Coupling reaction of magnesium alkylidene carbenoids with α-sulfonylallyllithiums: An efficient route to multi-substituted vinylallenes

Synthesis (Germany)

Volumn 44, Issue 23, 2012, Pages 3623-3632

  Kimura, Tsutomu ^a   Kobayashi, Gen ^a   Ishigaki, Masashi ^a   Inumaru, Mio ^a   Sakurada, Jo ^a   Satoh, Tsuyoshi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

1 chlorovinyl p tolyl sulfoxides; allyl sulfones; coupling; magnesium alkylidene carbenoids; vinyl sulfones; vinylallenes

Indexed keywords

1-CHLOROVINYL P -TOLYL SULFOXIDES; ALKYLIDENES; ALLYL SULFONES; VINYL SULFONES; VINYLALLENES;

CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COUPLINGS;

MAGNESIUM;

(3 TOSYLPROP 1 ENE 1,1 DIYL)DIBENZENE; 1 [(1 CHLORO 2 ETHYLBUT 1 EN 1 YL)SULFINYL] 4 METHYLBENZENE; 1 [(3,4 DIMETHYLPENT 3 EN 2 YL)SULFONYL] 4 METHYLBENZENE; 1 [(CYCLOHEXYLIDENEMETHYL)SULFONYL] 4 METHYLBENZENE; 1 [(CYCLOPENTYLIDENEMETHYL)SULFONYL] 4 METHYLBENZENE; 1 CHLOROVINYL 4 TOLYL SULFOXIDE DERIVATIVE; 1 METHOXY 4 (4 METHYL 3 TOSYLPENT 3 EN 1 YL)BENZENE; 1 METHYL 4 [(2 METHYLPROP 1 EN 1 YL)SULFONYL]BENZENE; 1 METHYL 4 [(3 PHENYLALLYL)SULFONYL]BENZENE; 8 (1 TOSYLPROPAN 2 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (3 CYCLOOCTYLIDENEALLYLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (3 CYCLOPENTYLIDENEALLYLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (3 METHYLBUTA 1,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (4 ETHYLHEXA 2,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (4 METHYLPENTA 1,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (4 METHYLPENTA 2,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (4 PHENETHYL 6 PHENYLHEXA 2,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (4 PHENYLBUTA 1,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8 (4,4 DIPHENYLBUTA 1,3 DIEN 1 YLIDENE) 1,4 DIOXASPIRO[4.5]DECANE; 8,8' (BUT 1 ENE 1,3 DIYLIDENE)BIS(1,4 DIOXASPIRO[4.5]DECANE); 8,8' (PROP 1 ENE 1,3 DIYLIDENE)BIS(1,4 DIOXASPIRO[4.5]DECANE); [3 [CHLORO (4 TOLYSULFINYL)METHYLENE]PENTANE 1,5 DIYL]DIBENZENE; ALLENE DERIVATIVE; ALPHA SULFONYL ALLYLLITHIUM DERIVATIVE; CARBENOID; LITHIUM DERIVATIVE; MAGNESIUM ALKYLIDENE CARBENOID DERIVATIVE; TERT BUTYL 3 METHYL 2 TOSYLBUT 2 ENOATE; UNCLASSIFIED DRUG; VINYLALLENE DERIVATIVE;

ACETYLATION; ANALYTIC METHOD; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; COLUMN CHROMATOGRAPHY; CROSS COUPLING REACTION; HORNER WADSWORTH EMMONS REACTION; ISOMERIZATION; NUCLEOPHILICITY; PROCESS OPTIMIZATION; PROTON TRANSPORT; SYNTHESIS;

EID: 84870236059     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0032-1317507     Document Type: Article

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