Influence of the acid/base and redox properties of catalysts in the gas-phase dehydration-dehydrogenation of cyclohexanol on iron and titania containing mesoporous materials

Reaction Kinetics, Mechanisms and Catalysis

Volumn 104, Issue 2, 2011, Pages 291-301

  Szegedi, Ágnes ^a   Popova, Margarita ^b   Lázár, Károly ^c  

^a CHEMICAL RESEARCH CENTER   (Hungary)

^b INSTITUTE OF ORGANIC CHEMISTRY   (Bulgaria)

^c INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

Author keywords

Cyclohexanol dehydrogenatiom; FeTiMCM 41; Titanium and iron modified MCM 41

Indexed keywords

CATALYTIC BEHAVIOR; CYCLOHEXANOL; DIFFUSE REFLECTANCE; FETIMCM-41; MODIFIED MESOPOROUS SILICAS; NITROGEN PHYSISORPTION; SSBAUER SPECTROSCOPIES; WELL-ORDERED PORES;

CATALYST SELECTIVITY; IRON; PHYSISORPTION; SILICA; TITANIUM; X RAY DIFFRACTION;

MESOPOROUS MATERIALS;

EID: 84864689984     PISSN: 18785190     EISSN: 18785204     Source Type: Journal    
DOI: 10.1007/s11144-011-0372-6     Document Type: Article

References (24)

1. Corma A (1997) From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem Rev 97:2373-2420
2. Wang Y, Zhang Q, Shishido T, Takehira K (2002) Characterizations of iron-containing MCM-41 and its catalytic properties in epoxidation of styrene with hydrogen peroxide. J Catal 209:186-196
3. Wu Ch, Kong Y, Gao F, Wu Y, Lu Y, Wang J, Dong L (2008) Synthesis, characterization and catalytic performance for phenol hydroxylation of Fe-MCM41 with high iron content. Microporous Mesoporous Mater 113:163-170
4. Taguchi A, Schüth F (2005) Ordered mesoporous materials in catalysis. Microporous Mesoporous Mater 77:1-45
5. Rodriguis ACC (2007) Metallic mixed oxides (Pt, Mn or Cr) as catalysts for the gas-phase toluene oxidation. Catal Commun 8:1227-1231
6. Szegedi Á , Kónya Z, Méhn D, Solymár E, Pál-Borbély G, Horváth ZE, Biró LP, Kiricsi I (2004) Spherical mesoporous MCM-41 materials containing transition metals: synthesis and characterization. Appl Catal A 272:257-266
7. Kang M, Lee M-H (2005) Synthesis and characterization of Al-, Bi-, and Fe-incorporated mesoporous titanosilicate (MPTS) materials and their hydrophilic properties. Appl Catal A 284:215-222
8. Galacho C, Carrott MMLR, Carrot PJM (2007) Structural and catalytic properties of Ti-MCM-41 synthesised at room temperature up to high Ti content. Microporous Mesoporous Mater 100:312-321
9. 4 and several inorganic solids. Appl Catal A 243:93-107
10. 2 catalysts: the role of copper species. Catal Commun 8:1891-1895
11. 2 catalysts and their activity for cyclohexanol conversion. J Mol Catal 252:238-244
12. Fridman VZ, Davydov AA (2000) Dehydrogenation of cyclohexanol on copper-containing catalysts: I. the influence of the oxidation state of copper on the activity of copper sites. J Catal 195:20-30
13. +. J Catal 222:545-557
14. 2 catalysts for the dehydrogenation of cyclohexanol to cyclohexanone. Korean J Chem 14:49-58
15. 3 catalyst. Catal Lett 59:157-160
16. Dobrovolszky M, Tétényi P, Paál Z (1982) Catalytic transformations of cyclohexanol on Group VIII metal catalysts. J Catal 74:31-43
17. Popova M, Szegedi Á , Cherkezova-Zheleva Z, Mitov I, Kostova N, Tsoncheva T (2009) Toluene oxidation on titanium and iron modified MCM-41 materials. J Hazard Mater 168:226-232
18. Hamdy MS, Mul G, Jansen JC, Ebaid A, Shan Z, Overweg AR, Th Maschmeyer (2005) Synthesis, characterization, and unique catalytic performance of the mesoporous material Fe-TUD-1 in Friedel-Crafts benzylation of benzene. Catal Today 100:255-260
19. Orlov A, Zhal Q-Z, Klinowski J (2006) Photocatalytic proprerties of the SBA-15 mesoporous silica molecular sieve modified with titanium. J Mater Sci 41:2187-2193
20. Burns RG (1994) Mineral Mössbauer spectroscopy: correlations between chemical shift and quadropole splitting parameters. Hyperfine Interact 91:739-745
21. Lázár K, Pál-Borbély G, Szegedi Á , Beyer HK (2002) Coordination and oxidation states of iron incorporated in mesoporous MCM41. Hyperfine Interact 139:19-31
22. Szegedi Á , Pál-Borbély G, Lázár K (2001) Comparison of the redox properties of iron incorporated in different amounts into MCM-41. React Kinet Catal Lett 74:277-287
23. Kataoka T, Dumesic JA (1988) Acidity of unsupported and silica-supported vanadia, molybdena, and titania as studied by pyridine adsorption. J Catal 112:66-79
24. Yang Zh, Li J, Yang X, Xie X, Wu Y (2005) Gas-phase oxidation of alcohols over silver: the extension of catalytic cycles of oxidation of alcohols in liquid-phase. J Mol Catal 241:15-21