Synthesis and tunable reactivity of N-heterocyclic germylene

Chemistry - An Asian Journal

Volumn 7, Issue 9, 2012, Pages 2145-2150

  Xiong, Yun ^a   Yao, Shenglai ^a   Driess, Matthias ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

1,4 addition; bond activation; carbene homologues; diketiminates; germanium

Indexed keywords

1 ,4-ADDITION; ALKYNYLS; BENZYL GROUP; BOND ACTIVATION; CARBENES; CHLOROGERMYLENE; DEHYDROCHLORINATION; DIKETIMINATES; GERMYLENES; H NMR SPECTROSCOPY; LITHIATION; MULTINUCLEAR NMR SPECTROSCOPY; N-HETEROCYCLIC; PHENYLACETYLENES; SINGLE CRYSTAL X-RAY DIFFRACTION ANALYSIS;

ACETYLENE; AROMATIC HYDROCARBONS; ETHERS; GERMANIUM; LIGANDS; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

SYNTHESIS (CHEMICAL);

EID: 84865449736     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.201200379     Document Type: Article

References (29)

1. N. Tokitoh, R. Okazaki, Coord. Chem. Rev. 2000, 210, 251
2. "Recent Advances in structural chemistry of organic germanium, tin and lead compounds":, K. W. Klinkhammer, in The Chemistry of Organic Germanium, Tin and Lead Compounds, Vol. 2 (Ed.:, Z. Rappoport,), Wiley, New York, 2002, chap. 4, pp. 284-332
3. O. Kühl, Coord. Chem. Rev. 2004, 248, 411
4. N. J. Hill, R. West, J. Organomet. Chem. 2004, 689, 4165
5. M. Kira, J. Organomet. Chem. 2004, 689, 4475
6. I. Saur, S. G. Alonso, J. Barrau, Appl. Organomet. Chem. 2005, 19, 414
7. W. P. Leung, K. W. Kan, K. H. Chong, Coord. Chem. Rev. 2007, 251, 2253
8. A. V. Zabula, F. E. Hahn, Eur. J. Inorg. Chem. 2008, 5165
9. S. Nagendran, H. W. Roesky, Organometallics 2008, 27, 457
10. Y. Mizuhata, T. Sasamori, N. Tokitoh, Chem. Rev. 2009, 109, 3479
11. S. M. Mandal, H. W. Roesky, Chem. Commun. 2010, 46, 6016
12. M. Asay, C. Jones, M. Driess, Chem. Rev. 2011, 111, 354
13. S. Yao, Y. Xiong, M. Driess, Organometallics 2011, 30, 1748.
14. J. Feldman, S. J. McLain, A. Parthasarathy, W. J. Marshall, J. C. Calabrese, S. D. Arthur, Organometallics 1997, 16, 1514.
15. W. Clegg, E. K. Cope, A. J. Edwards, F. S. Mair, Inorg. Chem. 1998, 37, 2317.
16. L. Bourget-Merle, M. F. Lappert, J. R. Severn, Chem. Rev. 2002, 102, 3031
17. S. Yao, M. Driess, Acc. Chem. Res. 2012, 45, 276.
18. M. Driess, S. Yao, M. Brym, C. Van Wüllen, D. Lenz, J. Am. Chem. Soc. 2006, 128, 9628
19. M. Driess, S. Yao, M. Brym, C. van Wüllen, Angew. Chem. 2006, 118, 4455
20. Angew. Chem. Int. Ed. 2006, 45, 4349
21. Y. Xiong, S. Yao, M. Driess, unpublished results
22. W. D. Woodul, E. Carter, R. Müller, A. F. Richards, A. Stasch, M. Kaupp, D. M. Murphy, M. Driess, C. Jones, J. Am. Chem. Soc. 2011, 133, 10074.
23. Y. Xiong, S. Yao, M. Driess, Chem. Asian J. 2009, 4, 1323.
24. W. Wang, S. Inoue, S. Yao, M. Driess, Organometallics 2011, 30, 6490.
25. D. T. Carey, E. K. Cope-Eatough, E. Vilaplana-Mafe, F. S. Mair, R. G. Pritchard, J. E. Warren, R. J. Woods, Dalton Trans. 2003, 1083.
26. Y. Ding, H. W. Roesky, M. Noltemeyer, H. G. Schmidt, P. P. Power, Organometallics 2001, 20, 1190
27. Y. Ding, H. W. Roesky, M. Noltemeyer, H. G. Schmidt, P. P. Power, Inorg. Chem. 2001, 40, 5314.
28. S. Yao, C. van Wüllen, M. Driess, Chem. Commun. 2008, 5393.
29. G. M. Sheldrick, SHELX-97 Program for Crystal Structure Determination, Universität Göttingen (Germany) 1997.