Lipase-catalyzed transesterification synthesis of citronellyl acetate in a solvent-free system and its reaction kinetics

European Food Research and Technology

Volumn 235, Issue 5, 2012, Pages 907-914

  Xiong, Jian ^a   Huang, Ya Juan ^a   Zhang, Hua ^a  

^a YANGZHOU UNIVERSITY   (China)

Author keywords

Citronellyl acetate; Kinetics; Lipase; Solvent free system; Transesterification

Indexed keywords

AGITATION SPEED; CITRONELLOL; CITRONELLYL ACETATE; DIFFUSION LIMITATIONS; ENZYME LOADS; EXPERIMENTAL VALUES; INTERNAL DIFFUSION; LINEAR RELATIONSHIPS; LIPASE-CATALYZED; MODEL PARAMETERS; OPTIMAL REACTION TEMPERATURE; PING-PONG BI-BI MECHANISM; PRODUCT INHIBITION; PSEUDOMONAS FLUORESCENS; RELATIVE ERRORS; SOLVENT-FREE SYSTEM; SUBSTRATE CONCENTRATIONS; SUBSTRATE INHIBITION;

ASSOCIATION REACTIONS; CATALYSIS; ENZYME KINETICS; KINETICS; MATLAB; REACTION RATES; SOLVENTS; TRANSESTERIFICATION; VOLATILE FATTY ACIDS;

LIPASES;

PSEUDOMONAS FLUORESCENS;

EID: 84867694371     PISSN: 14382377     EISSN: 14382385     Source Type: Journal    
DOI: 10.1007/s00217-012-1819-3     Document Type: Article

References (22)

1. Tozoni D, Zacaria J, Vanderlinde R, Delamare APL, Echeverrigaray S (2010) Degradation of citronellol, citronellal and citronellyl acetate by Pseudomonas mendocina IBPse 105. Electron J Biotechnol 13: 1-7.
2. Yahya ARM, Anderson WA, Moo-Young M (1998) Ester synthesis in lipase catalyzed reactions. Enzym Microb Technol 23: 438-450.
3. You PY, Su EZ, Yang XP, Mao DB, Wei DZ (2011) Carica papaya lipase-catalyzed synthesis of terpene esters. J Mol Catal B Enzym 71: 152-158.
4. Dhakea KP, Deshmukha KM, Patil YP, Singhal RS, Bhanagea BM (2011) Improved activity and stability of Rhizopus oryzae lipase via immobilization for citronellol ester synthesis in supercritical carbon dioxide. J Biotechnol 156: 46-51.
5. Sun P, Chen YY, Wang H, Li J, Gao J, Wang HB, Zheng XY, Zhang SK (2011) Lipase-catalyzed synthesis and characterization of myristoyl maltose ester. Eur Food Res Technol 233: 253-258.
6. Maja H, Saga S, Muzafera P (2007) Lipase-catalyzed esterification of citronellol with lauric acid in supercritical carbon dioxide/co-solvent media. J Supercrit Fluids 42: 199-203.
7. Yadav GD, Devendran S (2012) Lipase catalyzed synthesis of cinnamyl acetate via transesterification in non-aqueous medium. Process Biochem 47: 496-502.
8. Castro HF, Oliveira PC, Pereira EB (1997) Evaluation of different approaches for lipase catalysed synthesis of citronellyl acetate. Biotechnol Lett 19: 229-232.
9. Akoh CA, Yee LN (1998) Lipase-catalyzed transesterification of primary terpene alcohols with vinyl esters in organic media. J Mol Catal B Enzym 4: 149-153.
10. Claon PA, Akoh CC (1994) Lipase-catalyzed synthesis of primary terpenyl acetates by transesterification: study of reaction parameters. J Agric Food Chem 42: 2349-2352.
11. Ducret A, Trani M, Lortie R (1998) Lipase catalyzed enantioselective esterification of ibuprofen in organic solvents under controlled water activity. Enzyme Mcirob Technol 22: 212-216.
12. Garecia-Alles LF, Gotor V (1998) Lipase-catalyzed transesterification in organic media: solvent effects on equilibrium and individual rate constants. Biotechnol Bioeng 59: 684-694.
13. Wang N (2009) Biosynthesis of citronellyl esters using lipase from Rhizopus chinensis in non-aqueous phase[D]. Jiangnan University, Wuxi.
14. Macedo GA, Lozano MMS, Pastore GM (2004) Enzymatic synthesis of short chain citronellyl esters by a new lipase from Rhizopus sp. Electron J Biotechnol 7: 72-75.
15. Yadav GD, Borkar IV (2009) Kinetic and mechanistic investigation of microwave-assisted lipase catalyzed synthesis of citronellyl acetate. Ind Eng Chem Res 48: 7915-7922.
16. Uppenberg J, Patkar S, Bergfors T, Jones TA (1994) Crystallization and preliminary X-ray studies of lipase B from Candida antarctica. J Mol Biol 235: 790-792.
17. Ganapati D, Yadav K, Manjula D (2004) Immobilization lipase-catalysed esterfication and transesterification reactions in non-aqueous media for the synthesis of tetrahydrofurfuryl butyrate: comparison and kinetic modeling. Chem Eng Sci 59: 373-383.
18. Chulalaksananukui W, Condoret JS, Combes D (1992) Kinetics of geranyl acetate synthesis by lipase-catalyzed transesterification in n-hexane. Enzym Microb Technol 14: 293-298.
19. Rizzi M, Stylos P, Riek A, Reuss MA (1992) kinetic study of immobilized lipase catalysing the synthesis of isoamyl acetate by transesterification in n-hexane. Enzym Microb Technol 14: 709-714.
20. Wang SZ, Wu JP, Xu G, Yang LR (2009) Kinetic modelling of lipase-catalyzed remote resolution of citalopram intermediate in solvent-free system. Biochem Eng J 45: 113-119.
21. Xin JY, Chen LL, Zhang YX, Zhang S, Xia CG (2011) Lipase-catalyzed transesterification of ethyl ferulate with triolein in solvent-free medium. Food Bioprod Process 89: 457-462.
22. Chulalaksananukul W, Condoret JS, Combes D (1993) Geranyl acetate synthesis by lipase-catalyzed transesterification in supercritical carbon-dioxide. Enzym Microb Technol 15: 691-696.