Epoxidation of castor oil with peracetic acid formed in situ in the presence of an ion exchange resin

Chemical Engineering and Processing: Process Intensification

Volumn 62, Issue , 2012, Pages 106-113

  Sinadinović Fišer, Snežana ^a   Janković, Milovan ^a   Borota, Olga ^a  

^a UNIVERSITY OF NOVI SAD   (Serbia)

Author keywords

Castor oil; In situ epoxidation; Ion exchange resin; Kinetic model; Peracetic acid; Reaction variable

Indexed keywords

AMBERLITE IR-120; ARRHENIUS EQUATION; CASTOR OIL; DOUBLE BONDS; EPOXY COMPOUND; KINETIC MODELS; MARQUARDT METHOD; PERACETIC ACIDS; PRODUCT CONCENTRATION; RATE COEFFICIENTS; REACTION VARIABLES; RING CLEAVAGE; SIDE REACTIONS; TEMPERATURE DEPENDENCIES;

ACETIC ACID; BENZENE; ETHERS; HYDROGEN PEROXIDE; ION EXCHANGE RESINS; KINETIC THEORY; KINETICS; PH; VEGETABLE OILS;

EPOXIDATION;

EID: 84869869503     PISSN: 02552701     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cep.2012.08.005     Document Type: Article

References (21)

1. Abdullah B.M., Salimon J. Epoxidation of vegetable oils and fatty acids: catalysts, methods and advantages. Journal of Applied Sciences 2010, 10:1545-1553.
2. Campanella A., Baltanás M.A. Degradation of the oxirane ring of epoxidized vegetable oils in liquid-liquid heterogeneous reaction systems. Chemical Engineering Journal 2006, 118:141-152.
3. Wisniak J., Navarrete E. Epoxidation of fish oil: kinetic and optimization model. Industrial and Engineering Chemistry Product Research and Development 1970, 9:33-41.
4. Gan L.H., Goh S.H., Ooi K.S. Kinetic studies of epoxidation and oxirane cleavage of palm olein methyl esters. Journal of the American Oil Chemists Society 1992, 69:347-351.
5. Zaher F.A., El-Mallah M.H., El-Hefnawy M.M. Kinetic of oxirane cleavage in epoxidized soybean oil. Journal of the American Oil Chemists Society 1989, 66:698-700.
6. Janković M., Sinadinović-Fišer S. Kinetic models of reaction systems for the in situ epoxidation of unsaturated fatty acid esters and triglycerids. Hemijska Industrija 2004, 58:569-576.
7. 2. Journal of the American Oil Chemists Society 2006, 83:635-640.
8. Ikhuoria E.U., Obuleke R.O., Okieimen F.E. Studies on the kinetics of epoxidation of the methyl esters of parkia bioglobosa seed oil. Journal of Macromolecular Science, Part A-Pure and Applied Chemistry 2007, 44:235-238.
9. Dinda S., Patwardhan A.V., Goud V.V., Pradhan N.C. Epoxidation of cottonseed oil by aqueous hydrogen peroxide catalyzed by liquid inorganic acid. Bioresource Technology 2008, 99:3737-3744.
10. Cai C., Dai H., Chen R., Su C., Xu X., Zhang S., Yang L. Studies on the kinetics of in situ epoxidation of vegetable oils. European Journal of Lipid Science and Technology 2008, 110:341-346.
11. Mutlu H., Meier M.A.R. Castor oil as a renewable resource for the chemical industry. European Journal of Lipid Science and Technology 2010, 112:10-30.
12. Park S.J., Jin F.L., Lee J.R. Synthesis and thermal properties of epoxidized vegetable oil. Macromolecular Rapid Communications 2004, 25:724-727.
13. Goud V.V., Patwardhan A.V., Pradhan N.C. Strongly acidic cation exchange resin of sulphonated polystyrene type used as catalyst for epoxidation of castor oil with peracetic acid and performic acid. Solid State Science and Technology 2006, 14:62-68.
14. Sinadinović-Fišer S., Janković M., Petrović Z. Kinetics of in situ epoxidation of soybean oil in bulk catalyzed by ion exchange resin. Journal of the American Oil Chemists Society 2001, 78:725-731.
15. Standard Methods for the Analysis of Oils, Fats and Derivatives 1987, Blackwell Scientific Publications, London. seventh ed.
16. Goud V.V., Patwardhan A.V., Pradhan N.C. Kinetics of in situ epoxidation of natural unsaturated triglycerides catalyzed by acid ion exchange resin. Industrial and Engineering Chemistry Research 2007, 46:3078-3085.
17. Petrović Z., Zlatanić A., Lava C.C., Sinadinović-Fišer S. Epoxidation of soybean oil in toluene with peroxoacetic and peroxoformic acids - kinetics and side reactions. European Journal of Lipid Science and Technology 2002, 104:293-299.
18. Mungroo R., Pradhan N., Goud V.V., Dalai A.K. Epoxidation of canola oil with hydrogen peroxide by ion exchange resin. Journal of the American Oil Chemists Society 2008, 85:887-896.
19. Mungroo R., Goud V.V., Narayan Naik S., Dalai A.K. Utilization of green seed canola oil for in situ epoxidation. European Journal of Lipid Science and Technology 2011, 113:768-774.
20. Janković M., Sinadinović-Fišer S., Lamshoeft M. Liquid-liquid equilibrium constant for acetic acid in an epoxidized soybean oil-acetic acid-water system. Journal of the American Oil Chemists Society 2010, 87:591-600.
21. Marquardt D.W. An algorithm for least-squares estimation of nonlinear parameters. Journal of the Society for Industrial and Applied Mathematics 1963, 11:431-441.