CTAB/water/Chloroform reverse micelles: A closed or open association model?

Langmuir

Volumn 28, Issue 43, 2012, Pages 15185-15192

  Klíčová, L'Ubica ^a   Šebej, Peter ^a   Štacko, Peter ^a   Filippov, Sergey K ^b   Bogomolova, Anna ^b   Padilla, Marc ^a   Klán, Petr ^a  

^a MASARYK UNIVERSITY   (Czech Republic)

^b INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Czech Republic)

Author keywords

[No Author keywords available]

Indexed keywords

ASSOCIATION MODELS; AVERAGE VALUES; CETYLTRIMETHYLAMMONIUM BROMIDE; CETYLTRIMETHYLAMMONIUM CHLORIDE; CMC VALUES; CONCENTRATION RANGES; CONDUCTOMETRY; CRITICAL MICELLE CONCENTRATION (CMC); INVERSE MICELLES; ISOTHERMAL TITRATION CALORIMETRY; MICROENVIRONMENTS; MULTIPLE EQUILIBRIUM; NMR ANALYSIS; NMR SIGNALS; PREMICELLAR AGGREGATES; PRESENCE OF WATER; REVERSE MICELLES; STRUCTURAL REORGANIZATION; UPPER LIMITS;

AGGREGATES; AMMONIUM COMPOUNDS; CHLORINE COMPOUNDS; CRITICAL MICELLE CONCENTRATION; MICELLIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

MICELLES;

EID: 84868158520     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la303245e     Document Type: Article

References (49)

1. Dhar, S.; Rana, D. K.; Sarkar, A.; Mandal, T. K.; Ghosh, S.; Bhattacharya, S. C. Physicochemical characterization of reverse micelles of Triton X using 1-anthracene sulphonate as fluorescent probe: A spectroscopic study Colloid Surf., A 2009, 349, 117-124
2. Desando, M. A.; Lahajnar, G.; Sepe, A. Proton magnetic relaxation and the aggregation of n -octylammonium n -octadecanoate surfactant in deuterochloroform solution J. Colloid Interface Sci. 2010, 345, 338-345
3. Tran, C. D.; Yu, S. F. Near-infrared spectroscopic method for the sensitive and direct determination of aggregations of surfactants in various media J. Colloid Interface Sci. 2005, 283, 613-618
4. Anand, U.; Jash, C.; Mukherjee, S. Spectroscopic determination of critical micelle concentration in aqueous and non-aqueous media using a non-invasive method J. Colloid Interface Sci. 2011, 364, 400-406
5. Huang, C. C.; Hohn, K. L. Tetrakis(dimethylamino)ethylene chemiluminescence (TDE CL) characterization of the CMC and the viscosity of reversed microemulsions J. Chem. Phys. B 2010, 114, 2685-2694
6. Majhi, P. R.; Moulik, S. P. Microcalorimetric investigation of AOT self-association in oil and the state of pool water in water/oil microemulsions J. Chem. Phys. B 1999, 103, 5977-5983
7. Ghosh, S. K.; Khatua, P. K.; Bhattacharya, S. C. Physicochemical characteristics of reverse micelles of polyoxyethylene nonyl phenol in different organic solvents J. Colloid Interface Sci. 2004, 279, 523-532
8. Nakashima, T.; Fujiwara, T. Effects of surfactant counter-ions and added salts on reverse micelle formation of cetyltrimethylammonium surfactant studied by using (5,10,15,20-tetraphenylporphyrinato)-zinc(II) as a probe Anal. Sci. 2001, 17, 1241-1244
9. Eicke, H.-F. Surfactants in nonpolar solvents. Aggregation and micellization Top. Curr. Chem. 1980, 87, 85-145
10. Verbeeck, A.; Geladé, E.; De Schryver, F. C. Aggregation behavior in inverse micellar systems-Spectroscopic evidence for a unified model Langmuir 1986, 2, 448-456
11. Zana, R.; Lang, J.; Canet, D. Ternary water-in-oil microemulsions made of cationic surfactants, water, and aromatic solvents. 3. Self-diffusion studies in relation to exchange of material between droplets and percolation J. Phys. Chem. 1991, 95, 3364-3367
12. Dokter, A. M.; Woutersen, S.; Bakker, H. J. Ultrafast dynamics of water in cationic micelles J. Chem. Phys. 2007, 126, 124507
13. Mukherjee, K.; Mukherjee, D. C.; Moulik, S. P. Thermodynamics of microemulsion formation. 3. Enthalpies of solution of water in chloroform as well as chloroform in water aided by cationic, anionic, and nonionic surfactants J. Colloid Interface Sci. 1997, 187, 327-333
14. Lang, J.; Mascolo, G.; Zana, R.; Luisi, P. L. Structure and dynamics of cetyltrimethylammonium bromide water-in-oil microemulsions J. Phys. Chem. 1990, 94, 3069-3074
15. 1H NMR studies on the structure of water solubilized by reverse aggregates of dodecyltrimethylammonium bromide; didodecyldimethylammonium bromide, and their mixtures in organic solvents Prog. Colloid Polym. Sci. 2008, 134, 101-110
16. Nandi, S.; Bhattacharya, S. C.; Moulik, S. P. Effects of additives (NaCl, urea, glucose, guanidine hydrochloride) on the physico-chemical properties of reverse micelles of Tweens in chloroform Indian J. Chem., Sect. A 2000, 39, 589-597
17. Hasegawa, M.; Yamasaki, Y.; Sonta, N.; Shindo, Y.; Sugimura, T.; Kitahara, A. Clustering of AOT reversed micelles as studied by nonradiative energy transfer of solubilized probes J. Phys. Chem. 1996, 100, 15575-15580
18. Olesik, S. V.; Miller, C. J. Critical micelle concentration of AOT in supercritical alkanes Langmuir 1990, 6, 183-187
19. Jean, Y. C.; Ache, H. J. Study of micelle formation and effect of additives on this process in reversed micellar systems by positron-annihilation techniques J. Am. Chem. Soc. 1978, 100, 6320-6327
20. Baruah, B.; Swafford, L. A.; Crans, D. C.; Levinger, N. E. Do probe molecules influence water in confinement? J. Chem. Phys. B 2008, 112, 10158-10164
21. Crans, D. C.; Rithner, C. D.; Baruah, B.; Gourley, B. L.; Levinger, N. E. Molecular probe location in reverse micelles determined by NMR dipolar interactions J. Am. Chem. Soc. 2006, 128, 4437-4445
22. Blandamer, M. J.; Cullis, P. M.; Soldi, L. G.; Engberts, J.; Kacperska, A.; Vanos, N. M.; Subha, M. C. S. Thermodynamics of micellar systems: Comparison of mass action and phase equilibrium models for the calculation of standard Gibbs energies of micelle formation Adv. Colloid Interface Sci. 1995, 58, 171-209
23. Nyrkova, I. A.; Semenov, A. N. Multimerization: Closed or open association scenario? Eur. Phys. J. E: Soft Matter Biol. Phys. 2005, 17, 327-337
24. Eicke, H. F.; Christen, H. Nucleation process of micelle formation in apolar solvents J. Colloid Interface Sci. 1974, 48, 281-290
25. Muller, N. Multiple-equilibrium model for the micellization of ionic surfactants in nonaqueous solvents J. Phys. Chem. 1975, 79, 287-291
26. Emin, S. M.; Denkova, P. S.; Papazova, K. I.; Dushkin, C. D.; Adachi, E. Study of reverse micelles of di-isobutylphenoxyethoxyethyldimethylbenzylammonium methacrylate in benzene by nuclear magnetic resonance spectroscopy J. Colloid Interface Sci. 2007, 305, 133-141
27. Faure, A.; Tistchenko, A. M.; Zemb, T.; Chachaty, C. Aggregation and dynamical behavior in sodium diethylhexyl phosphate/water/benzene inverted micelles J. Phys. Chem. 1985, 89, 3373-3378
28. Luchetti, L.; Mancini, G. NMR investigation on the various aggregates formed by a gemini chiral surfactant Langmuir 2000, 16, 161-165
29. Yan, J. F.; Palmer, M. B. A nuclear magnetic resonance method for determination of critical micelle concentration J. Colloid Interface Sci. 1969, 30, 177-182
30. Guo, Q.; Singh, V.; Behrens, S. H. Electric charging in nonpolar liquids because of nonionizable surfactants Langmuir 2010, 26, 3203-3207
31. Eicke, H. F.; Hopmann, R. F. W.; Christen, H. Kinetics of conformational change during micelle formation in apolar media Ber. Bunsen-Ges. 1975, 79, 667-673
32. Verbeeck, A.; Voortmans, G.; Jackers, C.; De Schryver, F. C. Characterization and stabilization of inverse micelles Langmuir 1989, 5, 766-776
33. Djermouni, B.; Ache, H. J. Effect of temperature and counterion on the micelle formation process studied by positron-annihilation techniques J. Phys. Chem. 1979, 83, 2476-2479
34. Fucugauchi, L. A.; Djermouni, B.; Handel, E. D.; Ache, H. J. Study of micelle formation in solutions of alkylammonium carboxylates in apolar solvents by positron-annihilation techniques J. Am. Chem. Soc. 1979, 101, 2841-2844
35. Gottlieb, H. E.; Kotlyar, V.; Nudelman, A. NMR chemical shifts of common laboratory solvents as trace impurities J. Org. Chem. 1997, 62, 7512-7515
36. Warr, G. G.; Sen, R.; Evans, D. F.; Trend, J. E. Microemulsion formation and phase behavior of dialkydimethylammonium bromide surfactants J. Phys. Chem. 1988, 92, 774-783
37. Weidemaier, K.; Tavernier, H. L.; Fayer, M. D. Photoinduced electron transfer on the surfaces of micelles J. Chem. Phys. B 1997, 101, 9352-9361
38. Khan, A. M.; Shah, S. S. Determination of critical micelle concentration (Cmc) of sodium dodecyl sulfate (SDS) and the effect of low concentration of pyrene on its Cmc using Origin software J. Chem. Soc. Pak. 2008, 30, 186-191
39. Hait, S. K.; Moulik, S. P.; Palepu, R. Refined method of assessment of parameters of micellization of surfactants and percolation of W/O microemulsions Langmuir 2002, 18, 2471-2476
40. Tariq, M.; Podgorsek, A.; Ferguson, J. L.; Lopes, A.; Gomes, M. F. C.; Padua, A. A. H.; Rebelo, L. P. N.; Lopes, J. N. C. Characteristics of aggregation in aqueous solutions of dialkylpyrrolidinium bromides J. Colloid Interface Sci. 2011, 360, 606-616
41. Hu, H. S. Determination of vapour-liquid and vapour-liquid-liquid equilibrium of the chloroform-water and trichloroethylene-water binary mixtures Fluid Phase Equilib. 2010, 289, 80-89
42. Becker, E. D. High Resolution NMR; Academic Press, Inc.: New York, 1972.
43. Eisenberg, D.; Kaufman, W. The Structure and Properties of Water; Oxford University Press: London, 1969.
44. Zhang, J.; Bright, F. V. Nanosecond reorganization of water within the interior of reversed micelles revealed by frequency-domain fluorescence spectroscopy J. Phys. Chem. 1991, 95, 7900-7907
45. Almgren, M.; Lofroth, J.-E. Effects of polydispersity on fluorescence quenching in micelles J. Chem. Phys. 1982, 76, 2734-2743
46. Sainis, S. K.; Merrill, J. W.; Dufresne, E. R. Electrostatic interactions of colloidal particles at vanishing ionic strength Langmuir 2008, 24, 13334-13337
47. Hsu, M. F.; Dufresne, E. R.; Weitz, D. A. Charge stabilization in nonpolar solvents Langmuir 2005, 21, 4881-4887
48. Roberts, G. S.; Sanchez, R.; Kemp, R.; Wood, T.; Bartlett, P. Electrostatic charging of nonpolar colloids by reverse micelles Langmuir 2008, 24, 6530-6541
49. Eicke, H. F.; Borkovec, M.; Dasgupta, B. Conductivity of water-in-oil microemulsions: A quantitative charge fluctuation model J. Phys. Chem. 1989, 93, 314-317