Improved selectivity by stabilizing and exposing active phases on supported Pd nanoparticles in acetylene-selective hydrogenation

Chemistry - A European Journal

Volumn 18, Issue 47, 2012, Pages 14962-14966

  Shao, Lidong ^a   Zhang, Bingsen ^a,b   Zhang, Wei ^a   Teschner, Detre ^a   Girgsdies, Frank ^a   Schlögl, Robert ^a   Su, Dang Sheng ^a,b  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^b INSTITUTE OF METAL RESEARCH   (China)

Author keywords

acetylene; electron microscopy; hydrogenation; nanotubes; supported catalysts

Indexed keywords

ACTIVE PHASIS; CARBON DIFFUSION; GEOMETRIC STRUCTURE; METAL PARTICLE; PARTICLE SURFACE; STRONG INTERACTION; SUPPORTED PD;

ACETYLENE; CATALYST SUPPORTS; ELECTRON MICROSCOPY; LIGHTING; NANOTUBES;

HYDROGENATION;

ACETYLENE; ETHYLENE; ETHYLENE DERIVATIVE; METAL NANOPARTICLE; PALLADIUM;

ARTICLE; CHEMISTRY; HYDROGENATION; PARTICLE SIZE; SURFACE PROPERTY; SYNTHESIS;

ACETYLENE; ETHYLENES; HYDROGENATION; METAL NANOPARTICLES; PALLADIUM; PARTICLE SIZE; SURFACE PROPERTIES;

EID: 84869129184     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201202608     Document Type: Article

References (27)

1. G. C. Bond, D. A. Dowden, N. Mackenzie, Trans. Faraday Soc. 1958, 54, 1537.
2. G. Webb, in Comprehensive Chemical Kinetics, Vol. 20 (Eds.:, C. H. Bamford, C. F. H. Tipper,), Elsevier, Amsterdam, 1978, p. 1.
3. D. Teschner, Z. Révay, J. Borsodi, M. Hävecker, A. Knop-Gericke, R. Schlögl, D. Milroy, S. D. Jackson, D. Torres, P. Sautet, Angew. Chem. 2008, 120, 9414
4. Angew. Chem. Int. Ed. 2008, 47, 9274.
5. D. Teschner, J. Borsodi, A. Wootsch, Z. Revay, M. Havecker, A. Knop-Gericke, S. D. Jackson, R. Schlögl, Science 2008, 320, 86.
6. A. FrÄckiewicz, A. Janko, Acta Cryst 1978, A34, 377.
7. J. Stachurski, A. Frackiewicz, J. Less-Common Met. 1985, 108, 249.
8. J. Stachurski, J. Chem. Soc. Faraday Trans. 1985, 81, 2813.
9. A. BorodziÅski, Polish. J. Chem. 1998, 72, 2455.
10. A. S. Al-Ammar, G. J. Webb, J. Chem. Soc. Faraday Trans. 1 1978, 74, 657.
11. A. BorodziÅski, Catal. Lett. 1999, 63, 35.
12. K. M. Neyman, S. Schauermann, Angew. Chem. 2010, 122, 4851
13. Angew. Chem. Int. Ed. 2010, 49, 4743.
14. M. Wilde, K. Fukutani, W. Ludwig, B. Brandt, J.-H. Fischer, S. Schauermann, H. J. Freund, Angew. Chem. 2008, 120, 9430
15. Angew. Chem. Int. Ed. 2008, 47, 9289.
16. S. J. Tauster, S. C. Fung, R. T. K. Baker, J. A. Horsley, Science 1981, 211, 1121.
17. A. Rinaldi, J.-P. Tessonnier, M. E. Schuster, R. Blume, F. Girgsdies, Q. Zhang, T. Jacob, S. B. A. Hamid, D. S. Su, R. Schlögl, Angew. Chem. 2011, 123, 3371
18. Angew. Chem. Int. Ed. 2011, 50, 3313.
19. M. C. Burrell, G. A. Smith, J. Chera, J. Surf. Inter. Anal. 1988, 11, 160.
20. D. Teschner, E. Vass, M. Havecker, H. Sauer, A. Knop-Gericke, R. Schlögl, J. McGregor, L. F. Gladden, J. Catal. 2006, 242, 26.
21. S. B. Ziemecki, G. A. Jones, D. G. Swartzfager, R. L. Harlow, J. Faber, J. Am. Chem. Soc. 1985, 107, 4547.
22. S. B. Ziemecki, G. A. Jones, J. Catal. 1985, 95, 621.
23. S. B. Ziemecki, G. A. Jones, D. G. Swartzfager, J. Less-Common Met. 1987, 131, 157.
24. L. D. Shao, W. Zhang, M. Armbrüster, D. Teschner, F. Girgsdies, B. Zhang, O. Timpe, M. Friedich, R. Schlögl, D. S. Su, Angew. Chem. 2011, 123, 10414
25. Angew. Chem. Int. Ed. 2011, 50, 10231.
26. S. Iijima, Nature 1991, 354, 56.
27. L. D. Shao, T. W. Lin, G. Tobias, M. L. H. Green, Chem. Commun. 2008, 2164.