High-selectivity bis(imino)pyridine iron catalysts for the hydrosilylation of 1,2,4-trivinylcyclohexane

ACS Catalysis

Volumn 2, Issue 10, 2012, Pages 2169-2172

  Atienza, Crisita Carmen Hojilla ^a   Tondreau, Aaron M ^a   Weller, Keith J ^b   Lewis, Kenrick M ^c   Cruse, Richard W ^c   Nye, Susan A ^b   Boyer, Julie L ^b   Delis, Johannes G P ^d   Chirik, Paul J ^a  

^a PRINCETON UNIVERSITY   (United States)

^b Momentive Performance Materials   (United States)

^c Momentive Performance Materials   (United States)

^d Momentive Performance Materials Bv   (Netherlands)

Author keywords

Catalysis; Hydrosilylation; Iron; Silane; Trivinylcyclohexene

Indexed keywords

DINITROGEN COMPLEXES; IRON CATALYST; TRIVINYLCYCLOHEXENE;

CATALYSIS; IRON; IRON COMPOUNDS; OLEFINS; PLATINUM COMPOUNDS; PYRIDINE; SILANES;

HYDROSILYLATION;

EID: 84867510141     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs300584b     Document Type: Article

References (18)

1. Cornilis, B.; Hermann, W. A. Applied Homogeneous Catalysis with Organometallic Compounds; VCH: Weinheim, Germany, 1996.
2. Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H. Comprehensive Asymmetric Catalysis; Springer: Berlin, New York, 2004.
3. Lautenschlager, H.; Herzig, C. US Patent 7, 153, 912; Dec 26, 2006.
4. Lautenschlager, H.; Stallbauer, R. US Patent 7, 153, 913; Dec 26, 2006.
5. Herzig, C. US Patent 6, 265, 497; July 24, 2001.
6. Chen, G. J.; Snyder, C. E.; Eapen, K. C. US Patent 6, 278, 011; Aug 21, 2001.
7. Friedman, G.; Sperry, P.; Brossas, J. US Patent 5, 166, 298; Nov 24, 1992.
8. Cruse, R. W.; York, W. M.; Pohl, E. R.; Joshi, P. US Patent 7, 696, 269; April 13, 2010.
9. Marciniec, B.; Gulinski, J.; Urbaniak, W.; Kornetka, Z. W. In Comprehensive Handbook of Hydrosilylation; Marciniec, B., Ed.; Pergamon: Oxford, 2002, pp 3-7.
10. Details on the separation and assignment of the various TVCH isomers have been reported. See: Lewis, K. M.; Tondreau, A. M; Cruse, R. W.; Weller, K. J.; Delis, J. G. P.; Nye, S. A.; Chirik, P. J. US2012/0130105 A1.
11. Marciniec, B. Coord. Chem. Rev. 2005, 249, 2374.
12. Bart, S. C.; Lobkovsky, E.; Chirik, P. J. J. Am. Chem. Soc. 2004, 126, 13794.
13. Tondreau, A. M.; Atienza, C. C. H.; Weller, K. J.; Nye, S. A.; Lewis, K. M.; Delis, J. G. P.; Chirik, P. J. Science 2012, 335, 567.
14. Tondreau, A. M.; Atienza, C. C. H.; Darmon, J. M.; Milsmann, C.; Hoyt, H. M.; Weller, K. J.; Nye, S. A.; Lewis, K. M.; Boyer, J.; Delis, J. G. P.; Lobkovsky, E.; Chirik, P. J. Organometallics 2012, 31, 4886.
15. Russell, S. K.; Darmon, J. M.; Lobkovsky, E.; Chirik, P. J. Inorg. Chem. 2010, 49, 2782.
16. Darmon, J. M.; Turner, Z. R.; Lobkovsky, E.; Chirik, P. J. Organometallics 2012, 31, 2275.
17. Special care should be exercised in handling and working with triethoxysilane. See: Buchwald, S. L. Chem. Eng. News 1993, 71 (13), 2.
18. Yu, R.; Darmon, J. M.; Hoyt, J. M.; Margulieux, G.; Turner, Z. R.; Chirik, P. J. ACS Catal. 2012, 2, 1760.