Cation clock permits distinction between the mechanisms of α- And β-O- and β-C-glycosylation in the mannopyranose series: Evidence for the existence of a mannopyranosyl oxocarbenium ion

Journal of the American Chemical Society

Volumn 134, Issue 36, 2012, Pages 14746-14749

  Huang, Min ^a   Retailleau, Pascal ^a   Bohé, Luis ^a   Crich, David ^a,b  

^a CNRS   (France)

^b WAYNE STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOAT CONFORMATIONS; COMPETITION REACTIONS; CYCLIZATION REACTIONS; GLYCOSYL; ISO-PROPANOLS; MANNOPYRANOSE; OXOCARBENIUM; RELATIVE RATE CONSTANTS; TRIMETHYL;

CYCLIZATION; ESTERIFICATION; GLYCOSYLATION; RATE CONSTANTS;

REACTION INTERMEDIATES;

2 PROPANOL; ALLYLTRIMETHYLSILANE; BENZYLIDENE DERIVATIVE; CARBENE; MANNOSE; PYRANOSIDE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATION; CYCLIZATION; DISSOCIATION; GLYCOSYLATION; REACTION ANALYSIS;

CARBOHYDRATE CONFORMATION; CATIONS; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; GLYCOSYLATION; IONS; MANNOSE; MODELS, MOLECULAR;

EID: 84866403852     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja307266n     Document Type: Article

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