A neutral, monomeric germanium(I) radical

Journal of the American Chemical Society

Volumn 133, Issue 26, 2011, Pages 10074-10077

  Woodul, William D ^a   Carter, Emma ^b   Müller, Robert ^c   Richards, Anne F ^a   Stasch, Andreas ^a   Kaupp, Martin ^c   Murphy, Damien M ^b   Driess, Matthias ^c   Jones, Cameron ^a  

^a MONASH UNIVERSITY   (Australia)

^b CARDIFF UNIVERSITY   (United Kingdom)

^c TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORIDE COMPLEXES; RADICAL COMPLEXES; STOICHIOMETRIC REDUCTION;

CHLORINE COMPOUNDS; DIMERS; MAGNESIUM; SODIUM; X RAY CRYSTALLOGRAPHY;

GERMANIUM;

CHLORIDE; DIMER; GERMANIUM; GERMANIUM DERIVATIVE; GERMANIUM RADICAL; MAGNESIUM; METAL COMPLEX; NAPHTHALENE DERIVATIVE; NAPHTHALENIDE SODIUM; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; ELECTRON SPIN RESONANCE; MATHEMATICAL COMPUTING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; REDUCTION; STOICHIOMETRY; X RAY CRYSTALLOGRAPHY;

EID: 79959892420     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja204344e     Document Type: Article

References (28)

1. Power, P. P. Nature 2010, 463, 171
2. Lee, V. Y.; Sekiguchi, A. Acc. Chem. Res. 2007, 40, 410
3. Lee, V. Y.; Sekiguchi, A. Eur. J. Inorg. Chem. 2005, 1209
4. Power, P. P. Chem. Rev. 2003, 103, 789
5. •, was reported almost 40 years ago. See: Davidson, P. J.; Hudson, A.; Lappert, M. F.; Lednor, P. W. J. Chem. Soc., Chem. Commun. 1973, 829
6. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley: Toronto, 2001.
7. The Activation of Small Molecules; Tolman, W. B., Ed.; Wiley-VCH; Weinheim, Germany, 2006.
8. 2-2,6], has been described. See: Olmstead, M. M.; Pu, L.; Simons, R. S.; Power, P. P. Chem. Commun. 1997, 1595
9. Asay, M.; Jones, C.; Driess, M. Chem. Rev. 2011, 111, 354
10. Sekiguchi, A. Pure Appl. Chem. 2008, 80, 447
11. Power, P. P. Organometallics 2007, 26, 4362
12. Woodul, W. D.; Richards, A. F.; Stasch, A.; Driess, M.; Jones, C. Organometallics 2010, 29, 3655
13. Bonyhady, S. J.; Jones, C.; Nembenna, S.; Stasch, A.; Edwards, A. J.; McIntyre, G. J. Chem. - Eur. J. 2010, 16, 938
14. Stasch, A.; Jones, C. Dalton Trans. 2011, 40, 5659
15. Jones, C.; Bonyhady, S. J.; Holzmann, N.; Frenking, G.; Stasch, A. Inorg. Chem. [Online early access]. DOI: 10.1021/ic200682p. Published Online: May 6, 2011.
16. 2(μ- Cl)}] was obtained (see the Supporting Information for crystallographic details).
17. Conroy, K. D.; Piers, W. E.; Parvez, M. Organometallics 2009, 28, 6228
18. Stender, M.; Phillips, A. D.; Power, P. P. Inorg. hem. 2001, 40, 5314
19. Compound 1 decomposes via an unidentified paramagnetic intermediate. Its approximate half-life was determined by NMR spectroscopy (see the Supporting Information for details).
20. Egorov, M. P.; Nefedov, O. M.; Lin, T.-S.; Gaspar, P. P. Organometallics 1995, 14, 1539
21. Sekiguchi, A.; Fukawa, T.; Nakamoto, M.; Lee, V. Y.; Ichinohe, M. J. Am. Chem. Soc. 2002, 124, 9868
22. Cotton, J. D.; Cundy, C. S.; Harris, D. H.; Huson, A.; Lappert, M. F.; Lendor, P. W. J. Chem. Soc., Chem. Commun. 1974, 651
23. Tumanskii, B.; Pine, P.; Apeloig, Y.; Hill, N. J.; West, R. J. Am. Chem. Soc. 2005, 127, 8248
24. Bourget-Merle, L.; Lappert, M. F.; Severin, J. R. Chem. Rev. 2002, 102, 3031
25. For example, see: Khusniyarov, M. M.; Bill, E.; Weyhermüller, T.; Bothe, E.; Wieghardt, K. Angew. Chem., Int. Ed. 2011, 50, 1652
26. Eisenstein, O.; Hitchcock, P. B.; Khvostov, A. V.; Lappert, M. F.; Maron, L.; Perrin, L.; Protchenko, A. V. J. Am. Chem. Soc. 2003, 125, 10790
27. Jana, A.; Ghoshal, D.; Roesky, H. W.; Objartel, I.; Schwab, G.; Stalke, D. J. Am. Chem. Soc. 2009, 131, 1288
28. Ding, Y.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H.-G.; Power, P. P. Organometallics 2001, 20, 1190