Esterification of lauric acid with butanol over mesoporous materials

Renewable Energy

Volumn 50, Issue , 2013, Pages 585-589

  Barros, Suellen D T ^a   Coelho, Aline V ^a   Lachter, Elizabeth R ^a   San Gil, Rosane A S ^a   Dahmouche, Karim ^a   Pais da Silva, Maria Isabel ^b   Souza, Andrea L F ^a  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

^b PONTIFICAL CATHOLIC UNIVERSITY OF RIO DE JANEIRO   (Brazil)

Author keywords

Butanol; Esterification; Lauric acid; Mesoporous materials; MgO SBA 15; ZnO SBA 15

Indexed keywords

1-BUTANOL; ADSORPTION/DESORPTION; ESTERIFICATION REACTIONS; IMPREGNATION METHODS; LAURIC ACID; MAS NMR; MESOPOROUS SILICA; MGO; MILD REACTION; NANOSTRUCTURAL; SMALL ANGLE X-RAY SCATTERING; SOLID-STATE NUCLEAR MAGNETIC RESONANCE; ZNO;

ALCOHOLS; BUTENES; ESTERIFICATION; ESTERS; MAGIC ANGLE SPINNING; SATURATED FATTY ACIDS; SILICON; X RAY DIFFRACTION;

MESOPOROUS MATERIALS;

ADSORPTION; ALCOHOL; ESTER; FATTY ACID; ISOTHERM; MAGNESIUM; POROSITY; RENEWABLE RESOURCE; SILICA; ZINC;

EID: 84865318610     PISSN: 09601481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.renene.2012.06.059     Document Type: Article

References (30)

1. Lotero E., Liu Y., Lopez D.E., Suwannakarn K., Bruce D.A., Goodwin J.G. Synthesis of biodiesel via acid catalysis. Ind Eng Chem Res 2005, 44:5353-5363.
2. Rodrigues J.A., Cardoso F.P., Lachter E.R., Estevão L.R.M., Nascimento R.S.V. Correlating chemical structure and physical properties of vegetable oil esters. J Am Oil Chem Soc 2006, 83:353-357.
3. Hoydonckx H.E., De Vos D.E., Chavan S.A., Jacobs P.A. Esterification and transesterification of renewable chemicals. Top Catal 2004, 27:83-96.
4. Serio MDi, Tesser R., Pwengmel L., Santacesaria E. Heterogeneous catalysts for biodiesel production. Energy Fuels 2008, 22:207-217.
5. Lopez D.E., Goodwin J.G., Bruce D.A., Lotero E. Transesterification of triacetin with methanol on solid acid and base catalysts. Appl Catal A Gen 2005, 295:97-105.
6. Rezende S.M., Reis M.C., Reid M.G., Silva P.L., Coutinho F.M.B., San Gil R.A.S., et al. Transesterification of vegetable oils promoted by poly(styrene-divinylbenzene) and poly(divinylbenzene). Appl Catal A Gen 2008, 349:198-203.
7. Kiss A.A., Dimian A.C., Rothemberg G. Solid acid catalysts for biodiesel production --towards sustainable energy. Adv Synth Catal 2006, 348:75-81.
8. Ni J., Meunier F.C. Esterification of free fatty acids in sunflower oil over solid acid catalysts using batch and fixed bed-reactors. Appl Catal A Gen 2007, 333:122-130.
9. Mbaraka I.K., Shanks B.H. Conversion of oils and fats using advanced mesoporous heterogeneous catalysts. J Am Oil Chem Soc 2006, 83:79-91.
10. Morin P., Sapaly G., Rocha M.G.C., de Oliveira P.G.P., Gonzalez W.A., Sales E.A., et al. Transesterification of rapeseed oil with ethanol: I. Catalysis with homogeneous Keggin heteropolyacids. Appl Catal A Gen 2007, 330:69-76.
11. Melero J.Á., Iglesias J., Morales G. Heterogeneous acid catalysts for biodiesel production: current status and future challenges. Green Chem 2009, 11:1285-1308.
12. Melero J.A., Bautista L.F., Morales G., Iglesias J., Briones D. Biodiesel production with heterogeneous sulfonic acid-functionalized mesostructured catalysts. Energy Fuels 2009, 23:539-547.
13. Liu H., Xue N., Peng L., Guo X., Ding W., Chen Y. The hydrophilic/hydrophobic effect of porous solid acid catalysts on mixed liquid phase reaction of esterification. Catal Comm 2009, 10:1734-1737.
14. Li E., Rudolph V. Biodiesel production with heterogeneous sulfonic acid-functionalized mesostructured catalysts. Energy Fuels 2008, 22:145-149.
15. Melero J.A., Bautista L.F., Morales G., Iglesias J., Sánchez-Vásquez R. Biodiesel production from crude palm oil using sulfonic acid-modified mesostructured catalysts. Chem Eng J 2010, 161:323-339.
16. Lisboa F.S., Arizaga G.G.C., Wypych F. Esterification of free fatty acyds using layred carboxylates and hydroxide salts as catalysts. Top Catal 2011, 8-9:474-481.
17. Zatta L., Gardolinski J.E.C., Wypych F. Raw halloysite as reusable heterogeneous catalyst for esterification of lauric acid. Appl Clay Sci 2011, 51:165-169.
18. Leadbeater N.E., Barnard T.M., Stencel L. Batch and continuous-flow preparation of biodiesel derived from butanol and facilitated by microwave heating. Energy Fuels 2008, 22:2005-2008.
19. Fulvio P.F., Pikus S., Jaroniec M. Short-time synthesis of SBA-15 using various silica sources. J Colloid Interface Sci 2005, 287:717-720.
20. Massiot D., Fayon F., Capron M., King I., Le Calve S., Alonso B., et al. Modelling one- and two-dimensional solid-state NMR spectra. Magn Reson Chem 2002, 40:70-76.
21. Vizcaíno A.J., Carrero A., Calles J.á. Ethanol steam reforming on Mg- and Ca-modified Cu-Ni/SBA-15 catalysts. Catal Today 2009, 146:63-70.
22. Sun H., Han J., Ding Y., Li W., Duan J., Chen P., et al. One-pot synthesized mesoporous Ca/SBA-15 solid base for transesterification of sunflower oil with methanol. Appl Catal A Gen 2010, 390:26-34.
23. Hu W., Luo Q., Su Y., Chen L., Yue Y., Ye C., et al. Acid sites in mesoporous Al-SBA-15 material as revealed by solid-state NMR spectroscopy. Microporous Mesoporous Mater 2006, 92:22-30.
24. Du J., Xu H., Shen J., Huang J., Shen W., Zhao D. Catalytic dehydrogenation and cracking of industrial dipentene over M/SBA-15 (M = Al, Zn) catalysts. Appl Catal A Gen 2005, 296:186-193.
25. Mihai G.D., Meynem V., Mertens M., Bilba N., Cool P., Vansant E.F. ZnO nanoparticles supported on mesoporous MCM-41 and SBA-15: a comparative physicochemical and photocatalytic study. J Mater Sci 2010, 45:5786-5794.
26. Albuquerque M.C.G., Urbistondo I.J., González J.S., Robles J.M.M., Tost R.M., Castellón E.R., et al. CaO supported on mesoporous silicas as basic catalysts for transesterification reactions. Appl Catal A Gen 2008, 334:35-43.
27. Juan J.C., Zhang J., Yarmoa M.A. 12-Tungstophosphoric acid supported on MCM-41 for esterification of fatty acid under solvent-free condition. J Mol Catal A 2007, 267:265-271.
28. Hanh H.D., Dong N.T., Okitsu K., Nishimura R., Maeda Y. Biodiesel production by esterification of oleic acid with short-chain alcohols under ultrasonic irradiation condition. Renewable Energy 2009, 34:780-783.
29. Juan J.C., Zhang J., Yarmo M.A. Study of catalysts comprising zirconium sulfate supported on a mesoporous molecular sieve HMS for esterification of fatty acids under solvent-free condition. Appl Catal A Gen 2008, 347:133-141.
30. Antunes W.M., Veloso C.O., Henriques C.A. Transesterification of soybean oil with methanol catalyzed by basic solids. Catal Today 2008, 133-35:548-554.