NbF 5 additive improves hydrogen release from magnesium borohydride

International Journal of Hydrogen Energy

Volumn 37, Issue 23, 2012, Pages 17671-17677

  Al Kukhun, Ahmad ^a   Hwang, Hyun Tae ^a   Varma, Arvind ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

Dehydrogenation; Hydrogen storage; Magnesium borohydride; Metal complex hydrides; Niobium fluoride

Indexed keywords

BOROHYDRIDES; DEHYDROGENATION PROPERTIES; HYDROGEN RELEASE; HYDROGEN YIELDS; METAL-COMPLEX HYDRIDES; MODERATE TEMPERATURE; NMR ANALYSIS;

ADDITIVES; DEHYDROGENATION; HYDROGEN PRODUCTION; HYDROGEN STORAGE; MAGNESIUM; MASS SPECTROMETRY; METAL COMPLEXES; NIOBIUM; THERMOGRAVIMETRIC ANALYSIS;

HYDROGEN;

EID: 84868211846     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.09.097     Document Type: Article

References (27)

1. L. Schlapbach, and A. Zuttel Hydrogen-storage materials for mobile applications Nature 414 2001 353 358 (Pubitemid 33097818)
2. S. Satyapal, J. Petrovic, C. Read, G. Thomas, and G. Ordaz The US Department of Energy's National Hydrogen Storage Project: progress towards meeting hydrogen-powered vehicle requirements Catal Today 120 2007 246 256 (Pubitemid 46135909)
3. A. Al-Kukhun, H.T. Hwang, and A. Varma A comparison of ammonia borane dehydrogenation methods for proton-exchange-membrane fuel cell vehicles: hydrogen yield and ammonia formation and its removal Ind Eng Chem Res 50 2011 8824 8835
4. I.P. Jain, P. Jain, and A. Jain Novel hydrogen storage materials: a review of lightweight complex hydrides J Alloy Compd 503 2010 303 339
5. S. McWhorter, C. Read, G. Ordaz, and N. Stetson Materials-based hydrogen storage: attributes for near-term, early market PEM fuel cells Curr Opin Solid St M 15 2011 29 38
6. B. Sakintuna, F. Lamari-Darkrim, and M. Hirscher Metal hydride materials for solid hydrogen storage: a review Int J Hydrogen Energ 32 2007 1121 1140 (Pubitemid 46777202)
7. E. Fakioglu, Y. Yurum, and T.N. Veziroglu A review of hydrogen storage systems based on boron and its compounds Int J Hydrogen Energ 29 2004 1371 1376
8. C. Li, P. Peng, D.W. Zhou, and L. Wan Research progress in LiBH(4) for hydrogen storage: a review Int J Hydrogen Energ 36 2011 14512 14526
9. E. Ronnebro Development of group II borohydrides as hydrogen storage materials Curr Opin Solid St M 15 2011 44 51
10. 4 catalyzed by titanium-based additives J Phys Chem C 116 2012 1596 1604
11. H.W. Li, Y.G. Yan, S. Orimo, A. Zuttel, and C.M. Jensen Recent progress in metal borohydrides for hydrogen storage Energies 4 2011 185 214
12. G.L. Soloveichik, Y. Gao, J. Rijssenbeek, M. Andrus, S. Kniajanski, and R.C. Bowman Magnesium borohydride as a hydrogen storage material: properties and dehydrogenation pathway of unsolvated Mg(BH(4))(2) Int J Hydrogen Energ 34 2009 916 928
13. X.B. Yu, D.M. Grant, and G.S. Walker Dehydrogenation of LiBH(4) destabilized with various oxides J Phys Chem C 113 2009 17945 17949
14. M. An, and A. Jurgensen Modified lithium borohydrides for reversible hydrogen storage J Phys Chem B 110 2006 7062 7067 (Pubitemid 43675369)
15. 4 a new hydrogen storage material J Power Sources 118 2003 1 7 (Pubitemid 41325593)
16. B.J. Zhang, and B.H. Liu Hydrogen desorption from LiBH(4) destabilized by chlorides of transition metal Fe, Co, and Ni Int J Hydrogen Energ 35 2010 7288 7294
17. J.F. Mao, Z.P. Guo, X.B. Yu, and H.K. Liu Enhanced hydrogen sorption properties in the LiBH(4)-MgH(2) system catalysed by Ru nanoparticles supported on multiwalled carbon nanotubes J Alloy Compd 509 2011 5012 5016
18. 2) J Phys Chem C 111 2007 19134 19140
19. G. Severa, E. Ronnebro, and C.M. Jensen Direct hydrogenation of magnesium boride to magnesium borohydride: demonstration of >11 weight percent reversible hydrogen storage Chem Commun 46 2010 421 423
20. M. Fichtner, Z. Zhao-Karger, J.J. Hu, A. Roth, and P. Weidler The kinetic properties of Mg(BH(4))(2) infiltrated in activated carbon Nanotechnology 2009 20
21. H.W. Li, K. Kikuchi, Y. Nakamori, K. Miwa, S. Towata, and S. Orimo Effects of ball milling and additives on dehydriding behaviors of well-crystallized Mg(BH(4))(2) Scripta Mater 57 2007 679 682 (Pubitemid 47102707)
22. R.J. Newhouse, V. Stavila, S.J. Hwang, L.E. Klebanoff, and J.Z. Zhang Reversibility and improved hydrogen release of magnesium borohydride J Phys Chem C 114 2010 5224 5232
23. 5 J Alloy Compd 453 2008 138 142 (Pubitemid 351329545)
24. J.W. Kim, J.P. Ahn, S.A. Jin, S.H. Lee, H.S. Chung, and J.H. Shim Microstructural evolution of NbF(5)-doped MgH(2) exhibiting fast hydrogen sorption kinetics J Power Sources 178 2008 373 378
25. J.H. Kim, J.H. Shim, and Y.W. Cho On the reversibility of hydrogen storage in Ti- and Nb-catalyzed Ca(BH(4))(2) J Power Sources 181 2008 140 143
26. Y.G. Yan, H.W. Li, H. Maekawa, M. Aoki, T. Noritake, and M. Matsumoto Formation process of [B(12)H(12)](2-) from [BH(4)](-) during the dehydrogenation reaction of Mg(BH(4))(2) Mater Trans 52 2011 1443 1446
27. N. Hanada, K. Chopek, C. Frommen, W. Lohstroh, and M. Fichtner Thermal decomposition of Mg(BH(4))(2) under He flow and H(2) pressure J Mater Chem 18 2008 2611 2614 (Pubitemid 351718093)