Catalytic conversions in aqueous media: A novel and efficient hydrogenation of polybutadiene-1,4-block-poly(ethylene oxide) catalyzed by Rh/TPPTS complexes in mixed micellar nanoreactors

Journal of Molecular Catalysis A: Chemical

Volumn 231, Issue 1-2, 2005, Pages 93-101

  Kotzabasakis, Vasilis ^a   Georgopoulou, Eleni ^a   Pitsikalis, Marinos ^a   Hadjichristidis, Nikos ^a   Papadogianakis, Georgios ^a  

^a UNIVERSITY OF ATHENS   (Greece)

Author keywords

Aqueous media; Hydrogenation; Mixed micelles; Rhodium; TPPTS

Indexed keywords

CONCENTRATION (PROCESS); HYDROGENATION; LIGHT SCATTERING; MICELLES; POLYBUTADIENES; POLYETHYLENE OXIDES; RHODIUM; SOLUBILITY; TRANSITION METALS;

CATALYTIC HYDROGENATION; MICELLAR NANOREACTORS; NANOMICELLES; UNSATURATED POLYMER;

CATALYSIS;

AMMONIUM CHLORIDE; DODECYLTRIMETHYLAMMONIUM CHLORIDE; ETHYLENE OXIDE DERIVATIVE; HEXANE; POLYBUTADIENE 1,4 BLOCK POLY(ETHYLENE OXIDE); POLYMER; RHODIUM; TRANSITION ELEMENT; UNCLASSIFIED DRUG; WATER;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CONCENTRATION (PARAMETERS); DYNAMICS; EXPERIMENT; HYDRODYNAMICS; HYDROGENATION; LIGHT SCATTERING; MICELLE; REACTION ANALYSIS; REACTOR; SOLUBILITY;

EID: 14844316672     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2005.01.002     Document Type: Article

References (45)

1. G. Papadogianakis, and R.A. Sheldon New J. Chem. 20 1996 175
2. G. Papadogianakis, and R.A. Sheldon Catalysis 13 1997 114
3. G. Papadogianakis B. Cornils W.A. Herrmann Aqueous-Phase Organometallic Catalysis: Concepts and Applications 2nd ed. 2004 Wiley-VCH Weinheim
4. P.T. Anastas, and M.M. Kirchhoff Acc. Chem. Res. 35 2002 686
5. Organization for Economic Co-operation and Development (OECD): Promoting the Design, Manufacture, and Use of Environmentally Benign Chemicals Through Sustainable Chemistry (or "Green Chemistry"). http://www.oecd.org/ document/6/0,2340,en_2649_201185_1909638_1_1_1_1,00.html.
6. N.K. Singha, S. Bhattacharjee, and S. Sivaram Rubber Chem. Technol. 70 1997 309
7. N.T. McManus, and G.L. Rempel J. M. S. - Rev. Macromol. Chem. Phys. C 35 2 1995 239
8. N.K. Singha, P.P. De, and S. Sivaram J. Appl. Polym. Sci. 66 1997 1647
9. V.A.E. Barrios, R.H. Najera, A. Petit, and F. Pla Eur. Polym. J. 36 2000 1817
10. P.V.C. Rao, V.K. Upadhyay, and S.M. Pillai Eur. Polym. J. 37 2001 1159
11. M.D. Gehlsen, and F.S. Bates Macromolecules 26 1993 4122
12. A. Tullo Chem. Eng. News 77 51 1999 14
13. D.A. Hucul, and S.F. Hahn Adv. Mater. 12 2000 1855
14. J.A. Widegren, and R.G. Finke J. Mol. Catal. A: Chem. 191 2003 187
15. L. Wei, J. Jang, Y. Wang, and Z. Jin J. Mol. Catal. A: Chem. 221 2004 47
16. S. MacLeod, and R.J. Rosso Adv. Synth. Catal. 345 2003 568
17. N.K. Singha, S. Sivaram, and S.S. Talwar Rubber Chem. Technol. 68 1995 281
18. G. Mudalige, and G.L. Rempel J. Mol. Catal. A: Chem. 116 1997 309
19. G. Mudalige, and G.L. Rempel J. Mol. Catal. A: Chem. 123 1997 15
20. R. Gärtner, B. Cornils, H. Springer, P. Lappe, DE 3235030 (1982) to Ruhrchemie AG.
21. R. Gärtner, B. Cornils, H. Springer, and P. Lappe Chem. Abstr. 101 1984 55331t
22. N. Hadjichristidis, H. Iatrou, S. Pispas, and M. Pitsikalis J. Polym. Sci. Part A: Polym. Chem. 38 2000 3211
23. B. Esswein, and M. Moller Angew. Chem., Int. Ed. Engl. 35 1996 623
24. S. Forster, and E. Kramer Macromolecules 32 1999 2783
25. J.H. Fendler, and E.J. Fendler Catalysis in Micellar and Macromolecular Systems 1975 Academic Press New York
26. B. Gates Catalytic Chemistry 1992 Wiley New York p. 129
27. Y. Moroi Micelles: Theoretical and Applied Aspects 1992 Plenum New York p. 44
28. I. Grassert, V. Vill, and G. Oehme J. Mol. Catal. A: Chem. 116 1997 231
29. T.N. Parac-Vogt, K. Kimpe, S. Laurent, C. Pierart, L. Vander Elst, R.N. Muller, and K. Binnemans Eur. J. Inorg. Chem. 2004 3538
30. A. Riisager, and B.E. Hanson J. Mol. Catal. A: Chem. 189 2002 195
31. H. Chen, Y. Li, J. Chen, P. Cheng, Y. He, and X. Li J. Mol. Catal. A: Chem. 149 1999 1
32. L. Wang, H. Chen, Y. He, Y. Li, M. Li, and X. Li Appl. Catal. A: Gen. 242 2003 85
33. M. Li, Y. Li, H. Chen, Y. He, and X. Li J. Mol. Catal. A: Chem. 194 2003 13
34. K. Drexler, R. Meisel, I. Grassert, E. Paetzold, H. Fuhrmann, and G. Oehme Macromol. Chem. Phys. 201 2000 1436
35. B. Fell, Ch. Schobben, and G. Papadogianakis J. Mol. Catal. A: Chem. 101 1995 179
36. A. Halperin Macromolecules 20 1987 2943
37. J. Nooland, and M.H. Hong Macromolecules 16 1983 1443
38. L. Leibler, H. Orland, and J.C. Wheeler J. Chem. Phys. 79 1983 3550
39. R. Nagarajan, and K. Granesh J. Chem. Phys. 90 1989 5843
40. M.R. Munch, and A.P. Grast Macromolecules 21 1988 1360
41. J. Schulz, A. Roucoux, and H. Patin Chem. Commun. 1999 535
42. A. Roucoux, J. Schulz, and H. Patin Adv. Synth. Catal. 345 2003 222
43. J. Schulz, S. Levigne, A. Roucoux, and H. Patin Adv. Synth. Catal. 344 2002 266
44. C. Larpent, R. Dabard, and H. Patin Inorg. Chem. 26 1987 2922
45. A.W. Heinen, G. Papadogianakis, R.A. Sheldon, J.A. Peters, and H. Van Bekkum J. Mol. Catal. A: Chem. 142 1999 17