Reactivity of syringyl and guaiacyl lignin units and delignification kinetics in the kraft pulping of Eucalyptus globulus wood using Py-GC-MS/FID

Bioresource Technology

Volumn 123, Issue , 2012, Pages 296-302

  Lourenço, Ana ^a   Gominho, Jorge ^a   Marques, António Velez ^b   Pereira, Helena ^a  

^a INSTITUTO SUPERIOR DE AGRONOMIA   (Portugal)

^b INSTITUTO SUPERIOR DE ENGENHARIA DE LISBOA   (Portugal)

Author keywords

Delignification; Eucalyptus globulus; Lignin composition; Pyrolysis; S G ratio

Indexed keywords

EUCALYPTUS GLOBULUS; FIRST ORDER REACTIONS; GUAIACYL LIGNIN UNITS; LIGNIN CONTENTS; PULPING STAGES; PY-GC-MS; RESIDUAL LIGNINS; S/G RATIO;

DELIGNIFICATION; KRAFT PULP; PYROLYSIS; WOOD PRODUCTS;

LIGNIN;

GUAIACYL LIGNIN; LIGNIN; SYRINGYL LIGNIN; UNCLASSIFIED DRUG;

DICOTYLEDON; GAS CHROMATOGRAPHY; LIGNIN; MASS SPECTROMETRY; PYROLYSIS; REACTION KINETICS; TEMPERATURE EFFECT;

ARTICLE; DELIGNIFICATION; EUCALYPTUS GLOBULUS; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; NONHUMAN; PRIORITY JOURNAL; PULPING; PYROLYSIS; WOOD;

EUCALYPTUS; FLAME IONIZATION; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; KINETICS; LIGNIN; MODELS, CHEMICAL; PAPER; TEMPERATURE; WOOD;

CHEMICAL COMPOSITION; DELIGNIFICATION; EUCALYPTUS GLOBULUS; KRAFT PULPING; LIGNINS; PYROLYSIS; WOOD PRODUCTS;

EUCALYPTUS GLOBULUS;

EID: 84865550240     PISSN: 09608524     EISSN: 18732976     Source Type: Journal    
DOI: 10.1016/j.biortech.2012.07.092     Document Type: Article

References (34)

1. Bierman C.J. Handbook of pulping and papermaking 1996, Academic Press Limited, London. second ed.
2. Bose K.S., Francis R.C., Govender M., Bush T., Spark A. Lignin content versus syringyl to guaiacyl ratio amongst poplars. Bioresour. Technol. 2009, 100:1628-1633.
3. Boudet A.M., Grima-Pettenati J. Lignin genetic engineering. Mol. Breeding 1996, 2:25-39.
4. Chiang V.L., Funaoka M. The dissolution and condensation reactions of guaiacyl and syringyl units in residual lignin during kraft delignification of sweetgum. Holzforschung 1990, 44:147-155.
5. Chiang V.L., Yu J., Eckert R.C. Isothermal reaction kinetics of kraft delignification of Douglas-Fir. J. Wood Chem. Technol. 1990, 10(3):293-310.
6. del Rio J.C., Gutiérrez A., Romero J., Martínez M.J., Martínez A.T. Identification of residual lignin markers in eucalypt kraft pulps by Py-GC/MS. J. Anal. Appl. Pyrolysis 2001, 58-59:425-439.
7. Faix O., Meier D. Pyrolytic and hydrogenolytic degradation studies on lignocellulosics, pulps and lignins. Holz als Roh-und Werkstoff 1989, 47:67-72.
8. Faix O., Meier D., Fortman I. Thermal degradation products of wood. A collection of electron-impact (EI) mass spectra of monomeric lignin derived products. Holz als Roh-und Werkstoff 1990, 48:351-354.
9. Faix O., Meier D., Fortman I. Thermal degradation products of wood. Gas chromatographic separation and mass spectrometric characterization of monomeric lignin derived products. Holz als Roh-und Werkstoff 1990, 48:281-285.
10. Gellersted G., Lindfors E. Structural changes in lignin during kraft pulping. Holzforschung 1984, 38:151-158.
11. Gellerstedt G., Gustafsson K., Labidi A., Pla F. Alkaline delignification of hardwoods in a flowthrough reactor working at a low residence time. Part IV. Characterization of lignins by oxidative degradation and aminolysis. Holzforschung 1992, 46(3):199-204.
12. Gierer J. Chemical aspects of kraft pulping. J. Wood Sci. Technol. 1980, 14:241-266.
13. Gomide J.L., Colodette J.L., Oliveira R.C., Mudado C. Technological Characterization of the new Generation of Brazilian Eucalyptus Clones for kraft Pulp 2005, Tappi Pulping Conference, Philadelphia, August, 28-31.
14. 13C-NMR spectrometry. J. Anal. Appl. Pyrolysis 1999, 49:295-305.
15. Gutiérrez A., Rodríguez I.M., del Rio J.C. Chemical characterization of lignin fractions in industrial hemp bast fibers used for manufacturing high-quality paper pulps. J. Agric. Food Chem. 2006, 54(6):2138-2144.
16. Ibarra D., Chávez M.I., Rencoret J., del Rio J.C., Gutiérrez A., Romero J., Camarero S., Martínez M.J., Jiménez-Barbero J., Martínez A.T. Lignin modification during Eucalyptus globulus kraft pulping followed by totally chlorine-free bleaching: a two-dimensional nuclear magnetic resonance, fourier transformed infrared, and pyrolysis-gas chromatography/mass spectrometry study. J. Agric. Food Chem. 2007, 55:3477-3490.
17. Kondo R., Sarkanen K.V. Kinetics of lignin and hemicellulose dissolution during the initial stage of alkaline pulping. Holzforschung 1984, 38:31-36.
18. Labidi P.A., Pla F. Délignification en milieu alcalin de bois feullus à l'aide d'un réacteur à lit fixe et à faible temps de passage. Holzforschung 1992, 46:155-161.
19. Lourenço A., Gominho J., Pereira H. Pulping and delignification of sapwood and heartwood from Eucalyptus globulus. J. Pulp Pap. Sci. 2010, 36(3-4):63-69.
20. Lourenço A., Gominho J., Pereira H. Modelling of sapwood and heartwood delignification kinetics of Eucalyptus globulus using consecutive and simultaneous approaches. J. Wood Sci. 2011, 57:20-26.
21. Lourenço, A., Gominho, J., Marques, A.V., Pereira, H., in press. Variation of lignin monomeric composition during kraft pulping of Eucalyptus globulus heartwood and sapwood, J. Wood Chem. Technol.
22. Meier D., Faix O. Pyrolysis-gas chromatography-mass spectrometry. Methods in lignin chemistry 1992, 177-196. Springer-Verlag, Berlin. S.Y. Lin, C.W. Dence (Eds.).
23. Meier D., Faix O. State of the art of applied fast pyrolysis of lignocellulosic materials - a review. Bioresour. Technol. 1999, 68:71-77.
24. Miranda I., Pereira H. Kinetics of ASAM and Kraft pulping of Eucalyptus wood (Eucalyptus globulus). Holzforschung 2002, 56:85-90.
25. Nelson P.J., Gniel G.M. Delignification of Eucalyptus regnans wood during soda pulping. Appita J. 1986, 39:110-114.
26. Obst J.R. Kinetics of kraft pulping of a middle-lamella-enriched fraction of loblolly pine. Tappi J. 1985, 68(2):100-104.
27. Oliet M., Rodríguez F., Santos A., Gilarranz M.A., Garcia-Ochoa F., Tijero J. Organosolv delignification of Eucalyptus globulus: kinetic study of autocatalyzed ethanol pulping. Ind. Eng. Chem. Res. 2000, 39:34-39.
28. Oudia A., Mészaros E., Jakab E., Simões R., Queiroz J., Ragauskas A., Novák L. Analytical pyrolysis study of biodelignification of cloned Eucalyptus globulus (EG) clone and Pinus pinaster Aiton kraft pulp and residual lignins. J. Anal. Appl. Pyrolysis 2009, 85:19-29.
29. Pinto P.C., Evtuguin D.V., Neto C.P., Silvestre A.J.D. Behavior of Eucalyptus globulus lignin during kraft pulping. I. Analysis by chemical degradation methods. J. Wood Chem. Technol. 2002, 22(2-3):93-108.
30. Requejo A., Rodríguez A., Colodette J.L., Gomide J.L., Jiménez L. TCF bleaching sequence in kraft puping of olive tree pruning residues. Bioresour. Technol. 2012, 117:117-123.
31. Sakakibara, A., Sano, Y., 2001. Chemistry of lignin, in: Hon, D.N.S., Shiraishi, N. (Eds.), Wood and cellulosic chemistry, New York, pp. 109-175.
32. Santos R.B., Capanema E.A., Balakshin M.Y., Chang H., Jameel H. Effect of hardwoods characteristics on kraft pulping process: emphasis on lignin structure. Bioresouces 2011, 6(4):3623-3637.
33. Sixta, H., Potthast, A., Krotschek, A.W., 2006. Chemical pulping processes, in: Sixta, E., (Ed.) Handbook of pulp, Wiley-Vch, Verlag, pp. 109-366.
34. White J.E., Catallo W.J., Legendre B.L. Biomass pyrolysis kinetics: a comparative critical review with relevant agriculture residue case studies. J. Anal. Appl. Pyrolysis 2011, 91:1-33.