Feasibility for direct rapid energy dispersive X-ray fluorescence (EDXRF) and scattering analysis of complex matrix liquids by partial least squares

Applied Radiation and Isotopes

Volumn 70, Issue 11, 2012, Pages 2596-2601

  Angeyo, K H ^a   Gari, S ^b   Mustapha, A O ^b   Mangala, J M ^a  

^a UNIVERSITY OF NAIROBI   (Kenya)

^b FEDERAL UNIVERSITY OF AGRICULTURE   (Nigeria)

Author keywords

Chemometrics; Modeling; X ray fluorescence scattering complex matrix liquids

Indexed keywords

CHEMOMETRICS; COMPLEX MATRICES; ENERGY DISPERSIVE X-RAY FLUORESCENCE; LIGHT ELEMENTS; MATERIAL CHARACTERIZATIONS; METAL ADDITIVES; PARTIAL LEAST SQUARE (PLS); SCATTERING ANALYSIS;

CHEMICAL ELEMENTS; ENERGY DISPERSIVE SPECTROSCOPY; LIQUIDS; MODELS; QUALITY ASSURANCE; SCATTERING; TRACE ANALYSIS;

X RAYS;

LUBRICATING AGENT;

ARTICLE; ATOMIC ABSORPTION SPECTROMETRY; CALIBRATION; CHEMOMETRIC ANALYSIS; CONTROLLED STUDY; FEASIBILITY STUDY; INFRARED SPECTROSCOPY; MONTE CARLO METHOD; PARTIAL LEAST SQUARES REGRESSION; PRIORITY JOURNAL; QUALITY CONTROL; RAPID ENERGY DISPERSIVE X RAY FLUORESCENCE AND SCATTERING SPECTROMETRY; X RAY FLUORESCENCE;

EID: 84865557346     PISSN: 09698043     EISSN: 18729800     Source Type: Journal    
DOI: 10.1016/j.apradiso.2012.07.019     Document Type: Article

References (20)

1. Alexandre T.L., Bueno M.I.M.S. Classification of some species, genera and families of plants by X-ray spectrometry. X-Ray Spectrom. 2006, 35:257-260.
2. Auce'lio R.Q., Souza R.M., Campos R.C., Miekeley N., Silveira C.L.P. The determination of trace metals in lubricating oils by atomic spectrometry. Spectrochim. Acta B 2007, 62:952-961.
3. Barnasconi G.B. AXIL-QXAS Reference Manual 1996, IAEA, Vienna.
4. Gari, S., 2010. Complex Matrix Analysis via Chemometric-Assisted X-ray Fluorescence and Scattering Applied to Quality Characterization of Polymers and Lubricating Oils. M. Sc. Thesis. University of Nairobi.
5. Gardner R.P., Xu L. Status of the Monte Carlo library least-squares (MCLLS) approach for non-linear radiation analyzer problems. Radiat. Phys. Chem. 2009, 78(10):843-851.
6. He F., Van Espen P. An integrated system for quantitative EDXRF analysis based on fundamental parameters. Nucl. Instrum. Methods Phys. Res. 1990, 299(1-3):580-583.
7. Honkimäki V., Hämäläinen K., Manninen S. Quantitative X-ray fluorescence analysis using fundamental parameters: application to gold jewelry. X-Ray Spectrom. 1996, 25(5):215-220.
8. Kanngießer B. Quantification procedures in micro X-ray fluorescence analysis. Spectrochim. Acta B 2003, 58(4):609-614.
9. Kempenaers, L., 2006. PANanalytical Technical Report.
10. Knoll G.F. Radiation Measurement and Spectroscopy 1988, Wiley, New York. second ed.
11. Kump P. Quantitative analysis of environmental samples by X-ray spectrometry (QAES) instruction manual 1993, Ljubljana, Slovenia.
12. Lekberg P., Van Espen P. Quantitative energy-dispersive X-ray fluorescence analysis of liquids using partial least-squares regression. X-Ray Spectrom. 1999, 28(2):77-85.
13. Li F., Gardner R.P. Implementation of the elemental library stratified sampling technique on the GUI-based Monte Carlo library least squares (MCLLS) approach for EDXRF analysis. Appl. Radiat. Isotopes 2012, 70(7):1243-1249.
14. Massart D.L., Dijkstra A., Kaufman L. Evaluation and Optimization of Laboratory Methods and Analytical Procedures 1978, Elsevier, Amsterdam.
15. Urbanski P., Kowalska E. Application of partial least-squares calibration methods in low-resolution EDXRS. X-Ray Spectrom. 1995, 24(2):70-75.
16. Van Espen P., Nullens H., Adams F. A computer analysis of X-ray fluorescence spectra. Nucl. Instrum. Methods 1977, 142(1-2):243-250.
17. Van Marten G., Dijkstra A. Information theory applied to selection of peaks for retrieval of mass spectra. Anal. Chem. 1976, 48(3):244A-340a.
18. Vekemans B., Janssens K., Vincze L., Adams F., Van Espen P. Analysis of X-ray spectra by iterative least squares (AXIL): new development. X-Ray Spectrom. 1994, 23(6):278-285.
19. Wolska, J., Glose, T., 2003. PANalytical Technical Report.
20. Zieba-Palus J., Kościelniak P. Differentiation of motor oils by infrared spectroscopy and elemental analysis for criminalistic purposes. J. Mol. Struct. 1999, 482-483:533-538.