Micromechanisms of solid electrolyte interphase formation on electrochemically cycled graphite electrodes in lithium-ion cells

Carbon

Volumn 50, Issue 15, 2012, Pages 5359-5371

  Bhattacharya, Sandeep ^a   Alpas, Ahmet T ^a  

^a UNIVERSITY OF WINDSOR   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AMORPHOUS STRUCTURES; APPLIED VOLTAGES; COLUMNAR MORPHOLOGY; COMPOSITIONAL CHANGES; CRYSTALLINE DOMAINS; ELECTRODE/ELECTROLYTE INTERFACES; FORMATION PROCESS; LITHIUM-ION CELLS; MICRO-STRUCTURAL; MICROMECHANISMS; NANO-SIZED; SCAN RATES; SOLID ELECTROLYTE INTERPHASE; TUBULAR MORPHOLOGY; TWO-REGIME; UNIFORM COVERAGE;

CRYSTALLINE MATERIALS; DIFFUSION; GRAPHITE ELECTRODES; LITHIUM COMPOUNDS; MORPHOLOGY; SOLID ELECTROLYTES; TRANSMISSION ELECTRON MICROSCOPY;

SEEBECK EFFECT;

EID: 84866389530     PISSN: 00086223     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbon.2012.07.009     Document Type: Article

References (44)

1. E. Peled The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems - the solid electrolyte interphase model J Electrochem Soc 126 1979 2047 2051
2. E. Peled, and D. Golodnitsky P.B. Balbuena, Y. Wang, Lithium-ion batteries: solid electrolyte interphase 2004 Imperial College Press 2
3. E. Peled J.P. Gabano, Lithium batteries 1983 Academic 43
4. E. Peled, D. Golodnitsky, G. Ardel, and V. Eshkenazy The SEI Model - application to Li/PE batteries Electrochim Acta 40 1995 2197 2204
5. R. Imhof, and P. Novák In situ investigation of the electrochemical reduction of carbonate electrolyte solutions at graphite electrodes J Electrochem Soc 145 1998 1081 1087
6. D. Aurbach, B. Markovsky, I. Weissman, E. Levi, and Y. Ein-Eli On the correlation between surface chemistry and performance of graphite anodes for Li ion batteries Electrochim Acta 45 1999 67 86
7. R. Kostecki, and F. McLarnon Microprobe study of the effect of Li intercalation on the structure of graphite J Power Sources 119-121 2003 550 554
8. P. Verma, P. Maire, and P. Novák A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Electrochim Acta 55 2010 6332 6341
9. S.H. Kang, D.P. Abraham, A. Xiao, and B.L. Lucht Investigating the solid electrolyte interphase using binder-free graphite electrodes J Power Sources 175 2008 526 532
10. Peled E, Bar Tow D, Merson A, Gladkich A, Burstein L. Composition, Depth profiles and lateral distribution of materials in the SEI built on HOPG-TOF SIMS and XPS studies. J Power Sources 2001; 97-98:52-7.
11. S.H. Ng, C. Vix-Guterl, Ph. Bernardo, N. Tran, J. Ufheil, and H. Buqa Correlations between surface properties of graphite and the first cycle specific charge loss in lithium-ion batteries Carbon 47 2009 705 712
12. E. Markervich, G. Salitra, M.D. Levi, and D. Aurbach Capacity fading of lithiated graphite electrodes studied by a combination of electroanalytical methods, Raman spectroscopy and SEM J Power Sources 146 2005 146 150
13. S. Bhattacharya, A.R. Riahi, and A.T. Alpas A transmission electron microscope study of crack formation and propagation in electrochemically cycled graphite electrode in lithium-ion cells J Power Sources 196 2011 8719 8727
14. S. Bhattacharya, A.R. Riahi, and A.T. Alpas In-situ observations of lithiation/de-lithiation induced graphite damage during electrochemical cycling Scripta Mater 64 2011 165 168
15. Bhattacharya S, Riahi AR, Alpas AT. 2012. Role of voltage scan rate on degradation of graphite electrodes electrochemically cycled vs. Li/Li+. MRS Proceedings, 1388, mrsf11-1388-f12-11; doi:10.1557/opl.2012.8.
16. C.G. Granqvist Handbook of inorganic electrochromic materials 1995 Elsevier Science Amsterdam
17. N. Takami, A. Satoh, M. Hara, and T. Ohsaki Structural and kinetic characterization of lithium intercalation into carbon anodes for secondary lithium batteries J Electrochem Soc 142 1995 371 379
18. T. Uchida, Y. Morikawa, H. Ikuta, and M. Wakihara Chemical diffusion coefficient of lithium in carbon fiber J Electrochem Soc 143 1996 2606 2610
19. M.W. Verbrugge, and B.J. Koch Modeling lithium intercalation of single-fiber carbon microelectrodes J Electrochem Soc 143 1996 600 608
20. Doi T, Miyatake K, Iriyama Y, Takeshi Abe, Ogumi Z, Nishizawa T. Lithium-ion transfer at an electrolyte/non-graphitizable carbon electrode interface. Carbon 2004; 42:318-7.
21. N. Iwashita, C.R. Park, H. Fujimoto, M. Shiraishi, and M. Inagaki Specification for a standard procedure of X-ray diffraction measurements on carbon materials Carbon 42 2004 701 714
22. N. Iwashita, and M. Inagaki Relations between structural parameters obtained by X-ray powder diffraction of various carbon materials Carbon 31 2004 1107 1113
23. ASTM C373-88 (Reapproved 2006), Standard Test Method for Water Absorption, Bulk Density, Apparent Porosity, and Apparent Specific Gravity of Fired Whiteware Products, ASTM International, West Conshohocken, PA 19428-2959, US.
24. P. Novák, F. Joho, M. Lanz, B. Rykart, J.C. Panitz, and D. Alliata The complex electrochemistry of graphite electrodes in lithium-ion batteries J Power Sources 97-98 2001 39 46
25. F. Wu, L. Wang, C. Wu, and Y. Bai Structural characterization and electrochemical performance of lithium trivanadate synthesized by microwave sol-gel method Electrochim Acta 54 2009 4613 4619
26. C.C. Hsueh, R. Bravo, A.J. Jaramillo, and A. Brajter-Toth Surface and kinetic enhancement of selectivity and sensitivity in analysis with fast scan voltammetry at scan rates above 1000 V/s Anal Chim Acta 349 1997 67 76
27. Zhang H-Li, Zhang Y, Zhang X-G, Li F, Liu C, Tan J, et al. Urchin-like nano/micro hybrid anode materials for lithium ion battery. Carbon 2006; 44:2778-84.
28. Joint Committee on Powder Diffraction Standards (JCPDS) Card No. 75-1621.
29. A.H. Whitehead, K. Edström, N. Rao, and J.R. Owen In situ X-ray diffraction studies of a graphite-based Li-ion battery negative electrode J Power Sources 63 1996 41 45
30. Joint Committee on Powder Diffraction Standards (JCPDS) Card No. 9-359.
31. Joint Committee on Powder Diffraction Standards (JCPDS) Card No. 9-355.
32. M.A. O'Keefe, P.R. Buseck, and S. Iijima Computed crystal structure images for high resolution electron microscopy Nature 274 1978 322 324
33. J.C.H. Spence In experimental high-resolution electron microscopy 1988 Oxford University Press New York
34. T.L. Kulova, and A.M. Skundin Balance between reversible and irreversible processes during lithium intercalation in graphite Russ J Electrochem 42 2006 251 258
35. D. Aurbach, B. Markovsky, A. Shechter, Y. Ein-Eli, and H. Cohen A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on ethylene carbonate-dimethyl carbonate mixtures J Electrochem Soc 143 1996 3809 3820
36. D. Aurbach, J.S. Gnanaraj, M.D. Levi, E.A. Levi, J.E. Fischer, and A. Claye On the correlation among surface chemistry, 3D structure, morphology, electrochemical and impedance behavior of various lithiated carbon electrodes J Power Sources 97-98 2001 92 96
37. M.D. Levi, E.A. Levi, and D. Aurbach The mechanism of lithium intercalation in graphite film electrodes in aprotic media. Part 2. Potentiostatic intermittent titration and in situ XRD studies of the solid-state ionic diffusion J Electroanal Chem 421 1997 89 97
38. M. Nishizawa, R. Hashitani, T. Itoh, T. Matsue, and I. Uchida Measurements of chemical diffusion coefficient of lithium ion in graphitized mesocarbon microbeads using a microelectrode Electrochem Solid-State Lett 1 1998 10 12
39. E. Barsoukov, J.H. Kim, J.H. Kim, C.O. Yoon, and H. Lee Kinetics of lithium intercalation into carbon anodes: in situ impedance investigation of thickness and potential dependence Solid State Ionics 116 1999 249 261
40. 4 films and solar cells Sol Energy Mater Sol Cells 98 2012 110 117
41. Ph. Bernardo, J. Dentzer, R. Gadiou, W. Märkle, D. Goers, and P. Novák Influence of graphite surface properties on the first electrochemical lithium intercalation Carbon 49 2011 4867 4876
42. Y. Gogotsi, J.A. Libera, N. Kalashnikov, and M. Yoshimura Graphite polyhedral crystals Science 290 2000 317 320
43. P.J.F. Harris Structural transformation of graphite by arc-discharge Phil Mag 91 2011 2355 2363
44. S. Bhattacharya, A.R. Riahi, and A.T. Alpas Characterization of electrochemical cycling - induced damage of graphite working electrodes in lithium-ion cells Cer Trans 227 2011 17 26