Inorganic-organic hybrids based on poly (ε-Caprolactone) and silica oxide and characterization by relaxometry applying low-field NMR

Materials Research

Volumn 15, Issue 6, 2012, Pages 825-832

  De Bustamante Monteiro, Mariana Sato De Souza ^a   Neto, Roberto Pinto Cucinelli ^a   Santos, Izabel Cristina Souza ^a   Da Silva, Emerson Oliveira ^a   Tavares, Maria Inês Bruno ^a  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

Author keywords

Hybrids; Nuclear magnetic resonance; Polycaprolactone; Silica oxide

Indexed keywords

AEROSILS; CAPROLACTONE; CRYSTALLINITY DEGREE; CRYSTALLIZATION TEMPERATURE; HYBRIDS; INORGANIC-ORGANIC HYBRID; INTERMOLECULAR INTERACTIONS; LOW-FIELD NMR; MAXIMUM TEMPERATURE; NANO-FILLERS; NEAT POLYMER; NMR ANALYSIS; RELAXOMETRY; ROTATING FRAME; SILICA OXIDE; SOLUTION METHODS; WELL-DISPERSED;

DIFFERENTIAL SCANNING CALORIMETRY; HYBRID MATERIALS; HYDROGEN; NUCLEAR MAGNETIC RESONANCE; ORGANIC COATINGS; POLYCAPROLACTONE; RELAXATION TIME; SPIN-LATTICE RELAXATION; THERMOGRAVIMETRIC ANALYSIS; X RAY DIFFRACTION;

SILICA;

EID: 84870452690     PISSN: 15161439     EISSN: None     Source Type: Journal    
DOI: 10.1590/S1516-14392012005000121     Document Type: Article

References (36)

1. Ochi M, Takahashi R and Terauchi R. Phase structure and mechanical and adhesion properties of epoxy/silica hybrids. Polymer. 2001; 42:5151-5158. http://dx.doi.org/10.1016/S0032-3861(00)00935-6
2. Zou J, Shi W and Hong X. Characterization and properties of a novel organic-inorganic hybrid based on hyperbranched aliphatic polyester prepared via sol-gel process. Composites Part A: Applied Science and Manufacturing. 2005; 36:631-637. http://dx.doi.org/10.1016/j.compositesa.2004.08.001
3. Avella M, Bondioli F, Cannello V, Di Pace E, Errico ME, Ferrari AM et al. Poly(ε-caprolactone)-based nanocomposites: Influence of compatibilization on properties of poly(ε-caprolactone)-silica nanocomposites. Composites Science and Technology. 2006; 66:886-894. http://dx.doi.org/10.1016/j. compscitech.2005.08.014
4. 2 Nanocomposites. Macromolecular Symposia. 2004; 218:201-210.
5. Xu GC, Li AY, Zhang LD, Yu XY, Xie T and Wu GS. Nanomechanic Properties of Polymer-Based Nanocomposites with Nanosilica by Nanoindentation. Journal of Reinforced Plastics and Composites. 2004; 23(13)1365-1372. http://dx.doi.org/10. 1177/0731684404037044
6. Zou H, Wi S and Shen J. Polymer/Silica Nanocomposites: Preparation, Characterization, Properties, and Applications. Chemical Reviews. 2008; 108:3893-3957. PMid:18720998. http://dx.doi.org/10.1021/cr068035q
7. Chrissafis K, Antoniadis G, Paraskevopoulus KM, Vassiliou A and Bikiaris DN. Comparative study of the effect of different nanoparticles on the mechanical properties and thermal degradation mechanism of in situ prepared poly(ε-caprolactone) nanocomposites. Composites Science and Technology. 2007; 67:2165-2174. http://dx.doi.org/10.1016/j.compscitech.2006.10.027
8. Ayala GG, Pace ED, Laurienzo P, Pantalena D, Somma E and Nobila MR. Poly(ε-caprolactone) modified by functional groups: Preparation and chemical-physical investigation. European Polymer Journal. 2009; 45(11):3217-3229. http://dx.doi.org/10.1016/j.eurpolymj.2009.07.021
9. Ludueña LN, Alvarez VA and Vazquez A. Processing and microstructure of PCL/clay nanocomposites. Materials Science and Engineering: A. 2007; 460-461:121-129. http://dx.doi.org/10.1016/j.msea.2007.01.104
10. Tavares MIB, Nogueira RF, Gil RASS, Preto M, Silva EO, Silva MBR et al. Polypropylene-clay nanocomposite structure probed by H NMR relaxometry. Polymer Testing. 2007; 26:1100-1102. http://dx.doi.org/10.1016/j.polymertesting.2007.07. 012
11. Sirelli L, Prado RMK, Tavares MIB, Nunes RCR and Dias ML. Molecular Dynamics of Poly(Ethylene Terephthalate)/Muscovite Mica Composite by Low-Field NMR. International Journal of Polymer Analysis and Characterization. 2008; 13:180-189. http://dx.doi.org/10.1080/10236660802070678
12. Freire E, Bianchi O, Forte MMC, Preto M, Monteiro EEC and Tavares MIB. Thermal and low-field NMR study on poly(vinylidene fluoride) and their physical mixtures with poly(methyl methacrylate). Polymer Engineering & Science. 2008; 48:1901-1909. http://dx.doi.org/10.1002/pen.21174
13. Rosa DS, Carvalho CL, Gaboardi F, Rezende ML, Tavares MIB, Petro MSM et al. Evaluation of enzymatic degradation based on the quantification of glucose in thermoplastic starch and its characterization by mechanical and morphological properties and NMR measurements. Polymer Testing. 2008; 27:827-834. http://dx.doi.org/10.1016/j.polymertesting.2008.06.008
14. Rodrigues TC, Tavares MIB, Preto M, Soares IL and Moreira ACF. Evaluation of Polyethylene/Organoclay Nanocomposites by Low-field Nuclear Relaxation. International Journal of Polymeric Materials. 2008; 57:1119-1123. http://dx.doi.org/10.1080/00914030802428716
15. Nogueira RF, Tavares MIB, San Gil RAS and da Silva NM. Solid state NMR investigation of polypropylene/Brazilian clay blending process. Polymer Testing. 2005; 24:358-362. http://dx.doi.org/10.1016/j.polymertesting.2004.10.005
16. da Silva NM and Tavares MIB. Aplicação de Técnicas Combinadas de NMR no Estado Sólido para Avaliação do Sistema EPDM/PPa. Polímeros. 1994; 4:40-42.
17. Tang ZG, Black RA, Curran JM, Hunt JA, Rhodes NP and Williams DF. Surface properties and biocompatibility o f s o l ve n t -c a s t p o l y [ ε - c a p r o l a c t o n e ] fi l m s . Biomaterials. 2004; 25:4741-4748. PMid:15120520. http://dx.doi.org/10.1016/j.biomaterials.2003.12.003
18. Di Y, Iannace S, Di Maio E and Nicolais L. Nanocomposites by melt intercalation based on polycaprolactone and organoclay. Journal of Polymer Science Part B: Polymer Physics. 2003; 41:670-678. http://dx.doi.org/10.1002/ polb.10420
19. Nakamoto K. Theory and applications in inorganic chemistry: Infrared and Raman Spectra of inorganic and coordination compound. 5th ed. John Wiley; 1997.
20. Nassar EJ, Messaddeq Y, Ribeiro SJL. Influência da catálise ácida e básica na preparação da sílica funcionalizada pelo método sol-gel. Química Nova. 2002; 25(1):27 http://dx.doi.org/10.1590/S0100-40422002000100006
21. Li R, Nie K, Shen X and Wang S. Biodegradable polyester hybrid nanocomposites containing titanium dioxide network and poly(ε-caprolactone) : Synthesis and characterization. Materials Letters. 2007; 61:1368-1371. http://dx.doi.org/10.1016/j.matlet.2006.07.032
22. De Gaetano F, Ambrosio L, Raucci MG, Marotta A and Catauro M. Sol-gel processing of drug delivery materials and release kinetics. Journal of Materials Science: Materials in Medicine. 2005; 16:261-265. PMid:15744618. http://dx.doi.org/10.1007/s10856-005-6688-x
23. Prado AGS, Faria EA and Padilha PM. Aplicação e modificação química da sílica gel obtida de areia. Química Nova. 2005; 28(3):544. http://dx.doi.org/10.1590/S0100- 40422005000300030
24. 2 and poly(ε-caprolactone), a biodegradable aliphatic polyester. Journal of Biomedical Materials Research Part A. 2007; 83:114-122. PMid:17385234. http://dx.doi.org/10.1002/jbm.a.31224
25. Fukushima K, Tabuani D, Abbate C, Arena M and Rizzarelli P. Preparation, characterization and biodegradation of biopolymer nanocomposites based on fumed silica. European Polymer Journal. 2011; 47:139-152. http://dx.doi.org/10.1016/j. eurpolymj.2010.10.027
26. Fukushima K, Tabuani D and Camino G. Nanocomposites of PLA and PCL based on montmorillonite and sepiolite. Materials Science and Engineering: C. 2009; 29:1433-1441. http://dx.doi.org/10.1016/j.msec.2008.11.005
27. Sivalingam G and Madras G. Thermal degradation of binary physical mixtures and copolymers of poly(ε-caprolactone), poly(d, l-lactide), poly(glycolide). Polymer Degradation and Stability. 2004; 84:393-398. http://dx.doi.org/10.1016/j.polymdegradstab.2003.12.008
28. Draye AC, Persenaire O, Brožek J, Roda J, Košek T and Dubois Ph. Thermogravimetric analysis of poly(ε-caprolactam) and poly[(ε-caprolactam)-co-(ε-caprolactone)] polymers. Polymer. 2001; 42:8325-8332. http://dx.doi.org/10.1016/S0032-3861(01)00352-4
29. Ray SS and Bousmina M. Biodegradable polymers and their layered silicate nanocomposites: In greening the 21st century materials world. Progress in Materials Science. 2005; 50:962-1079. http://dx.doi.org/10.1016/j.pmatsci.2005. 05.002
30. Liao L, Zhang C, Gong S. Preparation of Poly(ε-caprolactone)/Clay Nanocomposites by Microwave-Assisted In Situ Ring-Opening Polymerization. Macromolecular Rapid Communications. 2007; 28:1148-1154. http://dx.doi.org/10. 1002/marc.200700063
31. Tavares MIB, Ferreira O, Preto MSM, Miguez E, Soares IL and Silva EP. Evaluation of Composites Miscibility by Low Field NMR. International Journal of Polymeric Materials. 2007; 56(4):1113-1118. http://dx.doi.org/10.1080/ 00914030701283063
32. Bruno M, Tavares MIB, Motta LM, Miguez E, Preto M and Fernandez AOR. Evaluation of PHB/Clay nanocomposite by spin-lattice relaxation time. Materials Research. 2008; 4:483. http://dx.doi.org/10.1590/S1516-14392008000400018
33. Preto M, Tavares MIB and Silva EP. Low-field NMR study of Nylon 6/silica composites. Polymer Testing. 2007; 26:501-504. http://dx.doi.org/10.1016/j. polymertesting.2007.01.009
34. 4)2 as studied by 1H spin-lattice relaxation in the rotating fram. Solid State Nuclear Magnetic Resonance. 2010; 37:69-74. PMid:20627482. http://dx.doi.org/10.1016/j.ssnmr.2010.05.002e
35. 2 nanocomposites. Polymer Test. 2009; 28:490-494. http://dx.doi.org/10.1016/j. polymertesting.2009.03.011
36. Kwak SY and Kim SY. Microphase structures of polymers containing structural heterogeneity as probed by n.m.r. spin-lattice relaxation analysis. Polymer. 1998; 39(17):4099-4105. http://dx.doi.org/10.1016/S0032-3861(97)10229-4