Experimental and modeling study on the influences of methanol on premixed fuel-rich n-heptane flames

Fuel

Volumn 103, Issue , 2013, Pages 467-472

  Chen, Gen ^a   Yu, Wu ^a   Jiang, Xue ^a   Huang, Zuohua ^a   Wang, Zhandong ^b   Cheng, Zhanjun ^b  

^a XI'AN JIAOTONG UNIVERSITY   (China)

^b UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

Author keywords

Kinetic modeling; Methanol; Molecular beam sampling mass spectrometry (MBMS); n Heptane premixed flame; Synchrotron photoionization

Indexed keywords

ALLYL RADICALS; CARBON FLUXES; CHEMICAL MECHANISM; CO CONCENTRATIONS; CO FORMATION; CROSS REACTION; DOMINANT PATHWAYS; EQUIVALENCE RATIOS; FLAME FRONT; FLUX ANALYSIS; KINETIC MODELING; LAMINAR PREMIXED; LOW PRESSURES; MAXIMUM FLAME TEMPERATURE; MODELING STUDIES; MOLECULAR-BEAM SAMPLING-MASS SPECTROMETRY (MBMS); N-HEPTANES; PEAK CONCENTRATIONS; PREMIXED; PREMIXED FLAME; PROPARGYL RADICAL;

BENZENE; FUELS; HEPTANE; MASS SPECTROMETRY; MOLECULAR BEAMS; PHOTOIONIZATION;

METHANOL;

EID: 84870498595     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2012.07.032     Document Type: Conference Paper

References (52)

1. D.R. Tree, and K.I. Svensson Soot processes in compression ignition engines Prog Energy Combust Sci 33 2007 272 309
2. A. Ergut, S. Granata, J. Jordan, J. Carlson, J.B. Howard, and H. Richter PAH formation in one-dimensional premixed fuel-rich atmospheric pressure ethylbenzene and ethyl alcohol flames Combust Flame 144 2006 757 772
3. K. Kohse-Höinghaus, P. Oßwald, U. Struckmeier, T. Kasper, N. Hansen, and C.A. Taatjes The influence of ethanol addition on premixed fuel-rich propene-oxygen-argon flames Proc Combust Inst 31 2007 1119 1127
4. C.S. McEnally, and L.D. Pfefferle The effects of dimethyl ether and ethanol on benzene and soot formation in ethylene nonpremixed flames Proc Combust Inst 31 2007 603 610
5. R.J. Therrien, A. Ergut, Y.A. Levendis, H. Richter, J.B. Howard, and J.B. Carlson Investigation of critical equivalence ratio and chemical speciation in flames of ethylbenzene-ethanol blends Combust Flame 157 2010 296 312
6. B.A.V. Bennett, C.S. McEnally, L.D. Pfefferle, M.D. Smooke, and M.B. Colket Computational and experimental study of the effects of adding dimethyl ether and ethanol to nonpremixed ethylene/air flames Combust Flame 156 2009 1289 1302
7. O.P. Korobeinichev, S.A. Yakimov, D.A. Knyazkov, T.A. Bolshova, A.G. Shmakov, and J. Yang A study of low-pressure premixed ethylene flame with and without ethanol using photoionization mass spectrometry and modeling Proc Combust Inst 33 2011 569 576
8. C.K. Westbrook, W.J. Pitz, and H.J. Curran Chemical kinetic modeling study of the effects of oxygenated hydrocarbons on soot emissions from diesel engines J Phys Chem A 110 2006 6912 6922
9. Y. Ra, and R.D. Reitz A reduced chemical kinetic model for IC engine combustion simulations with primary reference fuels Combust Flame 155 2008 713 738
10. F. Inal, and S.M. Senkan Effects of oxygenate additives on polycyclic aromatic hydrocarbons (PAHs) and soot formation Combust Sci Technol 174 2002 1 19
11. F. Inal, and S.M. Senkan Effects of oxygenate concentration on species mole fractions in premixed n-heptane flames Fuel 84 2005 495 503
12. Z. Hong, D.F. Davidson, S.S. Vasu, and R.K. Hanson The effect of oxygenates on soot formation in rich heptane mixtures: a shock tube study Fuel 88 2009 1901 1906
13. P. Dagaut, and C. Togbé Experimental and modeling study of the kinetics of oxidation of butanol-n-heptane mixtures in a jet-stirred reactor Energy Fuels 23 2009 3527 3535
14. P. Dagaut, and C. Togbé Experimental and modeling study of the kinetics of oxidation of ethanol-n-heptane mixtures in a jet-stirred reactor Fuel 89 2010 280 286
15. H. Richter, and J.B. Howard Formation of polycyclic aromatic hydrocarbons and their growth to soot - a review of chemical reaction pathways Prog Energy Combust Sci 26 2000 565 608
16. H. Richter, and J.B. Howard Formation and consumption of single-ring aromatic hydrocarbons and their precursors in premixed acetylene, ethylene and benzene flames Phys Chem Chem Phys 4 2002 2038 2055
17. C.S. McEnally, L.D. Pfefferle, B. Atakan, and K. Kohse-Höinghaus Studies of aromatic hydrocarbon formation mechanisms in flames: progress towards closing the fuel gap Prog Energy Combust Sci 32 2006 247 294
18. M. Canakci, C. Sayin, and M. Gumus Exhaust emissions and combustion characteristics of a direct injection (DI) diesel engine fueled with methanol-diesel fuel blends at different injection timings Energy Fuels 22 2008 3709 3723
19. Popa MG, Negurescu N, Pana C, Racovitza A. Results obtained by methanol fuelling diesel engine. SAE Paper 2001-01-3748; 2001.
20. Saravanan CG, Saravanan B, Sitharthaseelan J, Sudhakar, Raja A, Sharavanan AR. Fumigation of methanol and fuel additives in a diesel engine testing the performance and emission characteristics.SAE Paper 2002-01-2722; 2002.
21. F. Qi, R. Yang, B. Yang, C. Huang, L. Wei, and J. Wang Isomeric identification of polycyclic aromatic hydrocarbons formed in combustion with tunable vacuum ultraviolet photoionization Rev Sci Instrum 77 2006 084101 084105
22. Y. Li, Z. Tian, L. Zhang, T. Yuan, K. Zhang, and B. Yang An experimental study of the rich premixed ethylbenzene flame at low pressure Proc Combust Inst 32 2009 647 655
23. G. Cooper, J.E. Anderson, and C.E. Brion Absolute photoabsorption and photoionization of formaldehyde in the VUV and soft X-ray regions (3-200 eV) Chem Phys 209 1996 61 77
24. J.C. Robinson, N.E. Sveum, and D.M. Neumark Determination of absolute photoionization cross sections for vinyl and propargyl radicals J Chem Phys 119 2003 5311 5314
25. 5: allyl and 2-propenyl radicals Chem Phys Lett 383 2004 601 605
26. T.A. Cool, A. McIlroy, F. Qi, P.R. Westmoreland, L. Poisson, and D.S. Peterka Photoionization mass spectrometer for studies of flame chemistry with a synchrotron light source Rev Sci Instrum 76 2005 094102 094107
27. T.A. Cool, J. Wang, K. Nakajima, C.A. Taatjes, and A. Mcllroy Photoionization cross sections for reaction intermediates in hydrocarbon combustion Int J Mass spectrom 247 2005 18 27
28. C.A. Taatjes, D.L. Osborn, T.M. Selby, G. Meloni, H. Fan, and S.T. Pratt Absolute photoionization cross-section of the methyl radical J Phys Chem A 112 2008 9336 9343
29. Z. Zhou, M. Xie, Z. Wang, and F. Qi Determination of absolute photoionization cross-sections of aromatics and aromatic derivatives Rapid Commun Mass Spectrom 23 2009 3994 4002
30. Y. Li, L. Zhang, Z. Tian, T. Yuan, J. Wang, and B. Yang Experimental study of a fuel-rich premixed toluene flame at low pressure Energy Fuels 23 2009 1473 1485
31. J.H. Kent A noncatalytic coating for platinum-rhodium thermocouples Combust Flame 14 1970 279 281
32. R.M. Fristrom Flame structure and processes 1995 Oxford University Press New York
33. A.T. Hartlieb, B. Atakan, and K. Kohse-Höinghaus Effects of a sampling quartz nozzle on the flame structure of a fuel-rich low-pressure propene flame Combust Flame 121 2000 610 624
34. 2/Ar flames at low pressure Combust Flame 156 2009 1413 1426
35. C. Renard, P.J. Van Tiggelen, and J. Vandooren Effect of dimethoxymethane addition on the experimental structure of a rich ethylene/oxygen/argon flame Proc Combust Inst 29 2002 1277 1284
36. G. Blanquart, P. Pepiot-Desjardins, and H. Pitsch Chemical mechanism for high temperature combustion of engine relevant fuels with emphasis on soot precursors Combust Flame 156 2009 588 607
37. M. Chaos, A. Kazakov, Z. Zhao, and F.L. Dryer A high-temperature chemical kinetic model for primary reference fuels Int J Chem Kinet 39 2007 399 414
38. Wang H, Dames E, Sirjean B, Sheen DA, Tangko R, Violi A, et al. A high-temperature chemical kinetic model of n-alkane (up to n-dodecane), cyclohexane, and methyl-, ethyl-, n-propyl and n-butyl-cyclohexane oxidation at high temperatures, JetSurF version 2.0; September 19, 2010. < http://melchior.usc.edu/JetSurF/JetSurF2.0 >.
39. N. Hansen, J.A. Miller, C.A. Taatjes, J. Wang, T.A. Cool, and M.E. Law Photoionization mass spectrometric studies and modeling of fuel-rich allene and propyne flames Proc Combust Inst 31 2007 1157 1164
40. N. Hansen, J.A. Miller, P.R. Westmoreland, T. Kasper, K. Kohse-Höinghaus, and J. Wang Isomer-specific combustion chemistry in allene and propyne flames Combust Flame 156 2009 2153 2164
41. R.J. Kee, F.M. Rupley, M.D. Smooke, and J.A. Miller PREMIX: a fortran program for modeling steady one-dimensional premixed flames, SAND85-8240 1985 Springer Livermore, CA
42. R.J. Kee, F.M. Rupley, and J.A. Miller CHEMKIN-II: a fortran chemical kinetic package for the analysis of gas phase chemical kinetics, SAND89-8009 1989 Sandia National Laboratories Livermore, CA
43. A.E. Lutz, F.M. Rupley, R.J. Kee, and W.C. Reynolds EQUIL: a CHEMKIN implementation of STANJAN for computing chemical equilibria 1998 Reaction Design, Inc.
44. C. DoutÉ, J.-L. Delfau, and C. Vovelle Detailed reaction mechanisms for low pressure premixed n-heptane Flames Combust Sci Technol 147 1999 61 109
45. L. Terese Automatic generation of skeletal mechanisms for ignition combustion based on level of importance analysis Combust Flame 156 2009 1348 1358
46. T.J. Held, and F.L. Dryer A comprehensive mechanism for methanol oxidation Int J Chem Kinet 30 1998 805 830
47. M. Frenklach Reaction mechanism of soot formation in flames Phys Chem Chem Phys 4 2002 2028 2037
48. C.J. Pope, and J.A. Miller Exploring old and new benzene formation pathways in low-pressure premixed flames of aliphatic fuels Proc Combust Inst 28 2000 1519 1527
49. J.A. Cole, J.D. Bittner, J.P. Longwell, and J.B. Howard Formation mechanisms of aromatic compounds in aliphatic flames Combust Flame 56 1984 51 70
50. M. Frenklach, and J. Warnatz Detailed modeling of PAH Profiles in a sooting low-pressure acetylene flame Combust Sci Technol 51 1987 265 283
51. 6 potential J Phys Chem A 107 2003 7783 7799
52. K.L. McNesby, A.W. Miziolek, T. Nguyen, F.C. Delucia, R.R. Skaggs, and T.A. Litzinger Experimental and computational studies of oxidizer and fuel side addition of ethanol to opposed flow air/ethylene flames Combust Flame 142 2005 413 427