Organic solvent-free catalytic hydrogenation of diene-based polymer nanoparticles in latex form. Part II. Kinetic analysis and mechanistic study

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 50, Issue 22, 2012, Pages 4612-4627

  Wang, Hui ^a   Yang, Lijuan ^a   Scott, Stephen ^a   Pan, Qinmin ^a,b   Rempel, Garry L ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

^b SOOCHOW UNIVERSITY   (China)

Author keywords

catalysis; diffusion; latex hydrogenation; mechanism; nanoparticles; reaction kinetics

Indexed keywords

APPARENT ACTIVATION ENERGY; CATALYST CONCENTRATION; CATALYST LOADINGS; CATALYTIC HYDROGENATION; CATALYTICALLY ACTIVE SPECIES; COMPREHENSIVE STUDIES; FIRST-ORDER KINETIC MODELS; HIGH CONVERSIONS; HYDROGEN UPTAKE; HYDROGENATION ACTIVITY; HYDROGENATION PROCESS; HYDROGENATION RATE; HYDROGENATION REACTIONS; KINETIC ANALYSIS; KINETIC STUDY; LARGE-SCALE PRODUCTION; LOW LEVEL; MECHANISTIC STUDIES; OLEFINIC SUBSTRATES; POLYMER LATICES; POLYMER NANOPARTICLES; POLYMER SUBSTRATE; RATE DETERMINING STEP; SOLVENT FREE;

CATALYSIS; CATALYSTS; CHLORINE; COORDINATION REACTIONS; CROSSLINKING; DIFFUSION; HYDROGEN; KINETIC THEORY; KINETICS; LATEXES; MASS TRANSFER; MECHANISMS; NANOPARTICLES; OLEFINS; ORGANIC SOLVENTS; POLYMERS; REACTION KINETICS; SUBSTRATES; SYNTHESIS (CHEMICAL);

HYDROGENATION;

EID: 84867492408     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.26276     Document Type: Article

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