One-step vs stepwise immobilization of 1-D coordination-based Rh-Rh molecular wires on gold surfaces

Langmuir

Volumn 28, Issue 32, 2012, Pages 11779-11789

  Lokesh, Koodlur Sannegowda ^a   Chardon Noblat, Sylvie ^a   Lafolet, Frédéric ^a   Traoré, Youssouf ^a   Gondran, Chantal ^a   Guionneau, Philippe ^b   Guérente, Liliane ^a   Labbé, Pierre ^a   Deronzier, Alain ^a   Létard, Jean François ^b  

^a Centre National de la Recherche Scientifique   (France)

^b UNIVERSITÉ DE BORDEAUX   (France)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,10-PHENANTHROLINE; CHAIN STRUCTURE; COUNTER ANIONS; DIMERIC UNITS; EQUATORIAL PLANES; FREE END; FUNCTIONALIZATIONS; GOLD SURFACES; IMPEDANCE SPECTROSCOPY; METAL CENTERS; MOLECULAR ASSEMBLY; MOLECULAR WIRES; NITROGEN ATOM; ORGANIC LINKERS; PHYSICOCHEMICAL STUDIES; PYRAZINES;

CONTACT ANGLE; COORDINATION REACTIONS; CYCLIC VOLTAMMETRY; DIMERS; NANOWIRES; X RAY DIFFRACTION ANALYSIS;

RHODIUM;

EID: 84865165558     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la3012537     Document Type: Article

References (42)

1. Tao, N. J. Electron transport in molecular junctions Nat. Nanotechnol. 2006, 173-181
2. Ulgut, B.; Abruña, H. D. Electron transfer through molecules and assemblies at electrode surfaces Chem. Rev. 2008, 108, 2721-2736
3. Nitzan, A.; Ratner, M. A. Electron transport in molecular wire junctions Science 2003, 300, 1384-1389 (Pubitemid 36638150)
4. Amatore, C.; Maisonhaute, E.; Schöllhorn, B.; Wadhawan, J. Ultrafast voltammetry for probing interfacial electron transfer in molecular wires Chem. Phys. Chem. 2007, 8, 1321-1329
5. Reed, M. A.; Zhou, C.; Muller, C. J.; Burgin, T. P.; Tour, J. M. Conductance of a molecular junction Science 1997, 278, 252-254 (Pubitemid 27450865)
6. Haga, M.; Kobayashi, K.; Terada, K. Fabrication and functions of surface nanomaterials based on multilayered or nanoarrayed assembly of metal complexes Coord. Chem. Rev. 2007, 251, 2688-2701
7. Nishihara, H.; Kanaizuka, K.; Nishimori, Y.; Yamanoi, Y. Construction of redox- and photo-functional molecular systems on electrode surface for application to molecular devices Coord. Chem. Rev. 2007, 251, 2674-2687
8. Ulman, A. Formation and structure of self-assembled monolayers Chem. Rev. 1996, 96, 1533-1554 (Pubitemid 126639367)
9. Maskus, M.; Abruña, H. D. Synthesis and characterization of redox-active metal complexes sequentially self-assembled onto gold electrodes via a new thiol-terpyridine ligand Langmuir 1996, 12, 4455-4462 (Pubitemid 126536464)
10. Utsuno, M.; Toshimitsu, F.; Kume, S.; Nishihara, H. Synthesis of an anthraquinone-bridged bis(terpyridine) ligand and its use in the stepwise fabrication of complex oligomer wires on gold Macromol. Symp. 2008, 270, 153-160
11. Tuccitto, N.; Delfanti, I.; Torrisi, V.; Scandola, F.; Chiorboli, C.; Stepanenko, V.; Würthner, F.; Licciardello, A. Supramolecular self-assembled multilayers of terpyridine-functionalized perylene bisimide metal complexes Phys. Chem. Chem. Phys. 2009, 11, 4033-4038
12. Winter, A.; Hoeppener, S.; Newkome, G. R.; Schubert, U. S. Terpyridine-functionalized surfaces: redox-active, switchable, and electroactive nanoarchitectures Adv. Mater. 2011, 23, 3484-3498
13. Lin, C.; Kagan, C. R. Layer-by-layer growth of metal-metal bonded supramolecular thin films and its use in the fabrication of lateral nanoscale devices J. Am. Chem. Soc. 2003, 125, 336-337 (Pubitemid 36077846)
14. Mahapatro, A. K.; Ying, J..; Ren, T.; Janes, D. B. Electronic transport through ruthenium-based redox-active molecules in metal-molecule-metal nanogap junctions Nano Lett. 2008, 8, 2131-2136
15. -) Chem. Commun. 2010, 46, 1338-1340
16. n molecular wire Eur. J. Inorg. Chem. 2009, 111-118
17. Lafolet, F.; Chardon-Noblat, S.; Duboc, C.; Deronzier, A.; Pruchnik, F. P.; Rak, M. Electrochemical fabrication and characterization of thin films of redox-active molecular wires based on extended Rh-Rh bonded chains Dalton Trans. 2008, 2149-2156 (Pubitemid 351503480)
18. 2+ complexes; dbbpy = 4,4′-di-tert-butyl-2, 2′-bipyridine. Synthesis and physicochemical characterization Polyhedron 2010, 29, 3059-3065
19. Ozoemena, K. I.; Nyokong, T. Surface electrochemistry of iron phthalocyanine axially ligated to 4-mercaptopyridine self-assembled monolayers at gold electrode: Applications to electrocatalytic oxidation and detection of thiocyanate J. Electroanal. Chem. 2005, 579, 283-289 (Pubitemid 40626023)
20. Sheldrick, G. M. Programs for Crystal Structure Analysis (Release 97-2); Institüt für Anorganische Chemie der Universität: Göttingen, Germany, 1998.
21. Farrugia, L. J. WinGX suite for small-molecule single-crystal crystallography J. Appl. Crystallogr. 1999, 32, 837-838 (Pubitemid 129794704)
22. Coche-Guerente, L.; Desbrieres, J.; Fatisson, J.; Labbe, P.; Rodriguez, M. C.; Rivas, G. Physicochemical characterization of the layer-by-layer self-assembly of polyphenol oxidase and chitosan on glassy carbon electrode Electrochim. Acta 2005, 50, 2865-2877 (Pubitemid 40552648)
23. Takamizawa, S.; Hiroki, T.; Nakata, E.; Mochizuki, K.; Mori, W. Crystal structure and gas adsorption property of rhodium(II) benzoate pyrazine Chem. Lett. 2002, 1208-1209 (Pubitemid 36419041)
24. Crawford, C. A.; Matonic, J. H.; Huffman, J. C.; Folting, K.; Dunbar, K. R.; Christou, G. Reaction of nitrogen chelates with the [Rh2]4+ core: bis-chelate products and demonstration of reversible, chelate-based reduction processes Inorg. Chem. 1997, 36, 2361-2371 (Pubitemid 127485442)
25. Pruchnik, F. P.; Kluczewska, G.; Wilczok, A.; Mazurek, U.; Wilczok, T. Rhodium(II) complexes with phenanthrolines and their metabolic action on synchronized cell culture J. Inorg. Biochem. 1997, 65, 25-34 (Pubitemid 27016598)
26. Bien, M.; Lachowicz, T. M.; Rybka, A.; Pruchnik, F. P.; Trynda, L. Binuclear Rhodium(II) Complexes With Selective Antibacterial Activity Metal-Based Drugs 1997, 4, 81-88 (Pubitemid 27359009)
27. Pruchnik, F. P.; Jakimowicz, P.; Ciunik, Z. Synthesis and structural characterization of new one-dimensional rhodium complexes Inorg. Chem. Commun. 2001, 4, 726-729 (Pubitemid 33135953)
28. Love, J. C.; Estroff, L. A.; Kriebel, J. K.; Nuzzo, R. G.; Whitesides, G. M. Self-assembled monolayers of thiolates on metals as a form of nanotechnology Chem. Rev. 2005, 105, 1103-1169 (Pubitemid 40600878)
29. Sawaguchi, T.; Mizutani, F.; Yoshimoto, S.; Taniguchi, I. Voltammetric and in situ STM studies on self-assembled monolayers of 4-mercaptopyridine, 2-mercaptopyridine and thiophenol on Au(111) electrodes Electrochim. Acta 2000, 45, 2861-2867
30. Kučera, J.; Gross, A. Adsorption of 4-Mercaptopyridine on Au(111): A Periodic DFT Study Langmuir 2008, 24, 13985-13992
31. Dubacheva, G. V.; Van Der Heyden, A.; Dumy, P.; Kaftan, O.; Auzely-Velty, R.; Coche-Guerente, L.; Labbe, P. Electrochemically controlled adsorption of Fc-functionalized polymers on β-CD-modified self-assembled monolayers Langmuir 2010, 26, 13976-13986
32. Tuccitto, N.; Torrisi, V.; Cavazzini, M.; Morotti, T.; Puntoriero, F.; Quici, S.; Campagna, S.; Licciardello, A. Stepwise formation of ruthenium(II) complexes by direct reaction on organized assemblies of thiol-terpyridine species on gold Chem. Phys. Chem. 2007, 8, 227-230
33. Bien, M.; Pruchnik, F. P.; Seniuk, A.; Lachowicz, T. M.; Jakimowicz, P. Studies of antibacterial activity of binuclear rhodium(II) complexes with heterocyclic nitrogen ligands J. Inorg. Biochem. 1999, 73, 49-55 (Pubitemid 29165392)
34. Kosbar, L.; Srinivasan, C.; Afzali, A.; Graham, T.; Copel, M.; Krusin-Elbaum, L. Self-assembled multilayers of transition-metal-terpyridinyl complexes; formation, and characterization Langmuir 2006, 22, 7631-7638 (Pubitemid 44373436)
35. Greenler, R. G. Infrared study of adsorbed molecules on metal surfaces by reflection techniques J. Chem. Phys. 1966, 44, 310-315
36. Komadina, J.; Walch, S.; Fasching, R.; Grossman, A.; Prinz, F. B. Reversible Oxidation of Spinach Ferredoxin at Surface-Modified Electrodes J. Electrochem. Soc. 2008, 155, B1008-B1012
37. Hara, M.; Tamada, K.; Hahn, C.; Nishida, N.; Knoll, W. Adsorption and desorption processes of self-assembled monolayers studied by surface-sensitive microscopy and spectroscopy Supramol. Sci. 1996, 3, 103-109
38. Degefa, T. H.; Kwak, J. Electrochemical impedance sensing of DNA at PNA self assembled monolayer J. Electroanal. Chem. 2008, 612, 37-41 (Pubitemid 350236167)
39. Ganesh, V.; Pal, S. K.; Kumar, S.; Lakshminarayanan, V. Self-assembled monolayers (SAMs) of alkoxycyanobiphenyl thiols on gold-A study of electron transfer reaction using cyclic voltammetry and electrochemical impedance spectroscopy J. Colloid Interface Sci. 2006, 296, 195-203
40. Park, B.-W.; Yoon, D.-Y.; Kim, D.-S. Formation and modification of a binary self-assembled monolayer on a nano-structured gold electrode and its structural characterization by electrochemical impedance spectroscopy J. Electroanal. Chem. 2011, 661, 329-335
41. Matemadombo, F.; Westbroek, P.; Nyokong, T.; Ozoemena, K.; De Clerck, K.; Kiekens, P. Immobilization of tetra-amine substituted metallophthalocyanines at gold surfaces modified with mercaptopropionic acid or DTSP-SAMs Electrochim. Acta 2007, 52, 2024-2031 (Pubitemid 44958429)
42. Ozoemena, K. I.; Nyokong, T. Comparative electrochemistry and electrocatalytic activities of cobalt, iron and manganese phthalocyanine complexes axially co-ordinated to mercaptopyridine self-assembled monolayer at gold electrodes Electrochim. Acta 2006, 51, 2669-2677 (Pubitemid 43279689)