The physicochemical properties of some imidazolium-based ionic liquids and their binary mixtures

Science China Chemistry

Volumn 55, Issue 8, 2012, Pages 1509-1518

  Ning, Hui ^a   Hou, Min Qiang ^a   Mei, Qing Qing ^a   Liu, Yuan Hui ^a   Yang, De Zhong ^a   Han, Bu Xing ^a  

^a INSTITUTE OF CHEMISTRY   (China)

Author keywords

Conductivity; Density; Ionic liquids; Viscosity; Walden rule

Indexed keywords

1-HEXYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE; COMPOSITION RANGES; EXCESS MOLAR VOLUMES; IMIDAZOLIUM-BASED IONIC LIQUID; ION ASSOCIATION; PHYSICOCHEMICAL PROPERTY; TETRAFLUOROBORATES; TWO-COMPONENT; WALDEN RULE;

CHLORINE COMPOUNDS; DENSITY (SPECIFIC GRAVITY); ELECTRIC CONDUCTIVITY; IONIC LIQUIDS; VISCOSITY;

BINARY MIXTURES;

EID: 84866144826     PISSN: 16747291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-012-4655-1     Document Type: Article

References (38)

1. Rogers RD, Seddon KR. Ionic liquids-solvents of the future? Science, 2003, 302: 792-793
2. Martins MAP, Frizzo CP, Moreira DN, Zanatta N, Bonacorso HG. Ionic liquids in heterocyclic synthesis. Chem Rev, 2008, 108(6): 2015-2050
3. Liu QS, Yang M, Tan ZC, Urs WB. Estimation and prediction of the physicochemical properties of imidazolium-based ionic liquids. Acta Phys Chim Sin, 2010, 26(6): 1463-1467
4. Pârvulescu VI, Hardacre C. Catalysis in ionic liquids. Chem Rev, 2007, 107: 2615-2665 (Pubitemid 47029102)
5. 2 capture. Acc Chem Res, 2009, 43(1): 152-159
6. Wang HY, Wang JJ, Fan MH. Extraction of ionic liquids from aqueous solutions by humic acid: An environmentally benign, inexpensive and simple procedure. Chem Commun, 2012, 48(3): 392-394
7. Wang TF, Peng CJ, Liu HL, Hu Y. Description of the pVT behavior of ionic liquids and the solubility of gases in ionic liquids using an equation of state. Fluid Phase Equilib, 2006, 250(1-2): 150-157 (Pubitemid 44827551)
8. Hoang PH, Park H, Kim DP. Ultrafast and continuous synthesis of unaccommodating inorganic nanomaterials in droplet and ionic liquid-assisted microfluidic system. J Am Chem Soc, 2011, 133(37): 14765-14770
9. Morris RE. Ionic liquids and microwaves-making zeolites for emerging applications. Angew Chem Int Ed, 2008, 47(3): 442-444 (Pubitemid 351412321)
10. 2 nanocrystals in ionic liquid via a microwave-assisted process. J Am Chem Soc, 2007, 129(20): 6362-6363 (Pubitemid 46799319)
11. Bayley PM, Best AS, MacFarlane DR, Forsyth M. Transport properties and phase behaviour in binary and ternary ionic liquid electrolyte systems of interest in lithium batteries. ChemPhysChem, 2011, 12(4): 823-827
12. Nakagawa H, Izuchi S, Kuwana K, Nukuda T, Aihara Y. Liquid and polymer gel electrolytes for lithium batteries composed of room-temperature molten salt doped by lithium salt. J Electrochem Soc, 2003, 150(6): A695-A700
13. Gao Y, Zhang LQ, Wang Y, Li HR. Probing electron density of H-bonding between cation-anion of imidazolium-based ionic liquids with different anions by vibrational spectroscopy. J Phys Chem B, 2010, 114(8): 2828-2833
14. Zhao ZF, Ueno K, Angell CA. High conductivity, and "dry" proton motion, in guanidinium salt melts and binary solutions. J Phys Chem B, 2011, 115(46): 13467-13472
15. 4 and EMIC. Fluid Phase Equilib, 2005, 227(1): 41-46 (Pubitemid 40094700)
16. Zhang SJ, Li X, Chen HP, Wang JF, Zhang JM, Zhang ML. Determination of physical properties for the binary system of 1-ethyl-3-methylimidazolium tetrafluoroborate + H2O. J Chem Eng Data, 2004, 49(4): 760-764
17. Zhang QG, Wang NN, Wang SL, Yu ZW. Hydrogen bonding behaviors of binary systems containing the ionic liquid 1-butyl-3-methylimidazolium trifluoroacetate and water/methanol. J Phys Chem B, 2011, 115(38): 11127-11136
18. Wang JJ, Tian Y, Zhao Y, Zhuo KL. A volumetric and viscosity study for the mixtures of 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid with acetonitrile, dichloromethane, 2-butanone and N,N-dimethylformamide. Green Chem, 2003, 5(5): 618-622 (Pubitemid 37448545)
19. Wang JJ, Zhu AL, Zhao Y, Zhuo KL. Excess molar volumes and excess logarithm viscosities for binary mixtures of the ionic liquid 1-butyl-3-methylimidazolium hexaflurophosphate with some organic compounds. J Solut Chem, 2005, 34(5): 585-596 (Pubitemid 41095385)
20. Fan W, Zhou Q, Sun J, Zhang SJ. Density, excess molar volume, and viscosity for the methyl methacrylate + 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid binary system at atmospheric pressure. J Chem Eng Data, 2009, 54(8): 2307-2311
21. Muldoon MJ, Aki S, Anderson JL, Dixon JK, Brennecke JF. Improving carbon dioxide solubility in ionic liquids. J Phys Chem B, 2007, 111(30): 9001-9009 (Pubitemid 47317479)
22. 2N]. J Chem Eng Data, 2009, 55(1): 165-172
23. 2 in imidazolium-based ionic liquids using NPT Monte Carlo simulation. J Phys Chem B, 2011, 115(46): 13599-13607
24. Every H, Bishop AG, Forsyth M, MacFarlane DR. Ion diffusion in molten salt mixtures. Electrochim Acta, 2000, 45(8-9): 1279-1284 (Pubitemid 30526850)
25. Lopes JNC, Cordeiro TC, Esperanca J, Guedes HJR, Huq S, Rebelo LPN, Seddon KR. Deviations from ideality in mixtures of two ionic liquids containing a common ion. J Phys Chem B, 2005, 109(8): 3519-3525 (Pubitemid 40352321)
26. Kunze M, Jeong S, Paillard E, Winter M, Passerini S. Melting behavior of pyrrolidinium-based ionic liquids and their binary mixtures. J Phys Chem C, 2010, 114(28): 12364-12369
27. Navia P, Troncoso J, Romani L. Excess magnitudes for ionic liquid binary mixtures with a common ion. J Chem Eng Data, 2007, 52(4): 1369-1374 (Pubitemid 47218453)
28. Castiglione F, Raos G, Appetecchi GB, Montanino M, Passerini S, Moreno M, Famulari A, Mele A. Blending ionic liquids: How physico-chemical properties change. Phys Chem Chem Phys, 2010, 12(8): 1784-1792
29. Castiglione F, Moreno M, Raos G, Famulari A, Mele A, Appetecchi GB, Passerini S. Structural organization and transport properties of novel pyrrolidinium-Based ionic liquids with perfluoroalkyl sulfonylimide anions. J Phys Chem B, 2009, 113(31): 10750-10759
30. Stoppa A, Buchner R, Hefter G. How ideal are binary mixtures of room-temperature ionic liquids? J Mol Liq, 2010: 46-51
31. Dzyuba SV, Bartsch RA. Influence of structural variations in 1-alkyl(aralkyl)-3-methylimidazolium hexafluorophosphates and bis(trifluoromethylsulfonyl)imides on physical properties of the ionic liquids. ChemPhysChem, 2002, 3(2): 161-166
32. Bonhôte P, Dias AP, Papageorgiou N, Kalyanasundaram K, Grätzel M. Hydrophobic, highly conductive ambient-temperature molten salts. Inorg Chem, 1996, 35: 1168-1178
33. Weingärtner H. Understanding ionic liquids at the molecular level: facts, problems, and controversies. Angew Chem Int Ed, 2008, 47(4): 654-670
34. Stoppa A, Zech O, Kunz W, Buchner R. The conductivity of imidazolium-based ionic liquids from (-35 to 195) degrees C. A. variation of cation's alkyl chain. J Chem Eng Data, 2010, 55(5): 1768-1773
35. Andriyko YO, Reischl W, Nauer GE. Trialkyl-substituted imidazolium-based ionic liquids for electrochemical applications: basic physicochemical properties. J Chem Eng Data, 2009, 54(3): 855-860
36. Schreiner C, Zugmann S, Hartl R, Gores HJ. Fractional Walden rule for ionic liquids: Examples from recent measurements and a critique of the so-called ideal KCl line for the Walden plot. J Chem Eng Data, 2010, 55(5): 1784-1788
37. Zech O, Stoppa A, Buchner R, Kunz W. The conductivity of imidazolium-based ionic liquids from (248 to 468) K. B. variation of the anion. J Chem Eng Data, 2010, 55(5): 1774-1778
38. Izgorodina EI, Maganti R, Armel V, Dean PM, Pringle JM, Seddon KR, MacFarlane DR. Understanding the effect of the C2 proton in promoting low viscosities and high conductivities in imidazolium-based ionic liquids: part I. weakly coordinating anions. J Phys. Chem B, 2011, 115(49): 14688-14697