Understanding palladium hydrogenation catalysts: When the nature of the reactive molecule controls the nature of the catalyst active phase

Angewandte Chemie - International Edition

Volumn 47, Issue 48, 2008, Pages 9274-9278

  Teschner, Detre ^a   Révay, Zsolt ^b   Borsodi, János ^a,b   Hävecker, Michael ^a   Knop Gericke, Axel ^a   Schlögl, Robert ^a   Milroy, David ^c   Jackson, S David ^c   Torres, Daniel ^d   Sautet, Philippe ^d  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^b INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^c UNIVERSITY OF GLASGOW   (United Kingdom)

^d UNIVERSITÉ DE LYON   (France)

Author keywords

Adsorption; Density functional calculations; Hydrogenation; Palladium; Photoelectron spectroscopy

Indexed keywords

ACETYLENE; ADSORPTION; CATALYSIS; CATALYSTS; CHEMICAL BONDS; ELECTRON SPECTROSCOPY; HYDROCARBONS; HYDROGENATION; PALLADIUM; PHOTOELECTRICITY; PHOTOELECTRON SPECTROSCOPY; PHOTOIONIZATION; PHOTONS; SPECTRUM ANALYSIS;

CATALYST SURFACES; CHEMICAL NATURES; DENSITY FUNCTIONAL CALCULATIONS; FUNDAMENTAL DIFFERENCES; HYDROGENATION CATALYSTS; IN-SITU; PALLADIUM CATALYSTS; REACTIVE MOLECULES; STRONG LINKS; SURFACE REGIONS; X-RAY PHOTOELECTRON SPECTROSCOPIES;

X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 56449125216     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200802134     Document Type: Article

References (23)

1. a) H. Arnold, F. Dobert, J. Gaube in Hydrogenation Reaction in Handbook of Heterogeneous Catalysis, Vol. 5 (Eds.: G. Ertl, H. Knozinger, J. Weitkamp), Wiley-VCH, New York, 1997, p. 2165;
2. b) A. Molnar, A. Sarkany, M. Varga, J. Mol. Catal. A 2001, 173, 185.
3. A. Borodziñski, G. C. Bond, Catal. Rev. 2006, 48, 91, and references therein.
4. a) D. Teschner, J. Borsodi, A. Wootsch, Zs. Révay, M. Hävecker, A. Knop-Gericke, S. D. Jackson, R. Schlögl, Science 2008, 320, 86;
5. b) D. Teschner, E. M. Vass, M. Hvecker, S. Zafeiratos, P. Schnörch, H. Sauer, A. Knop-Gericke, R. Schlögl, M. Chamam, A. Wootsch, A. S. Canning, J. J. Gamman, S. D. Jackson, J. McGregor, L. F. Gladden, J. Catal. 2006, 242, 16.
6. A. D. Johnson, S. P. Daley, A. L. Utz, S. T. Ceyer, Science 1992, 257, 223.
7. a) A. Michaelides, P. Hu, A. Alavi, J. Chem. Phys. 1999, 111, 1343;
8. b) V. Ledentu, W. Dong, P. Sautet, J. Am. Chem. Soc. 2000, 122, 1796.
9. 335 eV), where I is the corresponding peak area, È the takeoff angle, and IMFP the inelastic mean free path. IMFP was 9 Å at 720 eV. The growth of the Pd/C phase was determined from the temporal evolution of the thickness.
10. H. Yokoyama, H. Numakura, M. Koiwa, Acta mater. 1998, 46, 2823.
11. Handbook of Prompt Gamma Activation Analysis with Neutron Beams (Ed.: G. L. Molnár), Kluwer Academic Publishers, Dordrecht, 2004.
12. Zs. Révay, T. Belgya, L. Szentmiklósi, Z. Kis, A. Wootsch, D. Teschner, M. Swoboda, R. Schlögl, J. Borsodi, R. Zepernick, Anal. Chem. 2008, 80, 6066.
13. H. Frieske, E. Wicke, Ber. Bunsen-Ges. 1973, 77, 48.
14. G. Kresse, J. Hafner, Phys. Rev. B 1993, 47, 558.
15. L. Gracia, M. Calatayud, J. Andrés, C. Minot, M. Salmeron, Phys. Rev. B 2005, 71, 033407.
16. K. Reuter, M. Scheffler, Phys. Rev. B 2003, 68, 045407.
17. a) W. Dong, V. Ledentu, P. Sautet, A. Eichler, J. Hafner, Surf. Sci. 1998, 411, 123;
18. b) J.-F. Paul, P. Sautet, Phys. Rev. B 1996, 53, 8015.
19. S. Tanuma, C. J. Powell, D. R. Penn, Surf. Interface Anal. 1991, 17, 911.
20. Zs. Révay, T. Belgya, Zs. Kasztovszky, J. L. Weil, G. L. Molnár, Nucl. Instrum. Methods Phys. Res. Sect. B 2004, 213, 385.
21. J. P. Perdew, J. A. Chevary, S. H. Vosko, K. A. Jackson, M. R. Pederson, D. J. Singh, C. Fiolhais, Phys. Rev. B 1992, 46, 6671.
22. P. E. Blöchl, Phys. Rev. B 1994, 50, 17953.
23. H. J. Monkhorst, J. D. Pack, Phys. Rev. B 1976, 13, 5188.