γ-Alumina: The essential and unexpected role of water for the structure, stability, and reactivity of "defect" sites

Journal of the American Chemical Society

Volumn 134, Issue 35, 2012, Pages 14430-14449

  Wischert, Raphael ^a,b,c   Laurent, Pierre ^a   Copéret, Christophe ^a,b   Delbecq, Françoise ^c   Sautet, Philippe ^c  

^a UNIVERSITÉ DE LYON   (France)

^b ETH ZURICH   (Switzerland)

^c UNIVERSITÉ DE LYON   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINA SURFACE; CATALYST PREPARATION; CO MOLECULE; DEHYDROXYLATIONS; DFT CALCULATION; DUAL ROLE; HETEROLYTIC SPLITTING; HIGH REACTIVITY; LEWIS ACID SITE; LEWIS ACID-BASE; LEWIS ACIDITY; LOW TEMPERATURES; METASTABLE SPECIES; PRESENCE OF WATER; PRETREATMENT TEMPERATURE; ROLE OF WATER; SPECTROSCOPIC SIGNATURES; SURFACE SITES;

ACTIVATED ALUMINA; ADSORPTION; DENSITY FUNCTIONAL THEORY; OPTIMIZATION; PROBES;

ALUMINUM;

ALUMINUM; ALUMINUM OXIDE; GAMMA ALUMINA; LEWIS ACID; OXIDE; OXYGEN; UNCLASSIFIED DRUG; WATER;

ACIDITY; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHEMOREACTIVITY; DEHYDROXYLATION; DENSITY FUNCTIONAL THEORY; HYDROXYLATION; MOLECULAR STABILITY; MOUTH TEMPERATURE;

EID: 84865708446     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3042383     Document Type: Article

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