Hydrocarbon Chain Lengthening in Catalytic CO Hydrogenation: Evidence for a CO-Insertion Mechanism

Journal of the American Chemical Society

Volumn 134, Issue 39, 2012, Pages 16135-16138

  Schweicher, Julien ^b   Bundhoo, Adam ^a   Kruse, Norbert ^a  

^a UNIVERSITÉ LIBRE DE BRUXELLES   (Belgium)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBED SPECIES; CHEMICAL TRANSIENT KINETICS; CO HYDROGENATION; GASEOUS REACTANTS; HYDROCARBON CHAINS; INSERTION MECHANISM; MODEL CATALYSTS; STEADY STATE; SURFACE CARBON; TIME RESPONSE; TIME-DEPENDENT RESPONSE;

ADSORPTION; ATMOSPHERIC PRESSURE; CARBON; HYDROCARBONS; HYDROGEN; MONOLAYERS; TRANSIENTS;

HYDROGENATION;

CARBON; CARBON MONOXIDE; COBALT; HYDROCARBON; HYDROGEN; MAGNESIUM OXIDE; OXYGEN;

ADSORPTION; ARTICLE; ATMOSPHERIC PRESSURE; CATALYSIS; CATALYST; CHEMICAL REACTION; GAS FLOW; HYDROGENATION; KINETICS; STEADY STATE;

EID: 84867055677     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3068484     Document Type: Article

References (30)

1. Fischer, F.; Tropsch, H. Brennst. Chem. 1923, 4, 276-285
2. Fischer, F.; Tropsch, H. Brennst. Chem. 1926, 7, 97-104
3. Brady, R. C.; Pettit, R. J. Am. Chem. Soc. 1980, 102, 6181-6182
4. Brady, R. C.; Pettit, R. J. Am. Chem. Soc. 1981, 103, 1287-1289
5. Bell, A. T. Catal. Rev.-Sci. Eng. 1981, 23, 203-232
6. Chuang, S. C.; Tian, Y. H.; Goodwin, J. G.; Wender, I. J. Catal. 1985, 96, 396-407
7. Ciobica, I. M.; Frechard, F.; van Santen, R. A.; Kleyn, A. W.; Hafner, J. Chem. Phys. Lett. 1999, 311, 185-192
8. Ciobica, I. M.; Kramer, G. J.; Ge, Q.; Neurock, M.; van Santen, R. A. J. Catal. 2002, 212, 136-144
9. Liu, Z.-P.; Hu, P. J. Am. Chem. Soc. 2002, 124, 11568-11569
10. Gong, X.-Q.; Raval, R.; Hu, P. J. Chem. Phys. 2005, 122, 024711-6
11. Cheng, J.; Gong, X.-Q.; Hu, P.; Lok, C. M.; Ellis, P.; French, S. J. Catal. 2008, 254, 285-295
12. Cheng, J.; Hu, P.; Ellis, P.; French, S.; Kelly, G.; Lok, C. M. J. Catal. 2008, 257, 221-228
13. Biloen, P.; Sachtler, W. M. H. Adv. Catal. 1981, 30, 165-216
14. Fischer, F. The Conversion of Coal into Oils; Ernest Benn Ltd.: London, 1925.
15. Podgurski, H. H.; Kummer, J. T.; DeWitt, T. W.; Emmett, P. H. J. Am. Chem. Soc. 1950, 72, 5382-5388
16. Storch, H. H.; Golumbic, N.; Anderson, R. B. The Fischer-Tropsch and Related Syntheses; Wiley: New York, 1951.
17. Vannice, M. A. J. Catal. 1975, 37, 462-473
18. Davis, B. H. Catal. Today 2009, 141, 25-33
19. Ojeda, M.; Nabar, R.; Nilekar, A. U.; Ishikawa, A.; Mavrikakis, M.; Iglesia, E. J. Catal. 2010, 272, 287-297
20. Huo, C.-F.; Li, Y.-W.; Wang, J.; Jiao, H. J. Phys. Chem. C 2008, 112, 14108-14116
21. Inderwildi, O. R.; Jenkins, S. J.; King, D. A. J. Phys. Chem. C 2008, 112, 1305-1307
22. Zhuo, M.; Tan, K. F.; Borgna, A.; Saeys, M. J. Phys. Chem. C 2009, 113, 8357-8365
23. Heck, R. F.; Breslow, D. S. J. Am. Chem. Soc. 1961, 83, 4023-4027
24. Pichler, H.; Schulz, H. Chem. Ing. Techn. 1970, 42, 1162-1174
25. Wagner, C.; Hauffe, K. Z. Elektrochem. 1939, 45, 409-425
26. Tamaru, K. Adv. Catal. 1965, 15, 65-90
27. Frennet, A.; Visart de Bocarmé, T.; Bastin, J.-M.; Kruse, N. J. Phys. Chem. B 2005, 109, 2350-2359
28. Bundhoo, A.; Schweicher, J.; Frennet, A.; Kruse, N. J. Phys. Chem. C 2009, 113, 10731-10739
29. Anderson, R. B.; Friedel, R. A.; Storch, H. H. J. Chem. Phys. 1951, 19, 313-319
30. Schweicher, J.; Bundhoo, A.; Frennet, A.; Kruse, N.; Daly, H.; Meunier, F. C. J. Phys. Chem. C 2010, 114, 2248-2255