Enantioselective synthesis of α-alkyl-β-ketoesters: Asymmetric Roskamp reaction catalyzed by an oxazaborolidinium ion

Angewandte Chemie - International Edition

Volumn 51, Issue 33, 2012, Pages 8322-8325

  Gao, Lizhu ^a   Kang, Byung Chul ^a   Hwang, Geum Sook ^b   Ryu, Do Hyun ^a  

^a Sungkyunkwan University   (South Korea)

^b Chungnam National University   (South Korea)

Author keywords

asymmetric synthesis; boron; diazo compounds; homogeneous catalysis; synthetic methods

Indexed keywords

ASYMMETRIC SYNTHESIS; DIAZO COMPOUNDS; ENANTIOSELECTIVE SYNTHESIS; HOMOGENEOUS CATALYSIS; KETO ESTER; REACTION CATALYZED; SYNTHETIC METHODS; TWO-STEP SYNTHESIS;

ALDEHYDES; BORON; REACTION KINETICS;

ENANTIOSELECTIVITY;

BORON DERIVATIVE; ESTER; HETEROCYCLIC COMPOUND; ION; KETONE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

AZA COMPOUNDS; BORON COMPOUNDS; CATALYSIS; ESTERS; IONS; KETONES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84864879515     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201204350     Document Type: Article

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