Sc(OTf) 3-catalyzed synthesis of thiosulfonates in ionic liquid-water

Tetrahedron Letters

Volumn 53, Issue 50, 2012, Pages 6768-6770

  Liang, Gaigai ^a   Chen, Jing ^a   Chen, Jiali ^a   Li, Wanmei ^a,b   Chen, Jiuxi ^a   Wu, Huayue ^a  

^a WENZHOU UNIVERSITY   (China)

^b HANGZHOU NORMAL UNIVERSITY   (China)

Author keywords

Ionic liquid; N (Organothio)succinimide; Sc(OTf)3; Sulfinate; Thiosulfonates

Indexed keywords

IONIC LIQUID; SOLVENT; SULFONIC ACID DERIVATIVE; WATER;

ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; SOLUBILITY; SYNTHESIS;

EID: 84868603253     PISSN: 00404039     EISSN: 18733581     Source Type: Journal    
DOI: 10.1016/j.tetlet.2012.09.132     Document Type: Article

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46. 3 was added at 30 °C. The mixture solution was stirred at 30 °C for respective time. After the completion of the reaction, as monitored by TLC and GC-MS analysis, the mixture was washed with water and extracted with diethyl ether. The organic phase was concentrated and the resulting residue was purified by column chromatography on silica gel (300-400 mesh) with petroleum ether-EtOAc as eluent to provide the desired thiosulfonates 3.