Facile metalation of silicon and germanium analogues of thiocarboxylic acids with a manganese(II) hydride precursor

Chemistry - A European Journal

Volumn 18, Issue 36, 2012, Pages 11356-11361

  Yao, Shenglai ^a   Xiong, Yun ^a   Driess, Matthias ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

dioxygen activation; germanium; manganese; silicon; transition metals

Indexed keywords

DIOXYGEN ACTIVATION; DIOXYGENS; DONOR-ACCEPTOR INTERACTION; DOUBLE BONDS; ELECTRON DELOCALIZATION; HIGH YIELD; HYDRIDE PRECURSOR; METALATIONS; SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS; THIOCARBOXYLATE;

BROMINE COMPOUNDS; CARBOXYLATION; CHEMICAL ACTIVATION; GERMANIUM; HYDRIDES; MANGANESE COMPOUNDS; OXYGENATION; PARAMAGNETISM; SILICON; SYNTHESIS (CHEMICAL); TRANSITION METALS; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

MANGANESE;

CARBOXYLIC ACID; GERMANIUM; MANGANESE; ORGANOMETALLIC COMPOUND; SILICON; THIOL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CARBOXYLIC ACIDS; CRYSTALLOGRAPHY, X-RAY; GERMANIUM; MANGANESE; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; SILICON; SULFHYDRYL COMPOUNDS;

EID: 84865466646     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201201335     Document Type: Article

References (52)

1. N. Tokitoh, R. Okazaki, in The Chemistry of Organosilicon Compounds, Vol. 2 (Eds.:, Z. Rappoport, Y. Apeloig,), Wiley, New York, 1998, Chapter 17, pp. 1063-1103
2. J. Barrau, G. Rima, Coord. Chem. Rev. 1998, 178-180, 593
3. P. P. Power, Chem. Rev. 1999, 99, 3463
4. R. Okazaki, N. Tokitoh, Acc. Chem. Res. 2000, 33, 625
5. N. Tokitoh, R. Okazaki, Adv. Drug Delivery Rev. Adv. Organometallic Chem. 2001, 47, 121
6. N. Takeda, N. Tokitoh, R. Okazaki, Handbook of Chalcogen Chemistry (Ed.:, F. A. Devillanova,), The Royal Society of Chemistry, Cambridge, 2007, Chapter 3, pp. 195-222
7. S. Nagendran, H. W. Roesky, Organometallics 2008, 27, 457
8. S. M. Mandal, H. W. Roesky, Chem. Commun. 2010, 46, 6016
9. M. Asay, C. Jones, M. Driess, Chem. Rev. 2011, 111, 354
10. S. Yao, Y. Xiong, M. Driess, Organometallics 2011, 30, 1748.
11. M. Driess, S. Yao, M. Brym, C. van Wüllen, D. Lenz, J. Am. Chem. Soc. 2006, 128, 9628
12. M. Driess, S. Yao, M. Brym, C. van Wüllen, Angew. Chem. 2006, 118, 6882
13. Angew. Chem. Int. Ed. 2006, 45, 6730.
14. M. Driess, S. Yao, M. Brym, C. van Wüllen, Angew. Chem. 2006, 118, 4455
15. Angew. Chem. Int. Ed. 2006, 45, 4349.
16. S. Yao, M. Brym, C. Van Wüllen, M. Driess, Angew. Chem. 2007, 119, 4237
17. Angew. Chem. Int. Ed. 2007, 46, 4159
18. S. Yao, Y. Xiong, M. Brym, M. Driess, J. Am. Chem. Soc. 2007, 129, 7268
19. S. Yao, Y. Xiong, M. Brym, M. Driess, Chem. Asian J. 2008, 3, 113
20. J. D. Epping, S. Yao, Y. Apeloig, M. Karni, M. Driess, J. Am. Chem. Soc. 2010, 132, 5443
21. Y. Xiong, S. Yao, M. Driess, J. Am. Chem. Soc. 2009, 131, 7562
22. S. Yao, Y. Xiong, M. Driess, Chem. Eur. J. 2010, 16, 1281
23. Y. Xiong, S. Yao, R. Müller, M. Kaupp, M. Driess, J. Am. Chem. Soc. 2010, 132, 6912
24. Y. Xiong, S. Yao, R. Müller, M. Kaupp, M. Driess, Nat. Chem. 2010, 2, 577
25. Y. Xiong, S. Yao, M. Driess, Angew. Chem. 2010, 122, 6792
26. Angew. Chem. Int. Ed. 2010, 49, 6642
27. Y. Xiong, S. Yao, M. Driess, Dalton Trans. 2010, 39, 9282
28. S. Yao, Y. Xiong, M. Driess, Chem. Commun. 2009, 6466
29. S. Yao, Y. Xiong, M. Driess, Chem. Eur. J. 2011, 17, 4890.
30. L. W. Pineda, V. Jancik, H. W. Roesky, R. Herbst-Irmer, Angew. Chem. 2004, 116, 5650
31. Angew. Chem. Int. Ed. 2004, 43, 5534
32. L. W. Pineda, V. Jancik, H. W. Roesky, D. Neculai, A. M. Neculai, Angew. Chem. 2004, 116, 1443
33. Angew. Chem. Int. Ed. 2004, 43, 1419.
34. C. W. Hoganson, G. T. Babcock, Science 1997, 277, 1953
35. H. Sakiyama, A. Sugawara, M. Sakamoto, K. Unoura, K. Inoue, M. Yamasaki, Inorg. Chim. Acta 2000, 310, 163
36. J. Stubbe, W. A. van der Donk, Chem. Rev. 1998, 98, 705.
37. J. Prust, K. Most, I. Müller, A. Stasch, H. W. Roesky, I. Usõn, Eur. J. Inorg. Chem. 2001, 1613-1616
38. J. Chai, H. Zhu, K. Most, H. W. Roesky, D. Vidovic, H.-G. Schmidt, M. Noltemeyer, Eur. J. Inorg. Chem. 2003, 4332-4337
39. J. Chai, H. Zhu, H. W. Roesky, C. He, H. G. Schmidt, M. Noltemeyer, Organometallics 2004, 23, 3284
40. A. Panda, M. Stender, R. J. Wright, M. M. Olmstead, P. Klavins, P. P. Power, Inorg. Chem. 2002, 41, 3909.
41. J. Chai, H. Zhu, A. C. Stückl, H. W. Roesky, J. Magull, A. Bencini, A. Caneschi, D. Gatteschi, J. Am. Chem. Soc. 2005, 127, 9201.
42. D. F. Evans, J. Chem. Soc. 1959, 2003
43. T. Ayers, R. Turk, C. Lane, J. Goins, D. Jameson, S. J. Slattery, Inorg. Chim. Acta 2004, 357, 202.
44. S. Phol, W. Saak, P. Stolz, Z. Naturforsch. B: Chem. Sci. 1988, 43, 171.
45. W. A. Chomitz, J. Arnold, Dalton Trans. 2009, 1714-1720.
46. V. Riera, M. A. Ruiz, Organometallics 1993, 12, 2962
47. F. J. García Alonso, M. Garcia Sanz, V. Riera, M. A. Ruiz, A. Tiripicchio, M. Tiripicchio Camellini, Angew. Chem. 1988, 100, 1224
48. Angew. Chem. Int. Ed. Engl. 1988, 27, 1167.
49. I. Szekely, C. Silvestru, J. E. Drake, G. Balazs, S. I. Farcas, I. Haiduc, Inorg. Chim. Acta 2000, 299, 247.
50. M. Kaftory, M. Kapon, M. Botoshansky, in The Chemistry of Organic Silicon Compounds, Vol. 2, Part 1 (Eds.:, Z. Rappoport, Y. Apeloig,), Wiley, New York, 1998, pp. 228-233.
51. D. J. E. Spencer, A. M. Reynolds, P. L. Holland, B. A. Jazdzewski, C. Duboc-Toia, L. L. Pape, S. Yokota, Y. Tachi, S. Itoh, W. B. Tolman, Inorg. Chem. 2002, 41, 6307.
52. G. M. Sheldrick, SHELX-97 Program for Crystal Structure Determination, Universität Göttingen (Germany), 1997.