Functionalization of layered double hydroxides by intumescent flame retardant: Preparation, characterization, and application in ethylene vinyl acetate copolymer

Applied Surface Science

Volumn 258, Issue 24, 2012, Pages 10115-10122

  Huang, Guobo ^a   Fei, Zhengdong ^b   Chen, Xiaoying ^a   Qiu, Fangli ^a   Wang, Xu ^b   Gao, Jianrong ^b  

^a TAIZHOU UNIVERSITY   (China)

^b ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Intumescent flame retardant; Layered double hydroxides; Nanocomposites

Indexed keywords

CAPILLARY FLOW; ENERGY DISPERSIVE X RAY ANALYSIS; ETHYLENE; FILLED POLYMERS; FLAME RETARDANTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; HYDROPHOBICITY; ION EXCHANGE; NANOCOMPOSITES; POLYMER MATRIX COMPOSITES; POLYMER MELTS; POLYVINYL ACETATES; RESINS; SCANNING ELECTRON MICROSCOPY; THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS; THERMOPLASTIC ELASTOMERS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

ETHYLENE VINYL ACETATE COPOLYMER; FLAMMABILITY PROPERTIES; FUNCTIONALIZATIONS; HIGH-ANGLE-ANNULAR-DARK-FIELD SCANNING TRANSMISSION ELECTRON MICROSCOPES; INTUMESCENT FLAME RETARDANT; LAYERED DOUBLE HYDROXIDES; PEAK HEAT RELEASE RATES; POLYMER MELT INTERCALATION;

X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 84864690697     PISSN: 01694332     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apsusc.2012.06.088     Document Type: Article

References (32)

1. D.R. Paula, and L.M. Robeson Polymer nanotechnology: nanocomposites Polymer 49 2008 3187 3204
2. Y.Q. Rao, and J.M. Pochan Mechanics of polymer-clay nanocomposites Macromolecules 40 2007 290 296
3. S. Yaru, K. Takashi, N.W. Richard, W.G. Jeffrey, E.L. Richard, and Y.S. Dotsevi Ethylene vinyl acetate/layered silicate nanocomposites prepared by a surfactant-free method: enhanced flame retardant and mechanical properties Polymer 50 2009 3478 3487
4. F. Leroux, and J.P. Besse Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites Chemistry of Materials 13 2001 3507 3515 (Pubitemid 32999288)
5. M.S. Lakshmi, B. Narmadha, and B.S.R. Reddy Enhanced thermal stability and structural characteristics of different MMT-clay/epoxy-nanocomposite materials Polymer Degradation and Stability 93 2008 201 213
6. F. Bertini, M. Canetti, G. Audisio, G. Costa, and L. Falqui Characterization and thermal degradation of polypropylene-montmorillonite nanocomposites Polymer Degradation and Stability 91 2006 600 605 (Pubitemid 41705292)
7. L.C. Du, B.J. Qu, and M. Zhang Thermal properties and combustion charaeterization of nylon 6/MgAI-LDH nanocomposites via organic modification and melt interealation Polymer Degradation and Stability 92 2007 497 502 (Pubitemid 46274987)
8. M. Zhang, P. Ding, B.J. Qu, and A.G. Guan A new method to prepare flame retardant polymer composites Journal of Materials Processing Technology 208 2008 342 347
9. L.Z. Qiu, W.C. Chen, and B.J. Qu Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites Polymer 47 2006 922 930
10. Y.Q. Shi, F. Chen, J.T. Yang, and M.Q. Zhong Crystalline behaviors and thermal stabilities of layered double hydroxide reinforced polypropylene nanocomposites Applied Clay Science 50 2010 87 91
11. J.W. Gilman, C.L. Jackson, A.B. Morgan, R. Harris, E. Manias Jr., E.P. Giannelis, M. Wuthenow, D. Hilton, and S.H. Phillips Flammability properties of polymer-layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites Chemistry of Materials 12 2000 1866 1873
12. S. Bourbigot, E. Devaux, and X. Xavier Flammability of polyamide-6/clay hybrid nanocomposite textiles Polymer Degradation and Stability 75 2002 397 402 (Pubitemid 34086311)
13. P.K. Sahoo, and R. Samal Fire retardancy and biodegradability of poly(methyl methacrylate)/montmorillonite nanocomposite Polymer Degradation and Stability 92 2007 1700 1707 (Pubitemid 47361344)
14. H.A. Stretz, M.W. Wootan, P.E. Cassidy, and J.H. Koo Effect of exfoliation on poly(styrene-co-acrylonitrile)/montmorillonite nanocomposite flammability Polymers for Advanced Technologies 16 2005 239 248 (Pubitemid 40405388)
15. C. Kaynak, G.I. Nakas, and N.A. Isitman Mechanical properties, flammability and char morphology of epoxy resin/montmorillonite nanocomposites Applied Clay Science 46 2009 319 324
16. Z.Y. Wang, E.H. Han, and W. Ke Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating Progress in Organic Coatings 53 2005 29 37 (Pubitemid 40391444)
17. C.M. Jiao, Z.Z. Wang, X.L. Chen, and Y. Hu Synthesis of a magnesium/aluminum/iron layered double hydroxide and its flammability characteristics in halogen-free, flame-retardant ethylene/vinyl acetate copolymer composites Journal of Applied Polymer Science 107 2008 2626 2631
18. C.M.C. Pereira, M. Herrero, F.M. Labajos, A.T. Marques, and V. Rives Preparation and properties of new flame retardant unsaturated polyester nanocomposites based on layered double hydroxides Polymer Degradation and Stability 94 2008 939 946
19. M. Ogawa, and S. Asai Hydrothermal synthesis of layered double hydroxide-deoxycholate intercalation compounds Chemistry of Materials 12 2000 3253 3255 (Pubitemid 32063933)
20. F.R. Costa, A. Leuteritz, U. Wagenknecht, D. Jehnichen, L. Häußler, and G. Heinrich Intercalation of Mg-Al layered double hydroxide by anionic surfactants: preparation and characterization Applied Clay Science 38 2008 153 164 (Pubitemid 351150157)
21. D.Y. Wang, F.R. Costa, A. Vyalikh, A. Leuteritz, U. Scheler, D. Jehnichen, U. Wagenknecht, L. Hussler, and G. Heinrich One-step synthesis of organic LDH and its comparison with regeneration and anion exchange method Chemistry of Materials 21 2009 4490 4497
22. F.R. Costa, A. Leuteritz, U. Wagenknecht, M.A. Landwehr, D. Jehnichen, L. Haeussler, and G. Heinrich Alkyl sulfonate modified LDH: Effect of alkyl chain length on intercalation behavior, particle morphology and thermal stability Applied Clay Science 44 2009 7 14
23. H. Zhang, Z.P. Xu, G.Q. Lu, and S.C. Smith Intercalation of sulfonate into layered double hydroxide: comparison of simulation with experiment Journal of Physical Chemistry C 113 2009 559 566
24. G.B. Huang, A.A. Zhuo, L.Q. Wang, and X. Wang Preparation and flammability properties of intumescent flame retardant-functionalized layered double hydroxides/polymethyl methacrylate nanocomposites Materials Chemistry and Physics 130 2011 714 720
25. G.B. Huang, J.R. Gao, Y.J. Li, L. Han, and X. Wang Functionalizing nano-montmorillonites by modified with intumescent flame retardant: preparation and application in polyurethane Polymer Degradation and Stability 95 2010 245 253
26. F.R. Costa, M. Saphiannikova, U. Wagenknecht, and G. Heinrich Layered double hydroxide based polymer nanocomposites Advances in Polymer Science 210 2008 101 168
27. S. Park, C. Yim, B.H. Lee, and S. Choe Properties of the blends of ethylene-vinyl acetate and ethylene-α-olefins copolymers Macromolecular Research 13 2005 243 252 (Pubitemid 40935091)
28. U. Costantino, A. Gallipoli, M. Nocchetti, G. Camino, F. Bellucci, and A. Frache New nanocomposites constituted of polyethylene and organically modified ZnAl-hydrotalcites Polymer Degradation and Stability 90 2005 586 590 (Pubitemid 41376425)
29. L. Ye, P. Ding, M. Zhang, and B.J. Qu Synergistic effects of exfoliated LDH with some halogen-free flame retardants in LDPE/EVA/HFMH/LDH nanocomposites Journal of Applied Polymer Science 107 2008 3694 3701 (Pubitemid 351388236)
30. C.X. Zhao, Y. Liu, D.Y. Wang, D.L. Wang, and Y.Z. Wang Synergistic effect of ammonium polyphosphate and layered double hydroxide on flame-retardant properties of poly (vinyl alcohol) Polymer Degradation and Stability 93 2008 1323 1331
31. G.B. Huang, Y.J. Li, L. Han, J.R. Gao, and X. Wang A novel intumescent flame retardant-functionalized montmorillonite: preparation, characterization, and flammability properties Applied Clay Science 51 2011 360 365
32. N.A. Isitman, H.O. Gunduz, and C. Kaynak Nanoclay synergy in flame retarded/glass fibre reinforced polyamide 6 Polymer Degradation and Stability 94 2009 2241 2250