Speciation and isotope dilution analysis of gadolinium-based contrast agents in wastewater

Environmental Science and Technology

Volumn 46, Issue 21, 2012, Pages 11929-11936

  Telgmann, Lena ^a   Wehe, Christoph A ^a   Birka, Marvin ^a   Künnemeyer, Jens ^a   Nowak, Sascha ^a   Sperling, Michael ^a   Karst, Uwe ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED SLUDGE TREATMENT; AERATION TANKS; ANAEROBIC SLUDGE; BATCH EXPERIMENTS; COMPLEX LOADS; COMPOSITE SAMPLES; CONTRAST AGENT; ENRICHMENT TECHNIQUES; FILTER PRESS; HYDROPHILIC INTERACTION LIQUID CHROMATOGRAPHIES; ICP-SFMS; INDUCTIVELY COUPLED PLASMA SECTOR FIELD MASS SPECTROMETRY; INPUT AND OUTPUTS; ISOTOPE DILUTION ANALYSIS; LIMIT OF DETECTION; LIMIT OF QUANTIFICATIONS; SEWAGE PLANTS; SLUDGE DEWATERING; SPECIATION ANALYSIS; SPECIES TRANSFORMATION; STATIONARY PHASE; TREATMENT PLANTS; WASTEWATER SAMPLES;

CHROMATOGRAPHY; EFFLUENTS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; INDUCTIVELY COUPLED PLASMA; MAGNETIC RESONANCE IMAGING; RADIOISOTOPES; SEWAGE SLUDGE; SEWAGE TANKS; SEWAGE TREATMENT PLANTS;

GADOLINIUM;

GADOBENATE DIMEGLUMINE; GADOBUTROL; GADODIAMIDE; GADOLINIUM PENTETATE MEGLUMINE; GADOTERATE MEGLUMINE;

DILUTION; GADOLINIUM; INDUCTIVELY COUPLED PLASMA METHOD; ISOTOPIC ANALYSIS; LIQUID CHROMATOGRAPHY; QUANTITATIVE ANALYSIS; SAMPLING; SPECIATION (CHEMISTRY); WASTE TREATMENT; WASTEWATER;

ANALYTIC METHOD; ARTICLE; CHEMICAL STRUCTURE; COMPOSITE MATERIAL; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; ISOTOPE DILUTION ANALYSIS; NUCLEAR MAGNETIC RESONANCE IMAGING; SEWAGE EFFLUENT; SEWAGE TREATMENT; SPECIES DIFFERENTIATION;

CONTRAST MEDIA; ENVIRONMENTAL MONITORING; GADOLINIUM; INDICATOR DILUTION TECHNIQUES; WASTE WATER; WATER POLLUTANTS, CHEMICAL;

EID: 84868579570     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es301981z     Document Type: Article

References (15)

1. Idee, J. M.; Port, M.; Raynal, I.; Schaefer, M.; Le Greneur, S.; Corot, C. Clinical and biological consequences of transmetallation induced by contrast agents for magnetic resonance imaging: A review Fund. Clin. Pharmacol. 2006, 20, 563-576
2. Kümmerer, K.; Helmers, E. Hospital effluents as a source of gadolinium in the aquatic environment Environ. Sci. Technol. 2000, 34, 573-577
3. Bau, M.; Dulski, P. Anthropogenic origin of positive gadolinium anomalies in river waters Earth Planet. Sci. Lett. 1996, 143, 245-255
4. Bau, M.; Knappe, A.; Dulski, P. Anthropogenic gadolinium as a micropollutant in river waters in Pennsylvania, and in Lake Erie, northeastern United States Chem. Erde Geochem. 2006, 66, 143-152
5. Lawrence, M. G.; Ort, C..; Keller, J. Detection of anthropogenic gadolinium in treated wastewater in South East Queensland, Australia Water Res. 2009, 43, 3534-3540
6. Zhu, Y.; Hoshino, M.; Yamada, H.; Itoh, A.; Haraguchi, H. Gadolinium anomaly in the distributions of rare earth elements observed for coastal seawater and river waters around Nagoya City Bull. Chem. Soc. Jpn. 2004, 77, 1835-1842
7. Nozaki, Y.; Lerche, D.; Alibo, D. S.; Tsutsumi, M. Dissolved indium and rare earth elements in three Japanese rivers and Tokyo Bay: Evidence for anthropogenic Gd and In Geochim. Cosmochim. Acta 2000, 64, 3975-3982
8. Elbaz-Poulichet, F.; Seidel, J. L.; Othoniel, C. Occurrence of an anthropogenic gadolinium anomaly in river and coastal waters of Southern France Water Res. 2002, 36, 1102-1105
9. Rabiet, M.; Brissaud, F.; Seidel, J. L.; Pistre, S.; Elbaz-Poulichet, F. Positive gadolinium anomalies in wastewater treatment plant effluents and aquatic environment in the Hérault watershed (South France) Chemosphere 2009, 75, 1057-1064
10. Möller, P.; Paces, T.; Dulski, P.; Morteani, G. Anthropogenic Gd in Surface Water, Drainage Systems, and the Water Supply of the City of Prague, Czech Republic Environ. Sci. Technol. 2002, 36, 2387-2394
11. Verplanck, P. L.; Furlong, E. T.; Gray, J. L.; Phillips, P. J.; Wolf, R. E.; Esposito, K. Evaluating the behavior of gadolinium and other rare earth elements through large metropolitan sewage treatment plants Environ. Sci. Technol. 2010, 44, 3876-3882
12. Lawrence, M. G.; Keller, J.; Poussade, Y. Removal of magnetic resonance imaging contrast agents through advanced water treatment plants Water Sci. Technol. 2010, 31, 685-692
13. Künnemeyer, J.; Terborg, L.; Meermann, B.; Brauckmann, C.; Möller, I.; Scheffer, A.; Karst, U. Speciation analysis of gadolinium chelates in hospital effluents and wastewater treatment plant sewage by a novel HILIC/ICP-MS Method Environ. Sci. Technol. 2009, 43, 2884-2890
14. Ternes, T. A.; Kreckel, P.; Mueller, J. Behaviour and occurrence of estrogens in municipal sewage treatment plants Sci. Total Environ. 1999, 225, 91-99
15. Markert, B.; Piehler, H.; Lieth, H.; Sugimae, A. Normalization and calculations of lanthanide element concentrations in environmental samples Radiat. Environ. Biophys. 1989, 28, 213-221