Nucleophilic fluoroalkylation of α,β-unsaturated carbonyl compounds with α-fluorinated sulfones: Investigation of the reversibility of 1,2-additions and the formation of 1,4-adducts

Helvetica Chimica Acta

Volumn 95, Issue 10, 2012, Pages 2043-2051

  Shen, Xiao ^a   Ni, Chuanfa ^a   Hu, Jinbo ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

Carbonyl compounds, , unsaturated; Fluorine compounds; Fluoroalkylation; Nucleophilic fluoroalkylation

Indexed keywords

CHALCONES; CONTROLLED EXPERIMENT; FLUOROALKYLATION; KINETICALLY CONTROLLED; LOW TEMPERATURES; NUCLEOPHILIC FLUOROALKYLATION; REACTION PATHWAYS; RELATIVE RATES; UNSATURATED CARBONYL COMPOUNDS;

FLUORINE COMPOUNDS; ISOMERIZATION; NEGATIVE IONS;

CARBONYL COMPOUNDS;

ANION; CARBONYL DERIVATIVE; CHALCONE; SULFONE;

ADDITION REACTION; ALKYLATION; ARTICLE; CHEMICAL STRUCTURE; ISOMERIZATION; KINETICS; LOW TEMPERATURE; NUCLEOPHILICITY; PRIORITY JOURNAL; THERMODYNAMICS;

EID: 84867695880     PISSN: 0018019X     EISSN: 15222675     Source Type: Journal    
DOI: 10.1002/hlca.201200445     Document Type: Article

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