A practical method for the quantitative assessment of non-enantioselective versus enantioselective interactions encountered in liquid chromatography on brush-type chiral stationary phase

Journal of Chromatography A

Volumn 1269, Issue , 2012, Pages 270-278

  Levkin, Pavel ^a,c   Maier, Norbert M ^b   Lindner, Wolfgang ^b   Schurig, Volker ^a  

^a UNIVERSITY OF TÜBINGEN   (Germany)

^b UNIVERSITY OF VIENNA   (Austria)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

Anion exchange type selectors; Apparent versus true enantioselectivity; Brush type CSPs; Controlled selector loading; Enantiomer separation; Enantioselective adsorption; Nonenantioselective adsorption

Indexed keywords

BRUSH-TYPE CSPS; CHIRAL RECOGNITION; CHIRAL SELECTOR; CHIRAL STATIONARY PHASE; CHIRAL STATIONARY PHASIS; CO-EXISTING; ENANTIOMER SEPARATION; ENANTIOSELECTIVE; ENANTIOSELECTIVE ADSORPTION; ENANTIOSELECTIVE ASSOCIATION; ENANTIOSELECTIVE INTERACTIONS; ENANTIOSEPARATIONS; EQUILIBRIUM PROCESS; EXPERIMENTAL METHODS; IMMOBILIZATION CHEMISTRY; INTERMOLECULAR BINDING; LIQUID-LIQUID EXTRACTION; LOADING LEVEL; MOBILE PHASE; MOBILE PHASE CONDITIONS; NON-POLAR; OPERATION CONDITIONS; PRACTICAL METHOD; PROPANOIC ACID; QUANTITATIVE ASSESSMENTS; QUANTITATIVE INFORMATION; RETENTION CHARACTERISTICS; REVERSED PHASE; SYSTEMATIC EVALUATION;

ADSORPTION; AMINO ACIDS; BRUSHES; CHIRALITY; ENANTIOMERS; LIQUID CHROMATOGRAPHY; SEPARATION; SYSTEMS ENGINEERING; THERMODYNAMICS;

ENANTIOSELECTIVITY;

ADSORPTION KINETICS; ARTICLE; BINDING KINETICS; CHIRALITY; ENANTIOMER; ENANTIOSELECTIVITY; EQUILIBRIUM CONSTANT; IMMOBILIZATION; INTERMETHOD COMPARISON; LIQUID CHROMATOGRAPHY; MOLECULAR INTERACTION; MOLECULAR RECOGNITION; PHASE SEPARATION; PRIORITY JOURNAL; QUANTITATIVE ANALYSIS; SURFACE PROPERTY; THERMODYNAMICS;

CHROMATOGRAPHY, HIGH PRESSURE LIQUID; STEREOISOMERISM;

EID: 84870352195     PISSN: 00219673     EISSN: 18733778     Source Type: Journal    
DOI: 10.1016/j.chroma.2012.10.006     Document Type: Article

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