Dehydrogenation of cyclohexanol on copper-containing catalysts: II. The pathways of the cyclohexanol dehydrogenation reaction to cyclohexanone on copper-active sites in oxidation state Cu0 and Cu+

Journal of Catalysis

Volumn 222, Issue 2, 2004, Pages 545-557

  Fridman, V Z ^a,b   Davydov, A A ^a   Titievsky, K ^a,c  

^a Xenonum Scientific Services   (United States)

^b Sud Chemie Incorporated   (United States)

^c Massachusetts Institute of Technology Cambridge   (United States)

Author keywords

Copper catalysts; Cyclohexanol; Cyclohexanone; Dehydrogenation kinetics; Monovalent and zero valent copper sites

Indexed keywords

COPPER; COPPER DERIVATIVE; CYCLOHEXANOL; CYCLOHEXANOL ALCOHOLATE; CYCLOHEXANOL DERIVATIVE; CYCLOHEXANONE; HYDROGEN; HYDROXYL HYDROGEN; MONOVALENT CATION; UNCLASSIFIED DRUG;

ABSORPTION; ADSORPTION; ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; DEHYDROGENATION; DISSOCIATION; ENTHALPY; ENTROPY; INFRARED SPECTROSCOPY; KINETICS; OXIDATION; REACTION ANALYSIS; ROOM TEMPERATURE; TEMPERATURE DEPENDENCE;

EID: 1542298157     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcat.2003.12.016     Document Type: Article

References (42)

1. Fridman V.Z., Davydov A.A. J. Catal. 195:2000;20.
2. Takagi Y., Teratani S., Tanaka K. J. Catal. 27:1972;79.
3. Manninger I., Paal Z., Tetenyi P. J. Catal. 48:1977;442.
4. Szilagyi T., Sarkany A., Mink J., Tetenyi P. J. Catal. 66:1980;191.
5. Medvedeva O.N., Badrian A.S., Kiperman S.L. Kinet. Catal. (in Russian). 17:1976;1530.
6. Medvedeva O.N., Gudkov B.S., Badrian A.S., Kiperman S.L. Bull. Acad. Sci. USSR, Chem. Vers. (in Russian). 1:1977;19.
7. Rioux R.M., Vannice M.A. J. Catal. 216:2003;362.
8. Shekochihin U.M., Davydov A.A. The Method's Questions of Applying of IR-Spectroscopy for the Investigation of Physics-Chemistry of a Surface of Semi-conductors, N 5014-83. 1983;Vinity, Moscow.
9. Davydov A.A. Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides. 1990;Wiley, Chichester.
10. Herman R.G., Klier K., Simmons G.W., Finn B.P., Bulko J.B. J. Catal. 56:1979;407.
11. Menta S., Simmons G.W., Klier K. J. Catal. 57:1979;339.
12. Dandekar A., Vannice M.A. J. Catal. 178:1998;621.
13. Socrates G. Infrared Characteristic Group Frequencies: Table and Charts. 1994;Wiley, New York.
14. Pouchert C.J. The Aldrich Library of Infrared Spectra. 1981;Aldrich Chemical Co. Milwaukee.
15. Davydov A.A., Knyzeva E.M., Shepotko M.L. J. Appl. Spectrosc. (in Russian). 49:1988;86.
16. Brabec L., Novakova J., Kubelkova L. J. Mol. Catal. 94:1994;117.
17. Pearce H.A., Sheppard N. Surf. Sci. 59:1976;205.
18. Griffiths D.M., Rochester C.H. J. Chem. Soc., Faraday Trans. I74:1978;403.
19. Efremov A.A., Davydov A.A. React. Kinet. Catal. Lett. 18:1982;353.
20. Escribano V.S., Busca G., Lorinzelli V. J. Phys. Chem. 94:1990;8939.
21. Martin C.I., Martin I., Rives V. J. Catal. 145:1994;239.
22. Davis J.L., Barteau M.A. Surf. Sci. 208:1989;383.
23. Vannice M.A., Erley W., Ibach H. Surf. Sci. 254:1991;1.
24. Osipova N.A., Davydov A.A., Kurina L.A., Loyko V.E. J. Phys. Chem. (in Russian). 109:1985;1479.
25. Osipova N.A., Davydov A.A., Kurina L.A. J. Phys. Chem. (in Russian). 109:1985;1484.
26. Krylov O.V. J. Phys. Chem. (in Russian). 39:1965;2911.
27. Kazansky V.B., Pid'ko E.A. Kinet. Catal. (in Russian). 43:2002;614.
28. Boccuzzi F., Garrone E., Zecchina A., Bossi A., Camia M. J. Catal. 51:1978;160.
29. Tetenyi P., Paal Z. J. Catal. 208:2002;494.
30. Paal Z., Peter A., Tetenyi P. Reaction. Kinet. Catal. Lett. 1:1974;121.
31. Manninger I., Peter A., Paal Z., Tetenyi P. Kemiai Kozl. (in Hungarian). 44:1975;35.
32. Fridman V.Z., Davydov A.A. J. Catal. 208:2002;497.
33. Weldon M.K., Fried C.M. Chem. Rev. 96:1996;1391.
34. Chen D.A., Fried C.M. Langmuir. 14:1998;1451.
35. Davydov A.A. Molecular Spectroscopy of Oxide Catalyst Surface. 2003;Wiley, New York.
36. Dandekar A., Baker R.T.K., Vannice M.A. J. Catal. 184:1999;421.
37. Babkova P.B., Avetisova A.K., Lubarskyi G.D. Kinet. Catal. (in Russian). 11:1970;1451.
38. Tripolskyi A.I., Pavlenko N.V., Golodez G.I. Kinet. Catal. (in Russian). 26:1985;1131.
39. Boudart M., Mears D.E., Vannice M.A. Ind. Chim. Belge. 32:1967;281.
40. Vannice M.A., Hyun S.H., Kalpakci B., Liauh W.C. J. Catal. 56:1979;358.
41. Dean A.J. Lange's Handbook of Chemistry. fifteen edition:1999.
42. Erofeev B.V., Scregan E.A. J. Phys. Chem. (in Russian). 43:1969;139.