Kinetics of glycerol dehydration with WO 3/TiO 2 in supercritical water

Industrial and Engineering Chemistry Research

Volumn 51, Issue 38, 2012, Pages 12253-12257

  Akizuki, Makoto ^a   Oshima, Yoshito ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

FIXED BED-FLOW REACTOR; HIGH WATER; INTERMEDIATE PRODUCT; KINETIC ANALYSIS; PROPIONIC ACIDS; REACTION ROUTES; SUPERCRITICAL WATER; SURFACE AREA; TIO;

ACETALDEHYDE; CATALYSTS; DEHYDRATION; GLYCEROL; HERBICIDES; OXIDE MINERALS; REACTION INTERMEDIATES; REACTION RATES;

TITANIUM DIOXIDE;

EID: 84867536081     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie301823f     Document Type: Article

References (24)

1. Ederer, H. J.; Buhler, W.; Dinjus, E.; Kruse, A.; Mas, C. Ionic reactions and pyrolysis of glycerol as competing reaction pathways in near- and supercritical water. J. Supercrit. Fluids 2002, 22, 37.
2. Watanabe, M.; Iida, T.; Aizawa, Y.; Aida, T. M.; Inomata, H. Acrolein synthesis from glycerol in hot-compressed water. Bioresour. Technol. 2007, 98, 1285.
3. Ott, L.; Bicker, M.; Vogel, H. Catalytic dehydration of glycerol in sub- and supercritical water: A new chemical process for acrolein production. Green Chem. 2006, 8, 214.
4. Tsukuda, E.; Sato, S.; Takahashi, R.; Sodesawa, T. Production of acrolein from glycerol over silica-supported heteropoly acids. Catal. Commun. 2007, 8, 1349.
5. Suprun, W.; Lutecki, M.; Haber, T.; Papp, H. Acidic catalysts for the dehydration of glycerol: Activity and deactivation. J. Mol. Catal. A: Chem 2009, 309, 71.
6. Corma, A.; Huber, G.; Sauvanaud, L.; Oconnor, P. Biomass to chemicals: Catalytic conversion of glycerol/water mixtures into acrolein, reaction network. J. Catal. 2008, 257, 163.
7. Ulgen, A.; Hoelderich, W. F. Conversion of glycerol to acrolein in the presence of WO3/TiO2 catalysts. Appl. Catal., A 2011, 400, 34.
8. Ramayya, S.; Brittain, A.; DeAlmeida, C.; Mok, W.; Antal, M. J., Jr Acid-Catalysed dehydration of alcohols in supercritical water. Fuel 1987, 66, 1364.
9. Kishida, H.; Jin, F.; Zhou, Z.; Moriya, T.; Enomoto, H. Conversion of glycerin into lactic acid by alkaline hydrothermal reaction. Chem. Lett. 2005, 34, 1560.
10. Watanabe, M.; Aizawa, Y.; Iida, T.; Nishimura, R.; Inomata, H. Catalytic glucose and fructose conversions with TiO2 and ZrO2 in water at 473 K: Relationship between reactivity and acid-base property determined by TPD measurement. Appl. Catal., A 2005, 295, 150.
11. Chareonlimkun, A.; Champreda, V.; Shotipruk, A.; Laosiripojana, N. Catalytic conversion of sugarcane bagasse, rice husk and corncob in the presence of TiO2, ZrO2 and mixed-oxide TiO2-ZrO2 under hot compressed water (HCW) condition. Bioresour. Technol. 2010, 101, 4179.
12. Sridhar, T.; Mahajani, S. M.; Shanna, M. M. Direct Hydration of propylene in liquid phase and under supercritical conditions in the presence of solid acid catalysts. Chem. Eng. Sci. 2002, 57, 4877.
13. Tomita, K.; Oshima, Y. Enhancement of the catalytic activity by an ion product of sub- and supercritical water in the catalytic hydration of propylene with metal oxide. Ind. Eng. Chem. Res. 2004, 43, 2345.
14. Yuan, P.-Q.; Liu, Y.; Bai, F.; Xu, L.; Cheng, Z.-M.; Yuan, W.-K. Hydration of cyclohexene in sub-critical water over WOx-ZrO2 catalysts. Catal. Commun. 2011, 12, 753.
15. Akizuki, M.; Tomita, K.; Oshima, Y. Kinetics of solid acid catalyzed 1-octene reactions with TiO2 in sub- and supercritical water. J. Supercrit. Fluids 2011, 56, 14.
16. Watanabe, M.; Iida, T.; Aizawa, Y.; Ura, H.; Inomata, H.; Arai, K. Conversions of some small organic compounds with metal oxides in supercritical water at 673 K. Green Chem. 2003, 5, 539.
17. Yamaguchi, T.; Tanaka, Y.; Tanabe, K. Isomerization and disproportionation of olefins over tungsten oxides supported on various oxides. J. Catal. 1980, 65, 442.
18. Benesi, H. A. Acidity of catalyst surfaces. II. Amine titration using hammett indicators. J. Phys. Chem. 1957, 61, 970.
19. Depero, L. E. Influence of vanadium and tungsten substitution on the stability of anatase. J. Solid State Chem. 1993, 104, 470.
20. Hall, R. H.; Stern, E. S. Acid-catalysed hydration of acraldehyde. kinetics of the reaction and isolation of β-hydroxypropaldehyde. J. Chem. Soc. 1950, 490.
21. Mok, W. S. L.; Antal, M. J.; Jones, M. Formation of acrylic-acid from lactic-acid in supercritical water. J. Org. Chem. 1989, 54, 4596.
22. Muller, C.; Michel, V.; Scacchi, G.; Come, G. M. THERGAS - A computer program for the evaluation of thermochemical data of molecules and free radicals in the gas phase. J. Chim. Phys. Phys. Chim. Biol 1995, 92, 1154.
23. Tao, L.-Z.; Chai, S.-H.; Zuo, Y.; Zheng, W.-T.; Liang, Y.; Xu, B.-Q. Sustainable production of acrolein: Acidic binary metal oxide catalysts for gas-phase dehydration of glycerol. Catal. Today 2010, 158, 310.
24. Ramis, G.; Busca, G.; Cristiani, C.; Lietti, L.; Forzatti, P.; Bregani, F. Characterization of tungsta-titania catalysts. Langmuir 1992, 8, 1744.