Electrochemical reduction of hydrogen peroxide on SIMFUEL (UO 2) in acidic pH conditions

Electrochimica Acta

Volumn 83, Issue , 2012, Pages 410-419

  Razdan, Mayuri ^a   Hall, David S ^a,b   Keech, Peter G ^a,c   Shoesmith, David W ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

^b UNIVERSITY OF OTTAWA   (Canada)

^c Nuclear Waste Management Organization   (Canada)

Author keywords

Acidic pH; Corrosion; Hydrogen peroxide; Uranium dioxide; X ray photoelectron spectroscopy (XPS)

Indexed keywords

ACIDIC PH; CATALYTIC SURFACES; CHEMICAL OXIDATION; ELECTROCHEMICAL REDUCTIONS; OVER POTENTIAL; PEROXIDE REDUCTION; PH RANGE; REDUCTION MECHANISMS; ROTATING DISK ELECTRODES; SIMFUEL; SOLUTION PH; SURFACE INTERMEDIATES; SURFACE LAYERS;

CORROSION; HYDROGEN PEROXIDE; PH; PHOTOELECTRONS; REACTION INTERMEDIATES; ROTATING DISKS; SURFACE STRUCTURE; URANIUM DIOXIDE; X RAY PHOTOELECTRON SPECTROSCOPY;

ELECTROLYTIC REDUCTION;

EID: 84865846315     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2012.05.163     Document Type: Article

References (51)

1. J. McMurry, D.A. Dixon, J.D. Garroni, B.M. Ikeda, S. Stroes-Gascoyne, P. Baumgartner, T.W. Melnyk, Ontario Power Generation Report: 06819-REP-01200- 10092-R00, 2003.
2. Nuclear Waste Management Organization (NWMO), Choosing a way forward: the future management of Canada's used nuclear fuel. November 2005, http://www.nwmo.ca.
3. D.W. Shoesmith NWMO TR-2007-03 2007 Nuclear Waste Management Organization Toronto, Canada
4. S. Sunder, N.H. Miller, and D.W. Shoesmith Corrosion Science 46 2004 1095
5. D.W. Shoesmith Journal of Nuclear Science and Technology 282 2000 1
6. J.S. Goldik, H.W. Nesbitt, J.J. Noël, and D.W. Shoesmith Electrochimica Acta 49 2004 1699
7. J.S. Goldik, J.J. Noël, and D.W. Shoesmith Journal of the Electrochemical Society 153 2006 E151
8. J.S. Goldik, J.J. Noël, and D.W. Shoesmith Electrochimica Acta 51 2006 3278
9. J.S. Goldik, J.J. Noël, and D.W. Shoesmith Journal of Electroanalytical Chemistry 582 2005 241
10. B.G. Santos, J.J. Noël, and D.W. Shoesmith Journal of Electroanalytical Chemistry 586 2006 1
11. B.G. Santos, J.J. Noël, and D.W. Shoesmith Electrochimica Acta 51 2006 4157
12. P.G. Keech, J.J. Noël, and D.W. Shoesmith Electrochimica Acta 53 2008 5675
13. J.C. Wren, D.W. Shoesmith, and S. Sunder Journal of the Electrochemical Society 152 2005 B470
14. D.W. Shoesmith, J.J. Noël, and F. Garisto Materials Research Society Symposium Proceedings 824 2004 81
15. W.J. Cheong, P.G. Keech, J.C. Wren, D.W. Shoesmith, and Z. Qin Materials Research Society Symposium Proceedings 985 2007 27
16. 2 Studsvik Report NS-90185, Studsvik Energiteknik AB, Nykoping, Sweden, 1990.
17. M.E. Broczkowski, P.G. Keech, J.J. Noël, and D.W. Shoesmith Journal of the Electrochemical Society 157 2010 C275
18. Olivia Roth, and J.A. LaVerne Journal of Physical Chemistry A 115 2011 700
19. J. De Pablo, I. Casasa, J. Gimenez, V. Marti, and M.E. Torrero Journal of Nuclear Materials 232 1996 138
20. C. Corbel, G. Sattonnay, S. Guilbert, F. Garrido, M.-F. Barthe, and C. Jegou Journal of Nuclear Materials 348 2006 1
21. M.J. Nicol, and C.R.S. Needes Electrochimica Acta 20 1975 585
22. I. Grenthe, J. Fuger, R.J. Konings, R.J. Lemire, A.B. Muller, C. Nguyen-Trung, and H. Wanne Chemical Thermodynamics of Uranium 1992 North Holland Amsterdam
23. M. Amme, B. Renker, B. Schmid, M.P. Feth, H. Bertagnolli, and W. Dobelin Journal of Nuclear Materials 306 2002 202
24. P. Diaz-Arocas, J. Quinones, C. Maffiotte, J. Serrano, J. Garcia, J.R. Almazan, and J. Esteban Materials Research Society Symposium Proceedings 353 1995 641
25. K.A. Kubatko, K.B. Helean, A. Navrotsky, and P.C. Burns Science 302 2003 1191
26. G. Sattonnay, C. Ardois, C. Corbel, J.F. Lucchini, M.F. Barthe, F. Garrido, and D. Gosset Journal of Nuclear Materials 288 2001 11
27. T.Z. Forbes, P. Horan, T. Devine, D. McInnis, and P.C. Burns American Mineralogist 96 2011 202
28. L.E. Eary, and L.M. Cathles Metallurgical Transactions B 14B 1983 325
29. F. Clarens, J. De Pablo, I. Casas, J. Gimenez, M. Rovira, J. Merino, E. Cera, J. Bruno, J. Quinones, and A. Martinez-Esparza Journal of Nuclear Materials 345 2005 225
30. F. Clarens, J. De Pablo, I. Diez-Perez, I. Casas, J. Gimenez, and M. Rovira Environmental Science and Technology 38 2004 6656
31. B. Hanson, B. McNamara, E. Buck, J. Friese, E. Jenson, K. Krupka, and B. Arey Radiochima Acta 93 2005 159
32. A. Rey, S. Utsunomiya, J. Gimenez, I. Casas, J.D. Pablo, and R.C. Ewing American Mineralogist 94 2009 229
33. P.G. Lucuta, R.A. Verrall, H. Matzke, and B.J. Palmer Journal of Nuclear Materials 178 1991 48
34. B.G. Santos, H.W. Nesbitt, J.J. Noël, and D.W. Shoesmith Electrochimica Acta 49 2004 1863
35. C.J. Hochanadel Journal of Physical Chemistry 56 1952 587
36. I. Stefanic, and J.A. LaVerne Journal of Physical Chemistry A 106 2002 447
37. G.C. Allen, and N.R. Holmes Journal of the Chemical Society, Dalton Transactions 12 1987 3009
38. E.S. Ilton, A. Haiduc, C.O. Moses, S.M. Heald, D.C. Eldbert, and D.R. Veblen Geochimica et Cosmochimica Acta 68 2004 2417
39. S. Sunder, G.D. Boyer, and N.H. Miller Journal of Nuclear Materials 175 1990 163
40. M. Schindler, F.C. Hawthorne, M.S. Freund, and P.C. Burns Geochimica et Cosmochimica Acta 73 2009 2488
41. E.S. Ilton, A. Haiduc, C.L. Cahil, and A.R. Felmy Inorganic Chemistry 44 2005 2986
42. E.S. Ilton, J.F. Boily, and P.S. Bagus Surface Science 601 2007 908
43. E.S. Ilton, and P.S. Bagus Surface and Interface Analysis 43 2011 1549
44. M.E. Broczkowski, J.J. Noël, and D.W. Shoesmith Journal of Nuclear Materials 346 2005 16
45. M.E. Broczkowski, R. Zhu, Z. Ding, J.J. Noël, and D.W. Shoesmith Materials Research Society Symposium Proceedings 932 2006 449
46. J. Paquette, and R.J. Lemire Nuclear Science and Engineering 79 1981 26
47. A.J. Bard, and L.R. Faulkner Electrochemical Methods 2nd ed. 2001 Wiley Toronto (Chapter 9)
48. Y.A. Teterin, V.M. Kulakov, A.S. Baev, N.B. Nevzorov, I.V. Melnikov, V.A. Streltsov, L.G. Mashirov, D.N. Suglobov, and A.G. Zelenkov Physics and Chemistry of Minerals 7 1981 151
49. S. Bera, S.K. Sali, S. Sampath, S.V. Narasimhan, and V. Venugopal Journal of Nuclear Materials 255 1998 26
50. S. Van den Berghe, J.-P. Laval, B. Gaudreau, H. Terryn, and M. Verwerft Journal of Nuclear Science and Technology 277 2000 28
51. E.S. Ilton, and P.S. Bagus Physical Review B: Condensed Matter 71 2005 195121