hydroxy ketones; C C bond cleavage; esterification; oxidation; synthetic methods

Indexed keywords

C-C BONDS; CONTROL EXPERIMENTS; ISOTOPIC LABELING; OXIDATIVE CLEAVAGES; OXIDIZING REAGENTS; REACTION MECHANISM; REACTION PATHWAYS; SYNTHETIC METHODS;

CHEMICAL REACTIONS; ESTERIFICATION; ORGANIC COMPOUNDS; OXIDATION; REACTION INTERMEDIATES; TRANSITION METALS;

KETONES;

CARBON; KETONE; OXYGEN; TRANSITION ELEMENT;

ARTICLE; CHEMISTRY; CONFORMATION; DIMERIZATION; ESTERIFICATION; ISOTOPE LABELING; OXIDATION REDUCTION REACTION; X RAY CRYSTALLOGRAPHY;

CARBON; CRYSTALLOGRAPHY, X-RAY; DIMERIZATION; ESTERIFICATION; ISOTOPE LABELING; KETONES; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; OXYGEN ISOTOPES; TRANSITION ELEMENTS;

EID: 84870585765     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201207206     Document Type: Article

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