Investigation of the electronic origin of asymmetric induction in palladium-catalyzed allylic substitutions with phosphinooxazoline (PHOX) ligands by Hammett and Swain-Lupton analysis of the 13C NMR chemical shifts of the (π-allyl)palladium intermediates

Organometallics

Volumn 31, Issue 19, 2012, Pages 6933-6946

  Armstrong, Paul B ^a   Dembicer, Elizabeth A ^a   Desbois, Andrew J ^a   Fitzgerald, Jay T ^a   Gehrmann, Janet K ^a   Nelson, Nathaniel C ^a   Noble, Amelia L ^a   Bunt, Richard C ^a  

^a MIDDLEBURY COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC SUBSTITUTION; ASYMMETRIC INDUCTION; CHIRAL LIGAND; DIASTEREOMERS; ELECTRONIC CONTROLS; ELECTRONIC IMPACT; ELECTRONIC ORIGIN; ELECTRONIC TUNING; ENANTIOSELECTION; ENANTIOSELECTIVE; FIELD EFFECTS; HAMMETT ANALYSIS; LIGAND COMPLEXES; LIGAND PROPERTIES; NMR CHEMICAL SHIFTS; NUCLEOPHILIC ADDITIONS; PALLADIUM INTERMEDIATES; PALLADIUM-CATALYZED; PHOSPHINO-OXAZOLINE; PHOSPHORUS ATOM;

CHEMICAL SHIFT; COMPLEXATION; CONTROL; ENANTIOSELECTIVITY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SUBSTITUTION REACTIONS;

LIGANDS;

EID: 84867367075     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om3007163     Document Type: Article

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