Brill transition of nylon-6 in electrospun nanofibers

Colloid and Polymer Science

Volumn 290, Issue 17, 2012, Pages 1799-1809

  Wang, Chi ^a   Tsou, Shih Yung ^a   Lin, Hsuan Sheng ^a  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

Brill transition; Electrospinning; Melting; Nylon 6

Indexed keywords

AS-SPUN FIBERS; BRILL TRANSITION; CRYSTAL SIZE DIFFERENCE; CRYSTALLINE PHASE; ELECTROSPUN FIBERS; ELECTROSPUN NANOFIBERS; ELECTROSPUNS; EQUILIBRIUM MELTING TEMPERATURE; FIBER CRYSTALLINITY; FIBER MORPHOLOGY; FOURIER TRANSFORM INFRARED; FTIR; IN-SITU; NYLON-6; PLAUSIBLE MECHANISMS; POLYELECTROLYTE SOLUTIONS; SKIN LAYER; SKIN/CORE; SMALL ANGLE X-RAY SCATTERING; SOLUTION-CAST FILMS; STRUCTURAL EVOLUTION; WIDE-ANGLE X-RAY DIFFRACTION;

DIFFERENTIAL SCANNING CALORIMETRY; ELECTROSPINNING; FIBERS; FORMIC ACID; MELTING; MELTING POINT; PHASE TRANSITIONS; POLYAMIDES; X RAY DIFFRACTION;

RAYON;

FORMIC ACID; NANOFIBER; NYLON; POLICAPRAM; POLYELECTROLYTE; UNCLASSIFIED DRUG;

ARTICLE; BRILL TRANSITION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONCENTRATION RESPONSE; CONTROLLED STUDY; CRYSTALLIZATION; DIFFERENTIAL SCANNING CALORIMETRY; ELECTROSPINNING; FILM; HEATING; INFRARED SPECTROSCOPY; MELTING POINT; MOLECULAR WEIGHT; PARTICLE SIZE; PRIORITY JOURNAL; WIDE ANGLE X RAY DIFFRACTION; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 84868214993     PISSN: 0303402X     EISSN: 14351536     Source Type: Journal    
DOI: 10.1007/s00396-012-2724-9     Document Type: Article

References (30)

1. Murthy NS (2006) Hydrogen bonding, mobility, and structural transitions in aliphatic polyamides. J Polym Sci Polym Phys 44:1763
2. Liu X, Wu Q (2002) Phase transition in nylon 6/clay nanocomposites on annealing. Polymer 43:1933
3. Ramesh C, Gowd EB (2001) High-temperature X-ray diffraction studies on the crystalline transitions in the alpha- and gammaforms of nylon-6. Macromolecules 34:3308
4. Murthy NS, Curran SA, Aharoni SM, Minor H (1991) Premelting crystalline relaxations and phase-transitions in nylon-6 and 6,6. Macromolecules 24:3215
5. Vasanthan N, Murthy NS, Bray RG (1998) Investigation of Brill transition in nylon 6 and nylon 6,6 by infrared spectroscopy. Macromolecules 31:8433
6. Fong H, Liu W, Wang CS, Vaia RA (2002) Generation of electrospun fibers of nylon 6 and nylon 6-montmorillonite nanocomposite. Polymer 43:775
7. Dersch R, Liu T, Schaper AK, Greiner A, Wendoref JH (2003) Electrospun nanofibers: internal structure and intrinsic orientation. J Polym Sci Polym Chem 41:545
8. Lee KH, Kim KW, Pesapane A, Kim HY, Rabolt JF (2008) Polarized FT-IR study of macroscopically oriented electrospun nylon-6 nanofibers. Macromolecules 41:1494
9. Liu Y, Cui L, Guan F, Gao Y, Hedin NE, Zhu L, Fong H (2007) Crystalline morphology and polymorphic phase transitions in electrospun nylon-6 nanofibers. Macromolecules 40:6283
10. Giller CB, Chase DB, Rabolt JF, Snively CM (2010) Effect of solvent evaporation rate on the crystalline state of electrospun nylon 6. Polymer 51:4225
11. Tsou SY, Lin HS, Wang C (2011) Studies on the electrospun nylon 6 nanofibers from polyelectrolyte solutions: 1. Effects of solution concentration and temperature. Polymer 52:3127
12. Todoki M, Kawaguchi T (1977) Melting of constrained drawn nylon-6 yarns. J Polym Sci Polym Phys 15:1507
13. Kojima Y, Matsuoka T, Takahashi H, Kurauchi T (1994) Crystallization of nylon 6-clay hybrid by annealing under elevated pressures. J Appl Polym Sci 51:683
14. Medellin-Rodriguez FJ, Burger C, Hsiao BS, Chu B, Vaia R, Phillips S (2001) Time-resolved shear behavior of end-tethered nylon 6-clay nanocomposites followed by non-isothermal crystallization. Polymer 42:9015
15. Liu TX, Liu ZH, Ma KX, Shen L, Zeng KY, He CB (2003) Morphology, thermal and mechanical behavior of polyamide 6/layered-silicate nanocomposites. Compo Sci Technol 63:331
16. Winberg P, Eldrup M, Pedersen NJ, van Es MA, Maurer FHJ (2005) Free volume sizes in intercalated polyamide 6/clay nanocomposites. Polymer 46:8239
17. Yu J, Tonpheng B, Andersson O (2010) High-pressure-induced microstructural evolution and enhancement of thermal properties of nylon-6. Macromolecules 43:10512
18. Jeng US, Su CH, Su CJ, Liao KF, Chuang WT, Lai YH, Chang JW, Chen UJ, Huang YS, Lee MT, Yu KL, Lin JM, Liu DG, Chang CF, Liu CY, Chang CH, Liang KS (2010) A small/wide-angle X-ray scattering instrument for structural characterization of air-liquid interfaces, thin films and bulk specimens. J Appl Cryst 43:110
19. McKee MG, Wilkes GL, Colby RH, Long TE (2004) Correlations of solution rheology with electrospun fiber formation of linear and branched polyesters. Macromolecules 37:1760
20. Shenoy SL, Bates WD, Frisch HL, Wnek GE (2005) Role of chain entanglements on fiber formation during electrospinning of polymer solutions: good solvent, non-specific polymer-polymer interaction limit. Polymer 46:3372
21. McKee MG, Hunley MT, Layman JM, Long TE (2006) Solution rheological behavior and electrospinning of cationic polyelectrolytes. Macromolecules 39:575
22. Wunderlich B (1973) Macromolecular physics, vol 1. Academic, New York, p 389
23. Ibanes C, de Boissieu M, David L, Seguela R (2006) High temperature behaviour of the crystalline phases in unfilled and clayfilled nylon 6 fibers. Polymer 47:5071
24. Murthy NS, Wang ZG, Hsiao BS (1999) Interactions between crystalline and amorphous domains in semicrystalline polymers: small-angle X-ray scattering studies of the Brill transition in nylon 6,6. Macromolecules 32:5594
25. Ramesh C, Keller A, Eltink SJEA (1994) Studies on the crystallization and melting of nylon-6,6. 1. The dependence of the Brill transition on the crystallization temperature. Polymer 35:2483
26. Yang X, Tan S, Li G, Zhou E (2001) Dependence of the Brill transition on the crystal size of nylon 10 10. Macromolecules 34:5936
27. Tosaka M, Yamaguchi K, Tsuji M (2010) Latent orientation in the skin layer of electrospun isotactic polystyrene ultrafine fibers. Polymer 51:547
28. Czaputa K, Brenn G, Meile W (2008) Concentration profiles in drying cylindrical filaments. Heat Mass Transf 45:227
29. Sano Y (2001) Dry behavior of acetate filament in dry spinning. Drying Technol 19:1335
30. Koombhongse S, Liu W, Reneker DH (2001) Flat polymer ribbons and other shapes by electrospinning. J Polym Sci Polym Phys 39:2598