Evolution and interlayer dynamics of active sites of promoted transition metal sulfide catalysts under hydrodesulfurization conditions

Fuel

Volumn 100, Issue , 2012, Pages 2-16

  Kogan, Victor M ^a   Nikulshin, Pavel A ^b   Rozhdestvenskaya, Nadezhda N ^a  

^a N D ZELINSKY INSTITUTE OF ORGANIC CHEMISTRY   (Russian Federation)

^b SAMARA STATE TECHNICAL UNIVERSITY   (Russian Federation)

Author keywords

Catalysis; CoMoS catalysts; Hydrodesulfurization; Thiophene; Transition metal sulfides

Indexed keywords

ACTIVE SITE; ADSORBED HYDROGEN; CATALYTIC REACTIONS; CRITICAL INFORMATION; DYNAMIC MIGRATION; GASPHASE; HETEROLYTIC DISSOCIATION; HYDROCARBON FEEDSTOCK; HYDROTREATING CATALYSTS; MECHANISTIC MODELS; METAL SULFIDES; MOLYBDENUM SULFIDE; RATIONAL DESIGN; REACTION CONDITIONS; SULFIDE LAYERS; TYPE II;

ATOMS; CATALYSIS; CHEMICAL BONDS; COBALT; HYDRIDES; HYDRODESULFURIZATION; HYDROGEN; MOLYBDENUM; MOLYBDENUM COMPOUNDS; NICKEL; SULFUR; THIOPHENE;

CATALYST ACTIVITY;

EID: 84865017304     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2011.11.016     Document Type: Conference Paper

References (42)

1. H. Topsoe, and B.S. Clausen Importance of Co-Mo-S type structures in hydrodesulfurization Catal Rev - Sci Eng 26 1984 395 420 (Pubitemid 15481150)
2. N.Y. Topsoe, and H. Topsoe Characterization of the structures and active sites in sulfided cobalt-molybdenum/alumina and nickel-molybdenum/alumina catalysts by nitric oxide chemisorption J Catal 84 1983 386 401
3. S. Kasztelan, H. Toulhoat, J. Grimblot, and J.-P. Bonnelle A geometrical model of the active phase of hydrotreating catalysts Appl Catal 13 1984 127 159 (Pubitemid 15427601)
4. S. Harris, and R.R. Chianelli Catalysis by transition-metal sulfides - a theoretical and experimental-study of the relation between the synergic systems and the binary transition-metal sulfides J Catal 98 1986 17 31
5. M. Daage, and R.R. Chianelli Structure-function relations in molybdenum sulfide catalysts - the rim-edge model J Catal 149 1994 414 427
6. S. Eijsbouts On the flexibility of the active phase in hydrotreating catalysts. A review Appl Catal A Gen 158 1997 53 92 (Pubitemid 127391060)
7. 2 structures in high-activity hydrotreating catalysts. 2. Evolution of the active phase during the catalyst life cycle - deactivation model Appl Catal A: Gen 105 1993 69 82
8. 3 hydroprocessing catalysts J Catal 229 2005 352 364
9. B.M. Vogelaar, P. Steiner, T.F. van der Zijden, A. Dick van Langeveld, S. Eijsbouts, and J.A. Moulijn Catalyst deactivation during thiophene HDS: The role of structural sulfur Appl Catal A: Gen 318 2007 28 36 (Pubitemid 46054425)
10. 3 catalysts in working state Catal Today 130 2008 97 108 (Pubitemid 350130323)
11. B. Guichard, M.M. Roy-Auberger, E.E. Devers, C.C. Pichon, C.C. Legens, and P. Lecour Influence of the promoter's nature (nickel or cobalt) on the active phases 'Ni(Co)MoS' modifications during deactivation in HDS of diesel fuel Catal Today 149 2010 2 10
12. G.V. Isagulyants, A.A. Greish, and V.M. Kogan Sulfidation of an aluminocobaltomolibdenum catalyst using the S-35 radioisotope Kinet Catal 28 1987 220 223 (Pubitemid 18535704)
13. G.V. Isagulyants, A.A. Greish, V.M. Kogan, G.M. Vyunova, and G.V. Antoshin Study of the mechanism of hydrogenolysis of thiophene on an aluminum-cobalt-molybdenum catalyst and molybdenum-disulfide using S-35 Kinet Catal 28 1987 550 555 (Pubitemid 18551984)
14. G.V. Isagulyants, A.A. Greish, and V.M. Kogan Study of the mechanism of hydrogenolysis of thiophene on an aluminum-cobalt-molybdenum catalyst and molybdenum-disulfide using tritium Kinet Catal 28 1987 555 559 (Pubitemid 18551985)
15. G.V. Isagulyants, A.A. Greish, V.M. Kogan, and G.M. Vyunova Study of sulphidation of an aluminium-cobalt-molybdenum hydrodesulfurization catalyst by elemental sulphur with the aid of the S-35 radioisotope Kinet Catal 30 1989 882 885
16. 3 catalyst. In: Phillips MJ, Ternan M, editors. Proc 9th international congress on catalysis, vol. l, Ottawa, Canada; 1988, p. 35-41.
17. 3 catalysts using S-35 Catal Lett 6 1990 157 162
18. Kogan VM. Reaction dynamics during C-S bond breaking in sulphur-containing molecules: isotope studies. In: Weber T, Prins R, van Santen R, editors. Transition Metal Sulfides. Chemistry and Catalysis, NATO ASI Series, Kluwer Academic Publishers, 3. High Technology, vol. 60; 1998. p. 235-71.
19. 3 sulfide catalysts for HDS. Part I. Active site monitoring Appl Catal A: Gen 234 2002 207 219 (Pubitemid 34782486)
20. 3 sulfide catalysts for HDS. Part II. Temperature effects Appl Catal A: Gen 237 2002 161 169
21. V.M. Kogan, and G.V. Isaguliants The HDS mechanism: which "auxiliary" process takes place - sulfur isotopic exchange or replacement - and why is it important to know it? Catal Today 130 2008 243 248 (Pubitemid 350123018)
22. L. Melander, and W.H. Saunders Reaction rates of isotopic molecules 1980 John Wiley & Sons, Inc.
23. V.M. Kogan, N.M. Parfenova, R.G. Gaziev, N.N. Rozhdestvenskaya, and I.K. Korshevets In situ radioisotopic study of the active sites of sulfide CoMo catalysts and the mechanism of thiophene hydrodesulfurization Kinet Catal 44 2003 583 599
24. 2 catalytic nanoparticles induced by working conditions: a theoretical study J Catal 207 2002 76 87
25. M. Sun, J. Adjaye, and A.E. Nelson Theoretical investigations of the structures and properties of molybdenum-based sulfide catalysts Appl Catal A: Gen 263 2004 131 255
26. 2 hydrodesulfurization catalyst: DFT study of the mechanism J Phys Chem B 107 2003 4057 4064
27. V.M. Kogan, and P.A. Nikulshin On the dynamic model of promoted molybdenum sulfide catalysts Catal Today 149 2010 224 231
28. B. Delmon Selectivity in HDS, HDN, HDO and hydrocracking. Contribution of remote control and other new concepts Bull Soc Chim Belg 104 1995 173 187
29. 3 and activated charcoal Kinet Catal 46 2005 77 87 (Pubitemid 40394885)
30. 35S Oil Gas Sci Technol - Rev IFP 61 2006 547 559
31. 2-based catalysts Catal Today 111 2006 44 51 (Pubitemid 41817428)
32. H. Topsoe, B. Hinnemann, J.K. Norskov, J.V. Lauritsen, F. Besenbacher, and P.L. Hansen The role of reaction pathways and support interactions in the development of high activity hydrotreating catalysts Catal Today 107 2005 12 22
33. 2 catalysts at realistic conditions: a density functional study J Catal 248 2007 188 203 (Pubitemid 46735941)
34. H. Topsoe The role of Co-Mo-S type structures in hydrotreating catalysts Appl Catal A: Gen 322 2007 3 8 (Pubitemid 46453159)
35. G.A. Camacho-Bragado, J.L. Elechiguerra, A. Olivas, S. Fuentes, D. Galvan, and M. Jose Yacaman Structure and catalytic properties of nanostructured molybdenum sulfides J Catal 234 2005 182 190
36. 6 nanowires Nano Lett 8 2008 3928 3931
37. P.A. Nikulshin, N.N. Tomina, A.A. Pimerzin, A.V. Kucherov, and V.M. Kogan Investigation into the role of the intermediate carbon carrier on the catalytic activity of the HDS catalysts prepared using heteropolycompounds Catal Today 149 2010 82 90
38. M.T. Pope Heteropoly and isopoly metallates 1990 Springer Berlin
39. M.T. Pope Heteropoly and isopoly metallates 1983 Nauka Novosibirsk
40. G. Brauer Handbuch der praporativen anorganischen chemie 1975-1981 Ferdinand Enke Stuttgart
41. G. Brauer Handbuch der praporativen anorganischen chemie 1986 Mir Moscow
42. 3 sulfide catalysts for HDS. Part III. Poisoning by N-containing compounds Appl Catal A: Gen 237 2003 161 169